Positron annihilation studies on the electronic structure of Pd−Ag−H system

Angular Correlation of Annihilation Radiation (ACAR) is shown to be useful to examine the electronic structure of -phase Pd_1–y Ag _y H _x system. Hydrogen absorption by Pd_1–y Ag _y alloys results in the increase of both nearly free andd-localized electron numbers in compliance with the KKR-CPA calculation outcomes. The investigation of -phase systems, PdH _x hydrides as well as Pd_1–y Ag _y H _x materials, failed because of a high concentration of lattice defects.     

Disordered charge distributions and dielectric loss in extra dense flint glasses

The complex permittivities of some extra dense flint glasses (EDF glasses) have been studied. The dielectric features of the samples are dominated by their PbO content. Both refractive indices and dielectric losses exhibit a close relation to the concentration of Pb ions. The latter are located either at sites of the network atoms or filling the potential minima interstitially. They can be identified by their different relaxation mechanisms. The dispersion in the submillimeter wave and FIR area is characterized by a very broad distribution of comparably sharp resonant states. Thermal lens — or hysteresis effects can be excluded.     

On the dynamics of cosmological particle production

The time evolution of the particle number density and spectrum of massive scalar particles, coupled conformally to a classical Friedman-Robertson-Walker gravitational field is followed numerically. Not only for a pure radiation cosmos, but also for one with an inflationary interlude, the density of particles produced remains constant in time. This results in a constant equivalent temperature scale up to the Compton time of the massive particles, and opens the possibility that during a sufficiently long inflation the energy density of the particles produced can exceed that of the radiation background.     

Crystal structures of dimethylsuccinate and dimethyloxalate: Carbonyl group orientation for C13 chemical shielding tensor studies

The crystal structures of dimethylsuccinate (DMS) and dimethyloxalate (DMO) have been determined to facilitate the determination of the C-13 chemical shielding tensors of the carbonyl carbon in esters. Crystals of DMS are monoclinic, space groupC2/c,Z=4,a=13.154(4),b=6.156(1),c=9.363(4)Å,=98.53(3)°. The structure was solved by direct methods and refined by leastsquares procedures to giveR=0.071 for 932 observed data. Crystals of DMO are monoclinic space group,P2₁/n,Z=2, witha=3.891(1),b=11.879(2),c=6.213(2) Å,=103.32(2)°. The structure is the same (within experimental error) as that reported by Dougill and Jeffrey (1953) and refined to giveR=0.074 for 395 observed data.     

Comparison between structural and residual error formulations of an optimum design mechanism problem

Summary The model formulation of the objective function is one of the most important steps for solving an optimization problem. Generally, the objective function of an optimal design mechanism problem can be mathematically formulated either with structural or residual errors. In this paper we have conducted some comparisons between the results obtained by the structural and residual error formulations utilized in solving the optimum design of a four-bar linkage. The optimization problem is defined as a nonlinear least-squares problem. The damped Gauss-Newton algorithm is utilized for computing the solution, which ensures a local convergence for almost all nonlinear least-squares problems.

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Sommario La formulazione matematica della funzione obiettivo è uno degli aspetti più delicati nella soluzione di un problema di ottimizzazione. Generalmente la funzione obiettivo di un problema di progettazione ottima di un meccanismo può essere formulata sia mediante l'errore strutturale che residuo. In questo lavoro sono stati eseguiti dei confronti tra i risultati ottenuti mediante le due precedenti formulazioni, in riferimento al problema della progettazione ottima di un quadrilatero articolato. Il problema di ottimizzazione viene definito come un problema nonlineare ai minimi quadrati la cui soluzione numerica è ottenuta mediante l'algoritmo damped di Gauss-Newton.

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This paper was partially discussed at theII Congegno di Meccanica Computazionale, Roma, 1987.     

Reducible Dupin submanifolds

Pinkall's standard constructions for obtaining a Dupin hypersurface W in ^N from a Dupin hypersurface M in ⁿ , N>n, are studied in the context of Lie sphere geometry. It is shown that a compact Dupin hypersurface W in ^N with g distinct principal curvatures at each point is reducible to a compact Dupin hypersurface M in ⁿ if and only if g=2.This research was supported by NSF Grant No. DMS 87-06015.     

Relaxation methods in control theory

Two different relaxed problems associated with a problem of optimal control theory, governed by an ODE, are considered: the first is obtained by Young's methods and the second by semicontinuity arguments. A formula which relates the two relaxed functionals to each other is given.     

Poisson structure of a periodic classical XYZ -chain

Classical variables ( -variables) are constructed for a periodic classical XYZ -chain (of the discrete Landau-Lifshitz equation). The connection of the quantum method of the inverse problem and the theory of finite-zone integration is discussed.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Matematicheskogo Instituta im. V. A. Steklova AN SSSR, Vol. 150, pp. 154–180, 1986.