全文获取类型
收费全文 | 296617篇 |
免费 | 5772篇 |
国内免费 | 3363篇 |
专业分类
化学 | 143720篇 |
晶体学 | 4262篇 |
力学 | 15908篇 |
综合类 | 246篇 |
数学 | 44774篇 |
物理学 | 96842篇 |
出版年
2022年 | 1608篇 |
2021年 | 1854篇 |
2020年 | 2074篇 |
2019年 | 2017篇 |
2018年 | 11169篇 |
2017年 | 12097篇 |
2016年 | 7596篇 |
2015年 | 3870篇 |
2014年 | 3887篇 |
2013年 | 9468篇 |
2012年 | 12752篇 |
2011年 | 22798篇 |
2010年 | 13791篇 |
2009年 | 13909篇 |
2008年 | 19714篇 |
2007年 | 23192篇 |
2006年 | 8461篇 |
2005年 | 14900篇 |
2004年 | 10360篇 |
2003年 | 9228篇 |
2002年 | 6980篇 |
2001年 | 6668篇 |
2000年 | 5358篇 |
1999年 | 4087篇 |
1998年 | 3145篇 |
1997年 | 3050篇 |
1996年 | 3170篇 |
1995年 | 2756篇 |
1994年 | 2595篇 |
1993年 | 2418篇 |
1992年 | 2665篇 |
1991年 | 2599篇 |
1990年 | 2318篇 |
1989年 | 2226篇 |
1988年 | 2224篇 |
1987年 | 2123篇 |
1986年 | 2041篇 |
1985年 | 2922篇 |
1984年 | 2887篇 |
1983年 | 2333篇 |
1982年 | 2507篇 |
1981年 | 2376篇 |
1980年 | 2318篇 |
1979年 | 2281篇 |
1978年 | 2355篇 |
1977年 | 2228篇 |
1976年 | 2195篇 |
1975年 | 2168篇 |
1974年 | 2068篇 |
1973年 | 2190篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
A mixed problem is considered for a system of partial differential equations modeling the process of adsorption dynamics. An existence and uniqueness theorem is proved for this problem, and the solution properties are investigated. The inverse problem is posed, involving the determination of the system coefficient given additional information about the solution. A uniqueness theorem is proved for the solution of the inverse problem.__________Translated from Prikladnaya Matematika i Informatika, No. 16, pp. 5 – 14, 2004. 相似文献
92.
In this paper we obtain a number of Maharam-type slice integral representations, with respect to scalar measures, for positive
projections in Dedekind complete vector lattices and f-algebras.
AMS Classification: 47B65, 46A40, 06F25 相似文献
93.
We present here a methodology for searching a robust pore size distribution (PSD) for adsorbent materials. The method is based on a combination of individual adsorption isotherms, obtained from Grand Canonical Monte Carlo simulations, a regularization procedure to invert the adsorption integral equation (Tikhonov regularization solved by singular value decomposition), and the needed experimental adsorption isotherm. The selection of several parameters from the available choices to start the procedure are discussed here: the size of the kernel (number of individual pores and number of experimental adsorption points to be included), the fulfillment of the Discrete Picard condition, and the L-curve criteria, all leading to find a reliable and robust PSD. The procedure is applied to plugged hexagonal templated silicas (PHTS), synthesized, and characterized in our laboratory. 相似文献
94.
K. C. Kumara Swamy E. Balaraman M. Phani Pavan N. N. Bhuvan Kumar K. Praveen Kumar N. Satish Kumar 《Journal of Chemical Sciences》2006,118(6):495-501
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated
acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature
of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction. 相似文献
95.
96.
It is widely accepted that next-generation networks will provide guaranteed services, in contrast to the “best effort” approach today. We study and analyze queueing policies for network switches that support the QoS (Quality of Service) feature. One realization of the QoS feature is that packets are not necessarily all equal, with some having higher priorities than the others. We model this situation by assigning an intrinsic value to each packet. In this paper we are concerned with three different queueing policies: the nonpreemptive model, the FIFO preemptive model, and the bounded delay model. We concentrate on the situation where the incoming traffic overloads the queue, resulting in packet loss. The objective is to maximize the total value of packets transmitted by the queueing policy. The difficulty lies in the unpredictable nature of the future packet arrivals. We analyze the performance of the online queueing policies via competitive analysis, providing upper and lower bounds for the competitive ratios. We develop practical yet sophisticated online algorithms (queueing policies) for the three queueing models. The algorithms in many cases have provably optimal worst-case bounds. For the nonpreemptive model, we devise an optimal online algorithm for the common 2-value model. We provide a tight logarithmic bound for the general nonpreemptive model. For the FIFO preemptive model, we improve the general lower bound to 1.414, while showing a tight bound of 1.434 for the special case of queue size 2. We prove that the bounded delay model with uniform delay 2 is equivalent to a modified FIFO preemptive model with queue size 2. We then give improved upper and lower bounds on the 2-uniform bounded delay model. We also show an improved lower bound of 1.618 for the 2-variable bounded delay model, matching the previously known upper bound. 相似文献
97.
A nonlinear (in the cubic approximation) relaxation equation of state is derived for a rod containing cracks partially filled with an incompressible viscous liquid. The nonlinear effects of the self-action and interaction of low-and high-frequency longitudinal elastic waves propagating in such a rod are studied for the cases of identical and size-varied cracks. Linear and nonlinear acoustic parameters characterizing the self-action and interaction of elastic waves in a cracked rod are determined. 相似文献
98.
V. A. Nadtochenko A. S. Lobach F. E. Gostev O. M. Sarkisov D. O. Shcherbinin E. D. Obraztsova 《JETP Letters》2004,80(3):176-180
The dynamics of the photoinduced differential absorption and excited-state bleaching spectra of single-walled carbon nanotubes suspended in a micellar solution were studied in the spectral range from 40 to 1000 nm within a time interval from 70 fs to 150 ps under excitation by 50-fs pulses with photon energies 2 and 4 eV. The bleaching and absorption bands were observed in the spectra; the positions of the bleaching peaks were independent of the photon energy of the exciting femtosecond pulse in the range 2–4 eV. It was established that, for delay times shorter than 1 ps, the shape of the differential spectrum of excited nanotubes coincided with the shape of the second derivative of the absorption spectrum of unexcited nanotubes in the frequency range of exciting pulse above 18000 cm?1 (the range of absorption bands of metallic nanotubes). In the frequency range below 16000 cm?1 (the range of absorption peaks of semiconducting nanotubes), the bleaching peaks in the differential spectrum of excited nanotubes undergo a high-frequency shift of 200–300 cm?1 with respect to the second-derivative spectrum of unexcited nanotubes. The excited-state relaxation rate constants were measured. They are well approximated by the exponential dependences and depend on the probe-pulse wavelength. An assumption was made about the nature of the observed spectra of excited nanotubes and about the excitation relaxation. 相似文献
99.
Photorefractive scattering occurs in rhodium-doped lithium niobate crystals irradiated by coherent light. The photorefractive scattering has both wide-angle and selective components. The results of experimental investigation of selective photorefractive scattering in LiNbO3:Rh crystals and calculation of the spatial structure of scattering are reported. The selective scattering is regarded as a kind of a frequency-degenerate fourwave vector interaction. 相似文献
100.
In order to study the influence of seeded impurities on ITER like reactor operation the COREDIV code has been extended to include the transport of several sputtered and/or injected impurities. In the COREDIV code the core plasma is treated in the frame of 1D radial transport model whereas in the edge the 2D multifluid code EPIT is used. The EPIT code solves in the slab geometry the MHD equations for densities and velocities for all ions species as well as for electron and ion temperatures. The iteration scheme in the code leads to steady state solution of coupled core and SOL system. The numerical results for Carbon and Nickel plate and seeded impurities Silicon and Neon are presented. 相似文献