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981.
In this paper, we study the consistency of a variant of fractionalstep Runge–Kutta methods. These methods are designed tointegrate efficiently semi-linear multidimensional parabolicproblems by means of linearly implicit time integration processes.Such time discretization procedures are also related to a splittingof the space differential operator (or the spatial discretizationof it) as a sum of simpler linear differentialoperators and a nonlinear term. 相似文献
982.
J Whittaker C Whitehead M Somers 《The Journal of the Operational Research Society》2007,58(7):911-921
A principled technique for monitoring the performance of a consumer credit scorecard through time is derived from Kalman filtering. Standard approaches sporadically compare certain characteristics of the new applicants with those predicted from the scorecard. The new approach systematically updates the scorecard combining new applicant information with the previous best estimate. The dynamically updated scorecard is tracked through time and compared to limits calculated by sequential simulation from the baseline scorecard. The observation equation of the Kalman filter is tailored to take the results of fitting local scorecards by logistic regression to batches of new clients that arrive in the current time interval. The states in the Kalman filter represent the true or underlying score for each attribute in the card: the parameters of the logistic regression. Their progress in time is modelled by a random walk and the filter provides the best estimate of the scores using past and present information. We illustrate the technique using a commercial mortgage portfolio and the results indicate significant emerging deficiencies in the baseline scorecard. 相似文献
983.
D.L. Mills 《Applied Physics A: Materials Science & Processing》2007,87(3):427-431
This paper begins with some historical remarks regarding the author’s early interest in the use of electron energy loss spectroscopy
to probe dynamical phenomena on crystal surfaces. We then discuss the physical nature of the interactions responsible for
vibrational and spin waves losses, with attention to their role in related phenomena.
PACS 61.14.-x; 68.35.Ja; 68.49.Jk; 68.49.Uv 相似文献
984.
Y.-Q. Peng J.-H. Yang F.-P. Lu Q.-S. Yang H.-W. Xing X.-S. Li C.-A. Song 《Applied Physics A: Materials Science & Processing》2007,86(2):225-229
Based on the assumption of Gaussian energy distributions of the lowest unoccupied molecular orbital (LUMO) and the highest occupied molecular orbital (HOMO), analytical expressions of generalized Einstein relation in chemically doped organic semiconductor are developed, by approximation of Coulomb traps with a rectangle potential well. Numerical calculations show that traditional Einstein relations do not hold for chemically doped organic semiconductors. Similar to physical doping, the dependence of diffusion coefficient to mobility D/μ ratio on the carrier concentration has a maximum. An essential difference between chemical doping and physical doping is that, the D/μ ratio in chemically doped organic semiconductors depends not only on carrier concentration and doping concentration, but also on the applied electric field. PACS 71.20.Rv; 72.90.+y; 73.50.-h 相似文献
985.
986.
C.E. Allmond V.P. Oleshko J.M. Howe J.M. Fitz-Gerald 《Applied Physics A: Materials Science & Processing》2006,82(4):675-678
Nanostructured powders have shown great promise for a variety of applications including chemical gas sensors, high surface
area supports for catalysis, tribology, chemical mechanical polishing, and optoelectronics. In this report, highly dispersed
Pd nanoparticles with a narrow size distribution, and mean diameter of 2±0.2 nm, were deposited at room temperature onto amorphous
carbon and oxide supports (TiO2, Al2O3) by pulsed-laser ablation of a Pd sputtering target. Depositions were performed in Ar at a back-fill pressure of 3 mTorr
after reaching a base pressure of 10-7 Torr. Populations of uniformly dispersed particles with an interparticle spacing of 3 to 10 nm were observed by high-resolution
transmission electron microscopy with little evidence of nanoparticle aggregation. The chemical compositions of individual
nanoparticles were confirmed by high spatial resolution energy-dispersive X-ray spectroscopy. 相似文献
987.
Epithio-substituted primary-tertiary dialkyl peroxides were prepared by treatment of tert-alkyl oxiranylmethyl peroxides with potassium thiocyanate and were tested as polymerization initiators in synthesis of light-resistant polystyrene. 相似文献
988.
V. S. Shmotin A. S. Knyazev A. I. Titkov A. N. Salanov O. V. Vodyankina L. N. Kurina 《Russian Journal of Applied Chemistry》2006,79(9):1458-1462
Surface morphology and catalytic properties of electrolytic silver crystals in partial oxidation of ethylene glycol into glyoxal were studied. 相似文献
989.
Modulated
DSC for gas hydrates analysis 总被引:1,自引:0,他引:1
C. Giavarini F. Maccioni Maria Laura Santarelli 《Journal of Thermal Analysis and Calorimetry》2006,84(2):419-424
Modulated DSC has been applied to the study of methane,
ethane and propane hydrates at different hydrate and ice concentrations. The
reversing component of the TMDSC curves, makes it possible to characterize
such hydrates.
Methane and ethane hydrates show the melting-decomposition
peak at a temperatures higher than the ice contained in the sample, while
propane hydrate melts and decomposes at lower temperature than the ice present
in the sample. The hydrate peaks tend to disappear if the hydrate is stored
at atmospheric pressure. Guest size and cavity occupation fix the heat of
dissociation and stability of the hydrates, as confirmed by parallel tests
on tetrahydrofurane hydrates. 相似文献
990.