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191.
192.
193.
A. J. Parsons S. D. J. Inglethorpe D. J. Morgan A. C. Dunham 《Journal of Thermal Analysis and Calorimetry》1997,48(1):49-62
Using a system based on non-dispersive infrared (NDIR) detectors, evolved gas analysis (EGA) was able to identify and quantify the principal volatiles produced by heating powdered samples of UK brick clays. From these results, atmospheric emissions likely to result from brick production can be predicted. In addition, EGA results for extruded brick clay test pieces are significantly different from those of powdered samples. Within an extruded brick clay body, evolved gases are contained within a pore system and evolved gas-solid phase reactions also occur. This EGA study provides further evidence on the nature of firing reactions within brick clay bodies. The qualitative and quantitative influence of heating rate — a key process condition in brick manufacture — on gas release is also outlined.Dedicated to Dr. Robert Mackenzie on the occasion of his 75th birthday 相似文献
194.
I. L. Eremenko M. A. Golubnichaya S. E. Nefedov A. A. Sidorov D. A. Nesterenko N. P. Konovalova L. M. Volkova L. T. Eremenko 《Russian Chemical Bulletin》1997,46(9):1595-1598
Thetrans-[Pt(NC5H4C(O)NHC2H4ONO2)2Cl2] complex (2) was prepared by the reaction of nicorandyl (N-nitroethoxynicotinamide), which is widely used in cardiology, with K2PtCl4 in water. The structure of2 was established by X-ray structural analysis. It was found that complex2 exhibits high antitumor activity, in particular, antimetastatic activity, unlike the analogous CuII complex with bromine atoms.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1672–1675, September, 1997. 相似文献
195.
R.C. Viscovini E.M. Telles A. Scalabrin D. Pereira 《Applied physics. B, Lasers and optics》1997,65(1):33-35
2 laser of wide tunability to pump 13CD3OD we could observe 10 new far infrared laser lines ranging from 109 μm to 472 μm. The lines were generated by pumping infrared
absorbing transitions of large offset appertaining to the C-O stretching Q-branch. All lines were characterised in wavelength,
polarisation, optimum pressure of operation and precise offset measurements.
Received: 17 September 1996/Revised version: 18 November 1996 相似文献
196.
S. A. Gurevich T. A. Zaraiskaya S. G. Konnikov V. M. Mikushkin S. Yu. Nikonov A. A. Sitnikova S. E. Sysoev V. V. Khorenko V. V. Shnitov Yu. S. Gordeev 《Physics of the Solid State》1997,39(10):1691-1695
The concentration and chemical state of copper in the subsurface region of Cu/SiO2 composite films obtained by simultaneous magnetron sputtering from two sources (Cu and SiO2) are determined by x-ray photoelectron spectroscopy (XPS). It is established that copper in the as-grown film is primarily in the form of unoxidized atoms dispersed in a SiO2 matrix. Annealing of the film results in practically no oxidation, but about 70% of the copper atoms condense into metallic clusters with sizes below 10 Å in the subsurface region and about 50 Å in the bulk of the film. The changes in the binding energy of core electrons, and especially in the energies of Auger electrons, are so large in this situation that photoelectron and Auger spectroscopy are efficient methods for monitoring the chemical state of this composite material. 相似文献
197.
A converging perturbation series that can be summed analytically has been obtained for intersubband transitions of electrons
coherently tunneling through the middle of a dimensionally quantized level in an asymmetric double-barrier structure in a
high-frequency terahertz electric field. The possibility of a substantial increase in tunneling current accompanied by either
absorption or emission of a photon has been demonstrated. The quantum efficiency of radiative transitions between dimensionally
quantized levels can be up to 66%.
Zh. éksp. Teor. Fiz. 112, 237–245 (July 1997) 相似文献
198.
It is shown that equations describing the dynamics of Darwinian systems (DS) far from the bifurcation points may be expressed
in Hamiltonian form. The cases of DS with constant organization and DS with a constant flux through the system are considered.
The configurational part of phase space is formed by variables containing information on the structure of the system. Momentum
variables may be regarded as specific rates of multiplication. The evolution of DS with constant organization in this phase
space is expressed as uniform rectilinear motion. In the case of DS with a constant flux, the motion occurs in some effective
constant and uniform field. The meaning of the elements of the Hamiltonian structure is described in terms of theoretical
biology.
Tomsk State University. Scientific-Research Institute of Biological Systems, Tomsk State University. Translated from Izvestiya
Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 23–28, July, 1997. 相似文献
199.
200.
The effect of iodine sorption on the free volume of polycarbonate is investigated by Positron Annihilation Lifetime method.
The observed results are interpreted in terms of the Charge Transfer Complex formation and precipitation of iodine at the
initial and final stages of sorption, respectively. At higher levels of sorption, changes in the second lifetime and its intensity
seem to suggest a conformational transformation, probably due to the net change in the amorphous-crystalline boundary regions
of the polymer matrix. The free volume cavities have been predominantly occupied by I-
3 species and the diffusion process obeys Fick’s law. An exponential type correlation has been observed between fractional
free volume and the diffusion coefficient.
Received: 13 June 1996/Accepted: 20 September 1996 相似文献