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971.
The stoichiometric reactions of trimethylaluminum with 2,6‐(MeOCH2)2C6H3OH (LH) revealed compounds L3Al ( 1 ) and L2AlMe ( 2 ). On the other hand reaction of 1 equiv. of LH with trimethylaluminum did not lead to the formation of complex LAlMe2 ( 3 ), rather 2 together with Me3Al were observed as a result of a disproportionation of 3 . Compounds 1 and 2 were characterized by elemental analysis, 1H and 13C NMR spectroscopy and in the case of 1 by X‐ray diffraction. Derivative 2 underwent transmetalation with Ph3SnOH, giving LSnPh3 ( 4 ) as the result of a migration of ligand L from the aluminum to the tin atom. The identity of 4 was established by elemental analysis, 1H, 13C and 119Sn NMR spectroscopy and 1H, 119Sn HMBC experiments. The system 2 and B(C6F5)3 in a 1:1 molar ratio was shown to be active in the polymerization of propylene oxide and ε‐caprolactone. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
972.
The first twelve members of three new mesogenic homologous series have been characterized, each of which are composed of molecules possessing lateral alkyl chains. The n-alkyl 2,5-bis-(4-n-hexyloxy-benzoyloxy)-benzoates are purely nematic whereas both nematic and smectic behaviour is observed for the 4-cyano-4'-biphenylyl 3'-n-alkyloxybenzoates and the 4-cyano-4'-biphenylyl 3',4'-n-alkyloxybenzoates. The transitional properties of these series are similar to those of the analogous conventional mesogens and hence, can be rationalized without making any special assumptions concerning the conformational distribution of the lateral alkyl chain. 相似文献
973.
It has been described earlier that imaging measurements of laser-induced fluorescence (LIF) in flames can be calibrated to number densities with an integrated absorption measurement provided the integrated absorption is small. In this paper a method is presented that extends the technique to flames with substantial absorption, improves the number density determination and allows the experimental parameters to be chosen more freely. The method is based on an iterative computer procedure that reconstructs the 1-D spatially resolved absorption profile from laser measurements of the 1-D spatially resolved LIF and the integrated absorption of the laser beam. The technique is experimentally demonstrated by measurements of OH number densities in atmospheric flames. It is potentially a single-pulse method. Other applications of the iterative procedure are mentioned. 相似文献
974.
975.
The performance of high power transistor devices is intimately connected to the substrate thermal conductivity. In this study, the relationship between thermal conductivity and dislocation density is examined using the 3 omega technique and free standing HVPE GaN substrates. Dislocation density is measured using imaging cathodoluminescence. In a low dislocation density regime below 105 cm−2, the thermal conductivity appears to plateau out near 230 W/K m and can be altered by the presence of isotopic defects and point defects. For high dislocation densities the thermal conductivity is severely degraded due to phonon scattering from dislocations. These results are applied to the design of homoepitaxially and heteroepitaxially grown HEMT devices and the efficiency of heat extraction and the influence of lateral heat spreading on device performance are compared. 相似文献
976.
977.
We discuss equivalent definitions of holomorphic second-order cusp forms and prove bounds on their Fourier coefficients. We
also introduce their associated L-functions, prove functional equations for twisted versions of these L-functions and establish a criterion for a Dirichlet series to originate from a second order form. In the last section we
investigate the effect of adding an assumption of periodicity to this criterion.
2000 Mathematics Subject Classification Primary—11F12, 11F66
G. Mason: Research supported in part by NSF Grant DMS 0245225.
C. O’Sullivan: Research supported in part by PSC CUNY Research Award No. 65453-00 34. 相似文献
978.
M.C. Robinson D.J. Morris P.D. Hayenga J.H. Cho C.D. Richards R.F. Richards D.F. Bahr 《Applied Physics A: Materials Science & Processing》2006,85(2):135-140
Piezoelectric membranes have been fabricated that incorporate a gold bottom electrode with an adhesion layer of titanium–tungsten (10:90 wt. %). For solution-deposited acetic acid based lead zirconate titanate (HoAc-PZT) with a Zr:Ti ratio of 40:60, the film’s average piezoelectric coefficient, e31, is -5.31 C/m2, with a dielectric constant of 814 at 200 Hz, which is similar to values for platinum bottom electrodes. The PZT structure remains columnar on both types of bottom electrodes. Initial fabrication attempts resulted in cracking that initiated in the PZT layer of the structure. X-ray photoelectron spectroscopy was utilized to establish how processing affects diffusion throughout the composite membrane structure. Crack-free membranes were fabricated and tested. This paper discusses the performance properties and piezoelectric fatigue results for these membranes. PACS 77.84.-s; 77.84.Lf 相似文献
979.
980.
I. Kandarakis D. Cavouras P. Prassopoulos E. Kanellopoulos C.D. Nomicos G.S. Panayiotakis 《Applied Physics A: Materials Science & Processing》1998,66(5):521-525
2 SiO4:Mn phosphor was evaluated for use in radiation detectors of medical imaging systems. Zn2SiO4:Mn was used in the form of laboratory-prepared fluorescent layers (screens) with coating weights from 18 to 150 mg/cm2. The phosphor was excited to luminescence by low-energy X-raysusing X-raytube voltages ranging from 15 to 50 kVp. The number
of emitted optical photons per incident X-rayquantum was thus determined for various X-rayenergies and phosphor coating weights.
The optical emission spectrum was also measured and it was used to evaluate the spectral compatibility of Zn2SiO4:Mn with radiographic films, photocathodes and the Si photodiode. Finally, phosphor optical properties were estimated by fitting
a theoretical model to experimental data. Results showed that Zn2SiO4:Mn is more efficient for low-energy X-rays. Its intrinsic conversion efficiency was found equal to 0.08, which is comparable
to that of actually used phosphors. Zn2SiO4:Mn was also adequately compatible with orthochromatic films and the ES-20 photocathode, thus being appropriate for low-voltage
radiography and fluoroscopy.
Received: 31 July 1998/Accepted: 3 August 1998 相似文献