全文获取类型
收费全文 | 1372篇 |
免费 | 53篇 |
国内免费 | 10篇 |
专业分类
化学 | 1047篇 |
晶体学 | 10篇 |
力学 | 29篇 |
数学 | 91篇 |
物理学 | 258篇 |
出版年
2023年 | 5篇 |
2022年 | 15篇 |
2021年 | 22篇 |
2020年 | 18篇 |
2019年 | 31篇 |
2018年 | 23篇 |
2017年 | 19篇 |
2016年 | 43篇 |
2015年 | 49篇 |
2014年 | 60篇 |
2013年 | 122篇 |
2012年 | 131篇 |
2011年 | 108篇 |
2010年 | 68篇 |
2009年 | 70篇 |
2008年 | 75篇 |
2007年 | 84篇 |
2006年 | 102篇 |
2005年 | 63篇 |
2004年 | 63篇 |
2003年 | 46篇 |
2002年 | 55篇 |
2001年 | 30篇 |
2000年 | 18篇 |
1999年 | 13篇 |
1998年 | 10篇 |
1997年 | 7篇 |
1996年 | 12篇 |
1995年 | 7篇 |
1994年 | 10篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1987年 | 3篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 7篇 |
1981年 | 2篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有1435条查询结果,搜索用时 15 毫秒
111.
Yu Na Shin Byung Soo Kim Hyun Hee Ahn Kyung Sook Kim Moon Suk Kim Gilson Khang 《Applied Surface Science》2008,255(2):293-296
Corona discharge treatment was applied to modify the surface of polyethylene (PE). The wettability of PE surface was gradually increased by power increase of a corona treatment along the PE length, indicating that the hydrophilicity of PE surface increased gradually. The adhesion and proliferation behavior of human bone marrow stem cells (hBMSCs) on the gradient PE surface was evaluated. We found that hBMSCs were adhered to and proliferated on better highly hydrophilic than hydrophobic surfaces. The plot of proliferation rate vs. the water contact angles was parabolic. These results indicate that surface wettability plays an important role in the cell attachment and proliferation. 相似文献
112.
The electrooxidation of dopamine (DA) and ascorbic acid (AA) was studied using gold electrodes modified by a cationic self-assembled monolayer of [Os(bpy)2(bpy-(CH2),3SH)]2+ by cyclic voltammetry. At an [Os(bpy)2(bpy-(CH2)13SH)]2+/Au electrode, the oxidation peak of DA shifted to a much more positive potential as compared with that of a bare gold electrode, while the oxidation peak potential of AA showed a slightly negative shift due to their different electrostatic interactions with the cationic monolayer. Thus, a sufficient potential difference was achieved for distinguishing the electrochemical responses of DA and AA. However, when CH3(CH2)11SH was mixed into the cationic monolayer, the enhanced packing of the mixed monolayer blocked the access of DA or AA to the electrode, resulting in further positive shifts for both oxidation-peak potentials. 相似文献
113.
In actuality, we face lots of uncertainty in the application of a Markov process. In order to reduce such uncertainty, it is indispensable to use additional information concerning the state of the process.Among various kinds of additional information, this paper focuses on how to use uncertain delayed observation in a partially observable Markovian decision process (POMDP). This study develops a basic information structure, adding lagged observations to a general POMDP, and derives a rule for updating the state vector based on the information structure. This POMDP model is solved on the basis of a modified one-pass algorithm. An example is also given. 相似文献
114.
Dong H. Jung Min A. Jeong Han M. Jeong Byung K. Kim 《Colloid and polymer science》2010,288(14-15):1465-1470
Chemical hybrids of imidized waterborne polyurethane (WPU) with silica nanoparticle were synthesized by UV cure. Imide groups were introduced into the hard segment of UV curable WPU by extending the NCO-terminated prepolymers with pyromellitic dianhydride where chemical hybridization by UV cure was made between the acrylate-terminated polyurethane prepolymer and vinyltrimethoxysilane-silica oligomer. It was found that imidization of WPU and imidized WPU-silica hybrids showed remarkably high mechanical and dynamic mechanical properties at room and elevated temperatures as well as thermal stability. 相似文献
115.
Chin Chye Teo Swee Ngin Tan Jean Wan Hong Yong Choy Sin Hew Eng Shi Ong 《Journal of chromatography. A》2010,1217(16):2484-2494
Pressurized hot water extraction (PHWE) has become a popular green extraction method for different classes of compounds present in numerous kinds of matrices such as environmental, food and botanical samples. PHWE is also used in sample preparation to extract organic contaminants from foodstuff for food safety analysis and soils/sediments for environmental monitoring purposes. The main parameters which influence its extraction efficiency are namely the temperature, extraction time, flow rates and addition of modifiers/additives. Among these different parameters studied, temperature is described as the most important one. It is reported that the extraction of certain compounds is rather dependent on pressurized water with different applied temperature. Thus, the stability and reduced solubilities of certain compounds at elevated temperatures are highlighted in this review. With some modifications, a scaled-up PHWE could extract a higher amount of desirable compounds from solid and powdered samples such as plant and food materials. The PHWE extracts from plants are rich in chemical compounds or metabolites which can be a potential lead for drug discovery or development of disease-resistant food crops. 相似文献
116.
Chunyan Cao Hyun Kyoung Yang Byung Kee Moon Jung Hyun Jeong Kwang Ho Kim 《Optics Communications》2011,284(23):5453-5456
By controlling the pH values of prepared solutions, the 10 mol% Ce3+, 5 mol% Tb3+ co-doped KGdF4 (synthesized with pH = 3) and the 10 mol% Ce3+, 5 mol% Tb3+ co-doped GdF3 (synthesized with pH = 1) submicro/nanocrystals have been synthesized based on a citric acid assisted hydrothermal method. For comparison, the samples synthesized by co-precipitation method (without hydrothermal treatment) with pH = 3 and 1 were also collected. The X-ray diffraction data illustrate that the hydrothermal treated KGdF4 sample crystallizes in the cubic phase and the GdF3 sample crystallizes in the orthorhombic phase. However, the samples synthesized by co-precipitation method with pH = 3 and 1 are both cubic phase KGdF4. The field emission scanning electron microscopy images suggest that the hydrothermal treated KGdF4 submicro/nanocrystals present spherical morphology and the GdF3 submicrocrystals are rhombic-shaped. And the photoluminescence excitation and emission spectra as well as the luminescent dynamic curves demonstrate the difference in optical properties of the two hydrothermal treated samples. 相似文献
117.
S. Sambasivam D. Paul Joseph Jung Hyun Jeong Byung Chun Choi Kwon Taek Lim Sang Su Kim Tae Kwon Song 《Journal of nanoparticle research》2011,13(10):4623-4630
Diluted magnetic semiconductor (DMS) nanoparticles of Sn1−x
Er
x
O2 (x = 0.0, 0.02, 0.04, and 0.1) were prepared by sol–gel method. The X-ray diffraction patterns showed SnO2 rutile structure for all samples with no impurity peaks. The decrease in crystallite size with Er concentration was confirmed
from TEM measurements (from 12 to 4 nm). The UV–Visible absorption spectra of Er-doped SnO2 nanoparticles showed blue shift in band gap compared to undoped SnO2. The electron spin resonance analysis of Er-doped SnO2 nanoparticles indicate Er3+ in a rutile lattice and also decrease in intensity with Er concentration above x = 0.02. Temperature-dependent magnetization studies and the inverse susceptibility curves indicated increased antiferromagnetic
interaction with Er concentration. 相似文献
118.
Min Hwan Lee Kyung Min Kim Seul Ji Song Sang Ho Rha Jun Yeong Seok Ji Sim Jung Gun Hwan Kim Jung Ho Yoon Cheol Seong Hwang 《Applied Physics A: Materials Science & Processing》2011,102(4):827-834
The bipolar resistive switching mechanisms of a p-type NiO film and n-type TiO2 film were examined using local probe-based measurements. Scanning probe-based current–voltage (I–V) sweeps and surface potential/current maps obtained after the application of dc bias suggested that resistive switching is
caused mainly by the surface redox reactions involving oxygen ions at the tip/oxide interface. This explanation can be applied
generally to both p-type and n-type conducting resistive switching films. The contribution of oxygen migration to resistive
switching was also observed indirectly, but only in the cases where the tip was in (quasi-) Ohmic contact with the oxide. 相似文献
119.
We prove a q-analogue of the Carter–Payne theorem in the case where the differences between the parts of the partitions are sufficiently large. We identify a layer of the Jantzen filtration which contains the image of these Carter–Payne homomorphisms and we show how these homomorphisms compose. 相似文献
120.
Younghun Kim Heechan Kim Dr. Jung Bae Son Dr. Michael Filatov Prof. Dr. Cheol Ho Choi Prof. Dr. Nam Ki Lee Prof. Dr. Dongwhan Lee 《Angewandte Chemie (International ed. in English)》2023,62(20):e202302107
Molecular emitters simultaneously generating light at different wavelengths have wide applications. With a small molecule, however, it is challenging to realize two independent radiative pathways. We invented the first examples of dual-emissive single-benzene fluorophores (SBFs). Two emissive tautomers are generated by synthetic modulation of the hydrogen bond acidity, which opens up pathways for excited-state proton transfer. White light is produced by a delicate balance between the energy and intensity of the emission from each tautomer. We show that the excited-state antiaromaticity of the benzene core itself dictates the proton movements driving the tautomer equilibrium. Using this simple benzene platform, a fluorinated SBF was synthesized with a record high solubility in perfluorocarbon solvents. White light-emitting devices and multicolor imaging of perfluorocarbon nanodroplets in live cells demonstrate the practical utility of these molecules. 相似文献