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581.
Lara FJ García-Campaña AM Gámiz-Gracia L Bosque-Sendra JM Alés-Barrero F 《Electrophoresis》2006,27(12):2348-2359
A CE instrument coupled with chemiluminescence (CL) detection was designed for the determination of promethazine hydrochloride (PTH) and promazine hydrochloride (PMH) in real samples. An important enhancement of the CL emission of luminol with potassium ferricyanide was observed in the presence of these phenothiazines; so this system was selected for their detection after CE separation. Parameters affecting the electrophoretic separation were optimized in a univariate way, while those affecting CL detection were optimized by means of a multivariate approach based on the use of experimental designs. Chemometrics was also employed for the study of the robustness of the factors influencing the postcolumn CL detection. The method allows the separation of the phenothiazines in less than 4 min, achieving LODs of 80 ng/mL for PMH and 334 ng/mL for PTH, using sample injection by gravity. Electrokinetic injection was used to obtain lower LODs for the determination of the compounds in biological samples. The applicability of the CE-CL method was illustrated in the determination of PTH in pharmaceutical formulations and in the analysis of PMH in human urine, using a previous SPE procedure, achieving an LOD of 1 ng/mL and recoveries higher than 85%. 相似文献
582.
Atkinson RC Gibson VC Long NJ West LJ White AJ 《Dalton transactions (Cambridge, England : 2003)》2006,(29):3597-3602
New unsymmetrical S/O 1,1'-disubstituted ferrocenediyl ethers and hydroxides have been synthesised. The coordination chemistry of 1-(methylsulfanyl)-1'-(methoxy)ferrocene has been investigated with palladium(II) and platinum(II) precursors. With palladium(II), a bis-mu-chloro-bridged dimeric complex was obtained with the ligand bound solely through the thioether donor group. With platinum(II), a bis-ligand trans-sulfur ligated complex was obtained and structurally characterised. 相似文献
583.
Lara P Paneque M Poveda ML Salazar V Santos LL Carmona E 《Journal of the American Chemical Society》2006,128(11):3512-3513
2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position. 相似文献
584.
585.
F. Buscemi P. Bordone A. Bertoni 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2012,66(12):1-11
We estimate the role of noise in the formation of entanglement and in the appearance of single- and two-electron interference in systems of coupled one-dimensional channels. Two cases are considered: a single-particle interferometer and a two-particle interferometer exploiting Coulomb interaction. In both of them, environmental noise yields a randomization of the carrier phases. Our results assess how the complementarity relation linking single-particle behavior to nonlocal quantities (such as entanglement and environment-induced decoherence) acts in electron interferometry. We show that in an experimental implementation of the setups examined, one- and two-electron detection probability at the output drains can be used to evaluate the decoherence and the degree of entanglement. 相似文献
586.
Alice Benzi Lara Bianchi Gianluca Giorgi Massimo Maccagno Giovanni Petrillo Domenico Spinelli Cinzia Tavani 《Molecules (Basel, Switzerland)》2022,27(10)
Nitrostilbenes characterized by two different or differently substituted aryl moieties can be obtained from the initial ring-opening of 3-nitrobenzo[b]thiophene with amines. Such versatile building blocks couple the well-recognized double electrophilic reactivity of the nitrovinyl moiety (addition to the double bond, followed by, e.g., intramolecular replacement of the nitro group) with the possibility to exploit a conjugated system of double bonds within an electrocyclization process. Herein, nitrostilbenes are reacted with different aromatic enols provided by a double (carbon and oxygen) nucleophilicity, leading to novel, interesting naphthodihydrofurans. From these, as a viable application, aromatization and electrocyclization lead in turn to valuable polycondensed, fully aromatic O-heterocycles. 相似文献
587.
Denis Ariel Avila-Salgado Arturo Jurez-Hernndez María Lara Banda Arnoldo Bedolla-Jacuinde Francisco V. Guerra 《Entropy (Basel, Switzerland)》2022,24(9)
In this research, a set of CuNiCrSiCoTi (H-0Nb), CuNiCrSiCoTiNb0.5 (H-0.5Nb) and CuNiCrSiCoTiNb1 (H-1Nb) high-entropy alloys (HEAs) were melted in a vacuum induction furnace. The effects of Nb additions on the microstructure, hardness, and wear behavior of these HEAs (compared with a CuBe commercial alloy) in the as-cast (AC) condition, and after solution (SHT) and aging (AT) heat treatments, were investigated using X-ray diffraction, optical microscopy, and electron microscopy. A ball-on-disc configuration tribometer was used to study wear behavior. XRD and SEM results showed that an increase in Nb additions and modification by heat treatment (HT) favored the formation of BCC and FCC crystal structures (CS), dendritic regions, and the precipitation of phases that promoted microstructure refinement during solidification. Increases in hardness of HEA systems were recorded after heat treatment and Nb additions. Maximum hardness values were recorded for the H-1Nb alloy with measured increases from 107.53 HRB (AC) to 112.98 HRB, and from 1104 HV to 1230 HV (aged for 60 min). However, the increase in hardness caused by Nb additions did not contribute to wear resistance response. This can be attributed to a high distribution of precipitated phases rich in high-hardness NiSiTi and CrSi. Finally, the H-0Nb alloy exhibited the best wear resistance behavior in the aged condition of 30 min, with a material loss of 0.92 mm3. 相似文献
588.
589.
Dr. Yen Vo Dr. Brett D. Schwartz Dr. Hideki Onagi Dr. Jas S. Ward Dr. Michael G. Gardiner Prof. Martin G. Banwell Dr. Keats Nelms Dr. Lara R. Malins 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(38):9830-9838
Although sulfated xylooligosaccharides are promising therapeutic leads for a multitude of afflictions, the structural complexity and heterogeneity of commercially deployed forms (e. g. Pentosan polysulfate 1 ) complicates their path to further clinical development. We describe herein the synthesis of the largest homogeneous persulfated xylooligomers prepared to date, comprising up to eight xylose residues, as standards for biological studies. Near quantitative sulfation was accomplished using a remarkably mild and operationally simple protocol which avoids the need for high temperatures and a large excess of the sulfating reagent. Moreover, the sulfated xylooligomer standards so obtained enabled definitive identification of a pyridinium contaminant in a sample of a commercially prepared Pentosan drug and provided significant insights into the conformational preferences of the constituent persulfated monosaccharide residues. As the spatial distribution of sulfates is a key determinant of the binding of sulfated oligosaccharides to endogenous targets, these findings have broad implications for the advancement of Pentosan-based treatments. 相似文献
590.
Dr. Lara Tejerina Jorge Labella Dr. Lara Martínez-Fernández Dr. Inés Corral Dr. M. Victoria Martínez-Díaz Prof. Tomás Torres 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(47):12058-12062
Subphthalocyanine (SubPc) chemistry has been limited so far by their high sensitivity toward strong nucleophiles. In particular, the substitution of the axial chlorine atom by a nucleophilic group in the case of less-reactive SubPcs, such as those bearing electron-withdrawing peripheral substituents, presents some limitations and requires harsh conditions. By taking advantage of the electrophilic character of DIBAL-H, it has been possible to prepare for the first time SubPc-hydride derivatives that exhibit high reactivity as hydroboration reagents of aldehydes. This hydride transfer requires using a typical carbonyl activator (trimethylsilyl triflate) and only one equivalent of aldehyde, affording SubPcs with an axial benzyloxy group in good yield. This transformation has proven to be a useful alternative method for the axial functionalisation of dodecafluoroSubPc, a paradigmatic SubPc derivative, by using electrophiles for the first time. Considering the increasing interest in SubPcs as electron-acceptor semiconductors with remarkable absorption in the visible range to replace fullerene in organic photovoltaic (OPV) devices, it is of the utmost importance to develop new synthetic methodologies for their axial functionalisation. 相似文献