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51.
We investigate the bifurcation phenomena and the change in phase space structure connected with the transition from regular to chaotic scattering in classical systems with unbounded dynamics. The regular systems discussed in this paper are integrable ones in the sense of Liouville, possessing a degenerated unstable periodic orbit at infinity. By means of a McGehee transformation the degeneracy can be removed and the usual Melnikov method is applied to predict homoclinic crossings of stable and unstable manifolds for the perturbed system. The chosen examples are the perturbed radial Kepler problem and two kinetically coupled Morse oscillators with different potential parameters which model the stretching dynamics in ABC molecules. The calculated subharmonic and homoclinic Melnikov functions can be used to prove the existence of chaotic scattering and of elliptic and hyperbolic periodic orbits, to calculate the width of the main stochastic layer and of the resonances, and to predict the range of initial conditions where singularities in the scattering function are found. In the second example the value of the perturbation parameter at which channel transitions set in is calculated. The theoretical results are supplemented by numerical experiments. 相似文献
52.
Determination of platinum and palladium in strongly acid solution by means of flow injection analysis 总被引:1,自引:0,他引:1
Microamounts of Pt(II/IV) (0.25–800 μg/ml) and Pd(II) (5–600 μg/ml) in> 0.5 M hydrochloric acid can readily be determined by means of a simple FIA method based on the selective reaction of tin(II)chloride with these metals. The FIA method has a high linear dynamic range, and is relatively free from interferences of many transition metals, with the exception of Au and Rh; small amounts of other PGMs can be tolerated. Determination of Pt on a hydrogenation catalyst by this method compares well with that found by flame atomic absorption spectroscopy. By monitoring at two or more wavelengths, Pt and Pd can be determined in mixtures by this means, to yield a simple, cost-effective FIA method for possible on-line determinations and quality control of, in particular, Pt containing acidic refinery and other process streams. 相似文献
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For the spectrophotometric characterization of redox reactions, a logarithmic transformation is proposed by which it is possible to analyse indirectly the functions E = f (pH) and E = f (C) derived from experimental data. Besides the mechanism of the reaction the equilibrium constant can also be calculated. The method is generally usable for equimolar redox systems and also for non-equimolar ones if a single equilibrium exists in the range under examination. References to the evaluation are given and the practicability is demonstrated with the system Fe(3+)/SO(2-)(3). 相似文献
58.
K. H. Koch K. Ohls E. Sebastiani und G. Riemer 《Fresenius' Journal of Analytical Chemistry》1970,249(5):307-312
Zusammenfassung Die direkte Bestimmung von Kobalt in unterschiedlichen Substanzen im Gehaltsbereich von 0,001 bis 5% ist nach einem einfachen Verfahren möglich, wenn die Komplexbildungsreaktion und der tatsächliche Störeffekt durch andere Elemente bekannt sind. Die für eine Bestimmung benötigte Zeit beträgt 25 min. Die relative Standardabweichung liegt zwischen 0,02–20%.
Direct photometric determination of cobalt in iron, steels, ores and slags using nitroso-R-salt
A simple procedure without any separation is described; the complex formation and the interfering effects of other elements are studied. This method is suitable for the accurate determination of 0.001 to 5% of cobalt in several materials. The time required for one determination is 25 min only. The coefficients of variation are within 0.02–20%.相似文献
59.
The synthesis and structure of an acetal protected 10-membered cyclic enediyne-1,2-diol rac-10 is reported. The conformational constrain of the unsaturated macrocycle by the acetal protection group prevents the thermal cyclization reaction of the endiyne during synthesis and purification. 相似文献
60.
Peter Xaver Iten Hana Mrki-Danzig Herbert Koch Conrad Hans Eugster 《Helvetica chimica acta》1984,67(2):550-569
Isolation and Structure Elucidation of Pteridines (Lumazines) from Russula sp. (Basidiomycetes) Extensive chromatogaphic separations and spectroscopic investigations have led to the isolation and identification of several water-soluble pteridines from Russula sp., the so-called russupteridines, namely: 1-(5-amino-2-6-dioxo-1,2,3,6-tetrahydeopyrimidin-4-yl)amino-1-deoxy-D -ribitol ( 1 ; a pro-lumazine; first identification in a basidiomycete(; l-deoxy-l-(6-methyl-2-4,7-trioxo-1,2,3,4,7,8-hexahydro-pteridin-8-yl)-D -ribitol ( 3 ) and l-deoxy-1-(2,4,7-trioxo-1,2,3,4,7,8-hexahydeopteridin-8-yl)-D -ribitol ( 4 ); both compounds found for the first time in higher fungi; they belong to the components with the strongest violet-blue fluorescence in Russula sp.; riboflavine ( 6 ; now recognized as an important yellow colorant in a great many of Russula sp.); russupteridine-yellow I (= l-(6-amino-7-(N-fromylimino)-2,4-dioxo-1,2,3,4,7,8-hexahydropteridin-8-yl)-1-deoxy-D -ribitol; 5 ; a component with very strong fluorescence; the first derivative of the novel 6,7-diamino-lamazine); russupteridine-yellow IV (= l-deoxy-1-)(2,6,8-trioxo-2,4,5,6,7,8-hexahydro-1H-imidazolo[4,5-g]pteridin-4-yl)-D -ribitol (7)). Two further yellow russupteridines (yellow II and Yellow V) with very strong fluorescence have been isolated and characterized. 相似文献