Unusual chemical behaviour of silylated 1,2-dithiins under Lewis acid conditions

Different silylated 1,2-dithiins, obtained through self-dimerization of the related α,β-ethylenic thioacylsilanes, in the presence of AlCl₃ show an unusual rearrangement leading in good yields to novel silyl-endodisulfide bicyclic systems.     

Rheology of concentrated suspensions containing mixtures of spheres and fibres

Optimising flow properties of concentrated suspensions is an important issue common for many industries. The rheology of concentrated suspensions has therefore been studied intensively both experimentally and theoretically. Most studies have focused on monodisperse and polydisperse suspensions of either spheres or fibres. In practice, most suspensions contain particles that are polydisperse both in size and shape. A mixing rule for such systems is expected to be a powerful tool for engineers and product designers. Therefore in this work, suspensions of spheres, fibres and mixtures thereof were characterised using rotational shear rheometry and in-line image analyses. Thereby, total solids volume concentration and fibre fraction was varied. Results from transient and steady-state shear rheometry are discussed with respect to concentration, fibre fraction, and shear induced microstructure. Experimentally obtained viscosity data were accurately fitted using the model proposed by Farris (T Soc Rheol 12:281, 1968) for mixtures of monodisperse non-interacting spheres of different sizes.Originally presented at the Annual European Rheology Conference 2003, AERC 2003     

Dynamical Renormalization Group for Mode-Coupling Field Theories with Solenoidal Constraint

Journal of Statistical Physics - A correction to this paper has been published: https://doi.org/10.1007/s10955-021-02770-w     

Universality properties of the quaternionic power series and entire functions

In this paper we establish the existence of “almost universal” quaternionic power series and entire functions. Denoting by B(0, 1) the open unit ball in , this means that there exists a quaternionic power series with radius of convergence 1 such that, denoting by the n‐th partial sum of S, for every , for every axially symmetric open subset Ω of containing K and every f slice regular on Ω, there exists a subsequence of the partial sums of S such that uniformly on K, as . The symbol denotes the set of axially symmetric compact sets in such that is connected for some . This is a slightly weaker property than the classical universal power series phenomenon obtained for analytic only on the interior of K and continuous on K. We also generalize a result originally proven by Birkhoff and finally we show that there exists an entire quaternionic function whose set of derivatives is dense in the class of entire quaternionic functions.     

Comparison of optical and mechanical measurements of second normal stress difference relaxation following step strain

Relaxation of the second normal stress difference (N ₂) following step strain of a concentrated monodisperse polystyrene solution has been studied using mechanical and optical rheometry. Measurements of normal thrust in a parallel plate geometry are corrected for strain inhomogeneity and combined with independent measurements of the first normal stress difference (N ₁) to determine N ₂. Optical experiments were performed using a novel configuration where flow birefringence data collected using multiple light paths within the shear plane are combined with the stress-optical law to determine all three independent stress components for shearing deformations. This technique eliminates end effects, and provides an opportunity to oversample the stress tensor and develop consistency checks of experimental data. N ₂ is found to be nonzero at all accessible times, and relaxes in roughly constant proportion to N ₁. This reflects nonaffine distribution of chain segments, even well within the regime of chain retraction at short times. Data collected with the two techniques are reasonably consistent with each other, and with results of previous studies, generally lying between the predictions of the Doi-Edwards model with and without the independent alignment approximation. The normal stress ratio –N ₂/N ₁ shows pronounced strain thinning in the nonlinear regime.     

Relaxation of bulk and interfacial energies

In this paper we obtain an integral representation for the relaxation inBV(Ω; ? ^p ) of the functional $$u \mapsto \int\limits_\Omega {f(x.\nabla u(x))dx + \int\limits_{\sum _{(u)} } {\varphi (x,[u](x),v(x))dH_{N - 1} (x)} }$$ with respect to theBV weak * convergence.