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11.
Michael Heck Klaus Blaum R. Burcu Cakirli Daniel Rodr??guez Lutz Schweikhard Stefan Stahl Marta Ubieto-D??az 《Hyperfine Interactions》2011,199(1-3):347-355
Dipolar and single-phase two-electrode quadrupolar detection schemes have been investigated at a Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) setup built for the KATRIN experiment at the Max-Planck-Institute for Nuclear Physics (MPIK) in Heidelberg. We present first experimental results of 7Li?+? signals from a cylindrical Penning trap configuration for both detection schemes. While the prominent signal of the conventional dipolar detection scheme marks the reduced cyclotron frequency, the main signal for the quadrupolar detection appears at the sum of the reduced cyclotron frequency and the magnetron frequency. For ideal trapping fields, this sum frequency equals the ion cyclotron frequency ?? c ?=?qB/(2??m). Sidebands due to the combined motions of the cyclotron mode and magnetron mode are observed by quadrupolar detection which allows the determination of the respective combinations of eigenfrequencies. 相似文献
12.
Çiğdem Hopa Mahir Alkan Canan Kazak N. Burcu Arslan Raif Kurtaran 《Journal of chemical crystallography》2010,40(2):160-164
Abstract
The dinuclear cadmium(II) complex with 2,6-bis(3,4,5-trimethyl-N-pyrazolyl)pyridine (btmpp) has been synthesized, and characterized by single crystal X-ray diffraction, IR, UV–Vis and TGA–DTA methods. Cd atoms are located in a distorted octahedral environment in the complex. The complex crystalizes in monoclinic space group C 2/c, with unit cell dimensions a = 20.5636(12) Å, b = 14.0167(13) Å, c = 15.6598(11) Å, β = 113.425(5)o, V = 4141.7(5) Å3. There are two intermolecular and a intramolecular hydrogen bonds interactions in crystal. 相似文献13.
An analog of the injective profile of a ring, with relative injectivity replaced by relative pure-injectivity, is investigated. Emphasis is placed on comparing and contrasting the properties of both profiles. In particular, the analog in this context of the notion of poor modules is considered and properties of pure-injectively poor modules are determined. While we do not know of any ring that does not have pure-injectively poor modules, their existence has not been determined in general. Rings having pure-injectively poor modules of various types are characterized. 相似文献
14.
This study presents the results of the methane adsorption properties of clinoptilolite tuff from Bigadic, Turkey and that of acid treated forms at 273 and 293 K up to 100 kPa using volumetric apparatus. In order to assess changes in structural and gas adsorption properties of clinoptilolite, zeolite sample was treated with acid solutions of varying concentrations (0.1, 0.5, 1.0 and 2.0 M) at 70 °C during 3 h. Structural and thermal characterization of natural and acid treated clinoptilolite samples were carried out using a combination of techniques such as X-ray diffraction, X-ray fluorescence, thermogravimetric, differential thermal analysis and nitrogen adsorption methods. At both temperatures, uptake of methane (CH4) increased in the following order: CLN < CLN-H2 < CLN-H1 < CLN-H05 < CLN-H01. CH4 adsorption capacities of the original and acid treated clinoptilolites were found in the range of 0.476–0.910 mmol/g and 0.398–0.691 mmol/g at 273 and 293 K, respectively. 相似文献
15.
Golan S Aytar BS Muller JP Kondo Y Lynn DM Abbott NL Talmon Y 《Langmuir : the ACS journal of surfaces and colloids》2011,27(11):6615-6621
Biological media affect the physicochemical properties of cationic lipid-DNA complexes (lipoplexes) and can influence their ability to transfect cells. To develop new lipids for efficient DNA delivery, the influence of serum-containing media on the structures and properties of the resulting lipoplexes must be understood. To date, however, a clear and general picture of how serum-containing media influences the structures of lipoplexes has not been established. Some studies suggest that serum can disintegrate lipoplexes formed using certain types of cationic lipids, resulting in the inhibition of transfection. Other studies have demonstrated that lipoplexes formulated from other lipids are stable in the presence of serum and are able to transfect cells efficiently. In this article, we describe the influence of serum-containing media on lipoplexes formed using the redox-active cationic lipid bis(n-ferrocenylundecyl)dimethylammonium bromide (BFDMA). This lipoplex system promotes markedly decreased levels of transgene expression in COS-7 cells as serum concentrations are increased from 0 to 2, 5, 10, and 50% (v/v). To understand the cause of this decrease in transfection efficiency, we used cryogenic transmission electron microscopy (cryo-TEM) and measurements of zeta potential to characterize lipoplexes in cell culture media supplemented with 0, 2, 5, 10, and 50% serum. Cryo-TEM revealed that in serum-free media BFDMA lipoplexes form onionlike, multilamellar nanostructures. However, the presence of serum in the media caused disassociation of the intact multilamellar lipoplexes. At low serum concentrations (2 and 5%), DNA threads appeared to separate from the complex, leaving the nanostructure of the lipoplexes disrupted. At higher serum concentration (10%), disassociation increased and bundles of multilamellae were discharged from the main multilamellar complex. In contrast, lipoplexes characterized in serum-free aqueous salt (Li(2)SO(4)) medium and in OptiMEM cell culture medium (no serum) did not exhibit significant structural changes. The zeta potentials of lipoplexes in serum-free media (salt medium and cell culture medium) were similar (e.g., approximately -35 mV). Interestingly, the presence of serum caused the zeta potentials to become less negative (about -20 mV in OptiMEM and -10 mV in Li(2)SO(4)), even though serum contains negatively charged entities that have been demonstrated to lead to more negative zeta potentials in other lipoplex systems. The combined measurements of zeta potential and cryo-TEM are consistent with the proposition that DNA threads separate from the lipoplex in the presence of serum, resulting in a decrease in the net negative charge of the surface of the lipoplex. 相似文献
16.
A method combining immunomagnetic separation (IMS) and surface-enhanced Raman scattering (SERS) was developed to enumerate Escherichia coli (E. coli). Gold-coated magnetic spherical nanoparticles were prepared by immobilizing biotin-labeled anti-E. coli antibodies onto avidin-coated magnetic nanoparticles and used in the separation and concentration of the E. coli cells. Raman labels have been constructed using rod shaped gold nanoparticles coated with 5,5-dithiobis-(2-nitrobenzoic acid) (DTNB) and subsequently with a molecular recognizer. Then DTNB-labeled gold nanorods were interacted with gold-coated magnetic spherical nanoparticle-antibody-E. coli complex. The capture efficiency and calibration graphs were obtained and examined in different E. coli concentrations (10(1)-10(7) cfu mL(-1)). The correlation between the concentration of bacteria and SERS signal was found to be linear within the range of 10(1)-10(4) cfu mL(-1) (R(2) = 0.992). The limit of detection (LOD) and limit of quantification (LOQ) values of the developed method were found to be 8 and 24 cfu mL(-1), respectively. The selectivity of the developed immunoassay was examined with Enterobacter aerogenes, Enterobacter dissolvens, and Salmonella enteriditis which did not produce any significant response. The ability of the immunoassay to detect E. coli in real water samples was also investigated and the results were compared with the experimental results from plate-counting methods. There was no significant difference between the methods that were compared (p > 0.05). This method is rapid and sensitive to target organisms with a total analysis time of less than 70 min. 相似文献
17.
A. Dilek Azaz Selma Celen Hilmi Namli Onur Turhan Raif Kurtaran Canan Kazak N. Burcu Arslan 《Transition Metal Chemistry》2007,32(7):884-888
A complex of NiII with 2,6-diacetylpyridinedihydrazone (L) towards nickel(II) has been prepared and characterized by means of elemental analyses,
IR, electronic spectra and single crystal X-ray analyses. [NiL2](NO3) was crystallized in the tetragonal space group P-4 21 c. The complex exhibits the expected coordination sphere with six
nitrogen atoms coordinated to the central NiII with a deformation from pseudo-octahedral geometry. Antimicrobial activities of the ligand and its complex were investigated. 相似文献
18.
We consider a multi-product two-stage production/distribution system design problem (PDSD) where a fixed number of capacitated distribution centers are to be located with respect to capacitated suppliers (plants) and retail locations (customers) while minimizing the total costs in the system. We present a mixed-integer problem formulation that facilitates the development of efficient heuristic procedures. We provide meta-heuristic procedures, including a population-based scatter search with path relinking and trajectory-based local and tabu search, for the solution of the problem. We also develop efficient construction heuristics and transshipment heuristics that are incorporated into the heuristic procedures for the solution of subproblems. We present extensive computational results that show the high performance of the solution approaches. We obtain smaller than 1.0% average optimality gaps with acceptable runtimes, even for relatively large problems. The computational results also demonstrate the effectiveness of the construction and transshipment heuristics that impact the solution quality and overall runtimes. 相似文献
19.
Burcu Krmz Philippe Colomban Monique Blanc 《Journal of Raman spectroscopy : JRS》2010,41(10):1240-1247
A selection of 15 painted enamels, most of which belong to Limoges productions, from 1500 to 1900 A.D. , has been studied on‐site in the storage rooms of musée des Arts décoratifs in Paris. The Raman signatures of the transparent and/or opacified glass matrix are discussed and compared with those which were previously recorded on glazed pottery, enamelled and stained glasses as well as Chinese cloisonné enamels. Analysed enamels mostly belong to soda‐lime‐based glass. Three types of compositions such as soda‐lime (fifteenth to sixteenth century), soda‐rich (fifteenth, sixteenth/nineteenth centuries) and lead‐potash‐lime (sixteenth and nineteenth centuries) are identified on the basis of the Raman signature of the glaze according to the wavenumber maxima of the Si O stretching and bending multiplets. The pigment signatures are similar to those recorded on ceramic glazes and glass enamels, which proves the similarity of the technologies. Cassiterite as an opacifier and hematite red and Naples yellow pigment variations give characteristic Raman signatures. The presence of lead arsenate as a pigment opacifier in nineteenth‐century samples is confirmed. Attempts are made to establish tools for the differentiation between genuine artefacts and nineteenth‐century restoration or fakes. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
20.
Burcu Baran 《Archiv der Mathematik》2010,94(1):11-18
Let p be a prime number and G be a finite commutative group such that p
2 does not divide the order of G. In this note we prove that for every finite module M over the group ring Z
p
[G], the inequality #M £ #Zp[G]/FitZp[G](M){\#M\,\leq\,\#{\bf Z}_{p}[G]/{{\rm Fit}}_{{\bf Z}_{p}[G]}(M)} holds. Here, FitZp[G](M){\rm Fit}_{{\bf Z}_{p}[G]}(M) is the Z
p
[G]-Fitting ideal of M. 相似文献