Enantiospecific approach toward pentalenolactone

[reaction: see text] The enantiospecific assembly of the pentalenolactones' carbon skeleton was achieved in 17 steps and 16% overall yield from methyl alpha-D-glucopyranoside. The synthetic strategy relies on two highly efficient key steps: an exo-diastereoselective Diels-Alder reaction and a nonsymmetric ozonolysis.     

Cyclodextrin-based self-assembled nanotubes at the water/air interface

Native alpha-cyclodextrin (alpha-CD) is found to spontaneously form films at aqueous solution/air interfaces. Shape-response measurements to volume perturbations on drops hanging from a capillary indicate that temperature and sodium dodecyl sulfate (SDS) concentration strongly modify the viscoelastic properties of such films. By using isothermal titration calorimetry (ITC), Brewster angle microscopy (BAM), atomic force microscopy (AFM), and molecular dynamics (MD) simulations, it is shown that the films consist of self-assembled nanotubes whose building blocks are cyclodextrin dimers (alpha-CD2) and alpha-CD2-SDS1 complexes.     

Contractive Approximations in Risk-Sensitive Average Semi-Markov Decision Chains on a Finite State Space

Journal of Optimization Theory and Applications - This work concerns with semi-Markov decision chains evolving on a finite state space. The controller has a positive and constant risk sensitivity...     

Micelles and reverse micelles in the nickel bis(2-ethylhexyl) sulfosuccinate/water/isooctane microemulsion

The ternary system Ni(2+)(AOT)(2) (nickel 2-bis[2-ethylhexyl] sulfosuccinate)/water/isooctane presents w/o and o/w microemulsions with a Winsor progression (2Phi-3Phi-2Phi), without the addition of salt; the "fish diagram" was obtained for alpha=0.5 and gamma=0.02-0.22. Using static and dynamic light scattering the micellar size, the ratio of water to surfactant, and the density of micelles for this system were estimated. In addition, the mean interfacial curvature as a function of temperature was obtained.     

Fragmentations induced by ion-atom reactions

Fragmentation of electron-impact-generated organic molecular cations, submitted to low-energy collisions with hydrogen in a MS/MS/MS multiquadrupole mass spectrometer, was promoted or significantly increased in the presence of atomic hydrogen generated from a microwave discharge. Loss of hydrogen alpha to a heteroatom and bond cleavage alpha to a carbonyl group are the major H-induced fragmentation pathways.     

Translation planes admitting many homologies

The translation planes with spreads inPG(3,2 ^r ) that admit >2 ^r +1 axes (coaxes) of homologies of orderu1 are classified.Partially supported by FONDECYT Project No. 890-1061     

Denumerable controlled Markov chains with strong average optimality criterion: Bounded & unbounded costs

This paper studies discrete-time nonlinear controlled stochastic systems, modeled by controlled Markov chains (CMC) with denumerable state space and compact action space, and with an infinite planning horizon. Recently, there has been a renewed interest in CMC with a long-run, expected average cost (AC) optimality criterion. A classical approach to study average optimality consists in formulating the AC case as a limit of the discounted cost (DC) case, as the discount factor increases to 1, i.e., as the discounting effectvanishes. This approach has been rekindled in recent years, with the introduction by Sennott and others of conditions under which AC optimal stationary policies are shown to exist. However, AC optimality is a rather underselective criterion, which completely neglects the finite-time evolution of the controlled process. Our main interest in this paper is to study the relation between the notions of AC optimality andstrong average cost (SAC) optimality. The latter criterion is introduced to asses the performance of a policy over long but finite horizons, as well as in the long-run average sense. We show that for bounded one-stage cost functions, Sennott's conditions are sufficient to guarantee thatevery AC optimal policy is also SAC optimal. On the other hand, a detailed counterexample is given that shows that the latter result does not extend to the case of unbounded cost functions. In this counterexample, Sennott's conditions are verified and a policy is exhibited that is both average and Blackwell optimal and satisfies the average cost inequality.