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91.
92.
Intramolecular Metalloamination of N,N‐Dimethylhydrazinoalkenes: A Versatile Method to Access Functionalized Piperidines and Pyrrolidines
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Bryce Sunsdahl Adrian R. Smith Prof. Dr. Tom Livinghouse 《Angewandte Chemie (International ed. in English)》2014,53(52):14352-14356
Highly diastereoselective metalloamination/cyclization reactions of zinc(II) hydrazides obtained through reaction of diethylzinc with N,N‐dimethylhydrazinoalkenes are described. The resulting organozinc intermediates undergo facile allylation and acylation, in situ, to provide the corresponding functionalized piperidines and pyrrolidines. 相似文献
93.
M Pattabiraman G Rangarajan Kwang-Yong Choi P Lemmens G Guentherodt G Balakrishnan DMcK Paul MR Lees 《Pramana》2002,58(5-6):1013-1017
We report polarized Raman scattering in single crystals of Nd0.7Sr0.3MnO3. The temperature dependence of the MnO6 octahedral bending and stretching modes observed in the XX spectra points to the existence of local lattice distortions,
possibly polarons. The XY spectra have been analyzed using a collision-dominated model, which allows the extraction of the
carrier scattering rate. 相似文献
94.
Natural-abundance (43)Ca solid-state NMR spectroscopy at 21.1 T and gauge-including projector-augmented-wave (GIPAW) DFT calculations are developed as tools to provide insight into calcium binding environments, with special emphasis on the calcium chemical shift (CS) tensor. The first complete analysis of a (43)Ca solid-state NMR spectrum, including the relative orientation of the CS and electric field gradient (EFG) tensors, is reported for calcite. GIPAW calculations of the (43)Ca CS and EFG tensors for a series of small molecules are shown to reproduce experimental trends; for example, the trend in available solid-state chemical shifts is reproduced with a correlation coefficient of 0.983. The results strongly suggest the utility of the calcium CS tensor as a novel probe of calcium binding environments in a range of calcium-containing materials. For example, for three polymorphs of CaCO3 the CS tensor span ranges from 8 to 70 ppm and the symmetry around calcium is manifested differently in the CS tensor as compared with the EFG tensor. The advantages of characterizing the CS tensor are particularly evident in very high magnetic fields where the effect of calcium CS anisotropy is augmented in hertz while the effect of second-order quadrupolar broadening is often obscured for (43)Ca because of its small quadrupole moment. Finally, as an application of the combined experimental-theoretical approach, the solid-state structure of the vaterite polymorph of calcium carbonate is probed and we conclude that the hexagonal P6(3)/mmc space group provides a better representation of the structure than does the orthorhombic Pbnm space group, thereby demonstrating the utility of (43)Ca solid-state NMR as a complementary tool to X-ray crystallographic methods. 相似文献
95.
Mansell D Rattray N Etchells LL Schwalbe CH Blake AJ Bichenkova EV Bryce RA Barker CJ Díaz A Kremer C Freeman S 《Chemical communications (Cambridge, England)》2008,(41):5161-5163
Natural myo-inositol phosphate antioxidants containing the 1,2,3-trisphosphate motif bind Fe(3+) in the unstable penta-axial conformation. 相似文献
96.
97.
Unprecedented stability has been observed in terminal aryl hexatriyne and terminal aryl octatetrayne derivatives by judicious choice of a bulky, nonplanar headgroup [viz., 4-(3,6-di- tert-butyl- N-carbazolyl)phenyl] which hinders topochemical intermolecular interactions in the crystal lattice. 相似文献
98.
A series of alkaline earth chloride hydrates has been studied by solid-state (35/37)Cl NMR spectroscopy in order to characterize the chlorine electric field gradient (EFG) and chemical shift (CS) tensors and to relate these observables to the structure around the chloride ions. Chlorine-35/37 NMR spectra of solid powdered samples of pseudopolymorphs (hydrates) of magnesium chloride (MgCl(2).6H(2)O), calcium chloride (CaCl(2).2H(2)O), strontium chloride (SrCl(2), SrCl(2).2H(2)O, and SrCl(2).6H(2)O), and barium chloride (BaCl(2).2H(2)O) have been acquired under stationary and magic-angle spinning conditions in magnetic fields of 11.75 and 21.1 T. Powder X-ray diffraction was used as an additional tool to confirm the purity and identity of the samples. Chlorine-35 quadrupolar coupling constants (C(Q)) range from essentially zero in cubic anhydrous SrCl(2) to 4.26+/-0.03 MHz in calcium chloride dihydrate. CS tensor spans, Omega, are between 40 and 72 ppm, for example, Omega= 45+/-20 ppm for SrCl(2).6H(2)O. Plane wave-pseudopotential density functional theory, as implemented in the CASTEP program, was employed to model the extended solid lattices of these materials for the calculation of their chlorine EFG and nuclear magnetic shielding tensors, and allowed for the assignment of the two-site chlorine NMR spectra of barium chloride dihydrate. This work builds upon our current understanding of the relationship between chlorine NMR interaction tensors and the local molecular and electronic structure, and highlights the particular sensitivity of quadrupolar nucleus solid-state NMR spectroscopy to the differences between various pseudopolymorphic structures in the case of strontium chloride. 相似文献
99.
Coupled cluster calculations provide a one‐to‐one mapping between calculated and observed transition energies in the electronic absorption spectrum of zinc phthalocyanine
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Andrew J. Wallace Bryce E. Williamson Deborah L. Crittenden 《International journal of quantum chemistry》2017,117(8)
All transitions in the experimentally designated and numbered Q, B, and N bands (< 4.8 eV) of the electronic absorption spectrum of zinc phthalocyanine (ZnPc) are assigned on the basis of one‐to‐one agreement between calculated and experimentally observed transition energies and oscillator strengths. Each band in this range of the spectrum represents a ligand‐based transition that originates from a combination of occupied orbitals and terminates in the lowest unoccupied molecular orbital (LUMO, ). Transition energies in the L and C regions (4.8–6.5 eV) are harder to capture quantitatively, due to the partial Rydberg character of some of the excited states, and so are tentatively assigned here. Most transitions in this range correspond to excitations from the HOMO or lower‐energy orbitals to π orbitals above the LUMO. 相似文献
100.
Dr. Luke J. O'Driscoll Dr. Xintai Wang Michael Jay Dr. Andrei S. Batsanov Dr. Hatef Sadeghi Prof. Colin J. Lambert Dr. Benjamin J. Robinson Prof. Martin R. Bryce 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(2):892-899
As the field of molecular-scale electronics matures and the prospect of devices incorporating molecular wires becomes more feasible, it is necessary to progress from the simple anchor groups used in fundamental conductance studies to more elaborate anchors designed with device stability in mind. This study presents a series of oligo(phenylene-ethynylene) wires with one tetrapodal anchor and a phenyl or pyridyl head group. The new anchors are designed to bind strongly to gold surfaces without disrupting the conductance pathway of the wires. Conductive probe atomic force microscopy (cAFM) was used to determine the conductance of self-assembled monolayers (SAMs) of the wires in Au–SAM–Pt and Au–SAM–graphene junctions, from which the conductance per molecule was derived. For tolane-type wires, mean conductances per molecule of up to 10−4.37 G0 (Pt) and 10−3.78 G0 (graphene) were measured, despite limited electronic coupling to the Au electrode, demonstrating the potential of this approach. Computational studies of the surface binding geometry and transport properties rationalise and support the experimental results. 相似文献