On the role of the interface charge in non-ideal metal–semiconductor contacts

The bias dependent interface charge is considered as the origin of the observed non-ideality in current–voltage and capacitance–voltage characteristics. Using the simplified model for the interface electronic structure based on defects interacting with the continuum of interface states, the microscopic origin of empirical parameters describing the bias dependent interface charge function is investigated. The results show that in non-ideal metal–semiconductor contacts the interface charge function depends on the interface disorder parameter, density of defects, barrier pinning parameter and the effective gap center. The theoretical predictions are tested against several sets of published experimental data on bias dependent ideality factor and excess capacitance in various metal–semicoductor systems.     

Tip-enhanced Raman scattering: Influence of the tip-surface geometry on optical resonance and enhancement

The tip-sample distance (z) dependence of tip-enhanced Raman scattering (TERS) has been investigated. The intensities of both, the Raman lines and the broad TERS background, exhibit strong decays with increasing z, which are nearly complete within 10 nm withdrawal of the STM tip in z direction. Interestingly, the maximum of the broad Lorentzian-shaped TER background is substantially blue shifted in energy with z. This effect is ascribed to a corresponding blue shift of the energies of localized plasmon modes upon tip retraction. Both experimental results fit very well data of a simple theoretical near-field model.     

High temperature Mars atmosphere. Part I: transport cross sections

In the perspective of higher approximations of the Chapman-Enskog theory for transport property calculations, existing transport cross sections databases for interactions involving Earth atmosphere species have been updated and extended to Mars atmosphere components, proposing a phenomenological approach for the derivation of the relevant elastic collision integrals in neutral-neutral and neutral-ion interactions. Inelastic collision integrals terms, due to resonant charge exchange channels, have been considered and the asymptotic approach extended to the estimation of charge transfer cross section of multiple resonant processes. Electronic supplementary material  Supplementary Online Material     

Influence of steady background gradients on the accuracy of molecular diffusion anisotropy measurements

Spatial susceptibility variations of body components lead to local gradients of the static magnetic field. Effects of such background gradients on fractional diffusion anisotropy (FA) measurements on whole-body magnetic resonance units operating at 1.5, 3.0 and 7.0 T were analyzed theoretically and experimentally. Analytical expressions were derived for the cases of diffusion occurring in isotropic media and in tissues with cylindrical symmetry (e.g., white matter tracts or skeletal musculature). Typical magnitudes of background gradient strengths were estimated from in vivo and in vitro measurements with B0 field mapping sequences. Additionally, numerical simulations of magnetic field distributions and resulting field gradients were performed considering tissue-air interfaces in simplified geometrical arrangements. For media with isotropic diffusion, both measurements and analytical calculations showed increasing FA inaccuracy with stronger coupling between diffusion-encoding and background gradients. For cylindrical symmetry, FA values were estimated for a standard diffusion tensor imaging protocol in a realistic scenario. At 1 mm distance from a water-air interface, susceptibility-related background gradients amount to approximately 9 mT/m at 7 T and lead to a relative error of the measured FA of up to 48%. The error in the anisotropy assessment rises considerably with increasing field strength and must be taken into account especially for experimental and clinical studies on modern high-field systems.     

Exchange interaction between single magnetic adatoms

The magnetic coupling between single Co atoms adsorbed on a copper surface is determined by probing the Kondo resonance using low-temperature scanning tunneling spectroscopy. The Kondo resonance, which is due to magnetic correlation effects between the spin of a magnetic adatom and the conduction electrons of the substrate, is modified in a characteristic way by the coupling of the neighboring adatom spins. Increasing the interatomic distance of a Cobalt dimer from 2.56 to 8.1 A we follow the oscillatory transition from ferromagnetic to antiferromagnetic coupling. Adding a third atom to the antiferromagnetically coupled dimer results in the formation of a collective correlated state.     

Use of apodization in quantitative spectroscopy

Apodization, which is a tool frequently used for cosmetic representation and efficient modeling of a spectrum, is now also adopted in techniques for the quantitative retrieval of parameters from observed spectra. Whether apodization can help in quantitative spectroscopy is the subject of debate in the literature. We find that, when the considered spectral range is wide enough to accurately model the instrument line shape, the same results can be obtained with and without apodization of the spectrum. However, when a truncation error is introduced by the limited extension of the modeled spectral interval, apodization can efficiently reduce this error. Therefore it is possible to save computing time by using apodization.     

Step-selective measurement by grating-based lateral shearing interferometry for segmented telescopes

We present an original step-selective mode which allows to measure only the steps and not the slowly varying aberrations of a wave front. This mode can be implemented when measuring segmented wave front by a diffraction-grating-based lateral shearing interferometer. This set-up rests on the different chromatic response of these interferometers depending on the rate of change of the impinging wave front: for smooth defects, the response is classically achromatic whereas it is chromatic for a step variation, which was to our knowledge overlooked. The interest of this mode for astronomical measurements is highlighted. First we present theoretical considerations to show how this mode of measure is possible; then a numerical simulation illustrates them.     

Quantum Mechanics and Imprecise Probability

An extension of the Born rule, the quantum typicality rule, has recently been proposed [B. Galvan in Found. Phys. 37:1540–1562 (2007)]. Roughly speaking, this rule states that if the wave function of a particle is split into non-overlapping wave packets, the particle stays approximately inside the support of one of the wave packets, without jumping to the others. In this paper a formal definition of this rule is given in terms of imprecise probability. An imprecise probability space is a measurable space endowed with a set of probability measures ℘. The quantum formalism and the quantum typicality rule allow us to define a set of probabilities on (X ^T ,ℱ), where X is the configuration space of a quantum system, T is a time interval and ℱ is the σ-algebra generated by the cylinder sets. Thus, it is proposed that a quantum system can be represented as the imprecise stochastic process , which is a canonical stochastic process in which the single probability measure is replaced by a set of measures. It is argued that this mathematical model, when used to represent macroscopic systems, has sufficient predictive power to explain both the results of the statistical experiments and the quasi-classical structure of the macroscopic evolution.     

Algebraic study of chiral anomalies

The algebraic structure of chiral anomalies is made globally valid on non-trivial bundles by the introduction of a fixed background connection. Some of the techniques used in the study of the anomaly are improved or generalized, including a systematic way of generating towers of descent equations.This work was supported in part by the Director, Office of Energy Research, Office of High Energy and Nuclear Physics, Division of High Energy Physics of the U.S. Department of Energy under contract DE-AC03-76SF00098 and in part by the National Science Foundation under research grant PHY81-18547