A novel femtosecond-laser formation of CdS nanocrystallites in zirconia matrices

A novel method for direct laser writing of two-dimensional cadmium sulfide (CdS) semiconductor nanoparticle microstructures is reported. A two photon or a higher-order multiphoton absorption process, originating from femtosecond laser pulses, was used to decompose CdS precursors dispersed in a zirconia thin film previously dip-coated on a glass substrate. The kinetics of nanoparticle formation as a function of laser power were monitored in situ by photoluminescence spectroscopy. Raman spectroscopy was also performed to characterize the structural changes of the zirconia matrix under irradiation and to verify the formation of CdS nanoparticles. Results show that CdS nanoparticles were formed by two-photon absorption (TPA) with or without the help of an additional carbazole photoinitiator.     

Tip-enhanced Raman spectroscopy and microscopy on single dye molecules with 15 nm resolution

Our recently developed approach of UHV-tip-enhanced Raman spectroscopy permits us to acquire Raman spectra of a few single brilliant cresyl blue (BCB) molecules and even a single one adsorbed on a Au(111) surface. This is substantiated by simultaneously recorded STM images. Furthermore, because of the reduced photobleaching in UHV, the time frame for spectral acquisition is sufficiently extended to allow tip-enhanced Raman imaging of a single BCB molecule with a lateral resolution of 15 nm.     

A Combined Immunofluorescence and Fluorescent Viability Cocktail Staining Procedure for Rapid Microscopic Detection and Enumeration of Live Legionella pneumophila

Journal of Fluorescence - This report describes a combined immunofluorescence and fluorescence viability stain applied as one staining solution for rapid detection of live Legionella...     

Arbres minimaux d'un graphe preordonne

We study the minimal spanning trees of a connected graph G = (X,U) where U is partially preordered (or quasi-ordered). We characterize several kinds of optimal spanning trees and give conditions for existence of strongly optimal trees. Generalizations to bases of matroids (binary matroïds in part 2) are immediate. Sone of our results are given in terms of Krugdahl's dependence graphs. They imply previous results of Rosenstiehl and Gale in the case of linear orders or preorders.     

Conformal regularization of the Kepler Problem

The manifoldM of null rays through the origin of ^2,n+1 is diffeomorphic toS ¹×S ⁿ , and it is a homogeneous space of SO(2,n+1). This group therefore acts onT*M, which we show to be the generating manifold of the extended phase space of the regularized Kepler Problem. A local canonical chart inT*M is found such that the restriction to the subbundle of the null nonvanishing covectors is given byp ₀+H(q,p)=0, whereH(q,p) is the Hamiltonian of the Kepler Problem. By means of this construction, we get some results that clarify and complete the previous approaches to the problem.     

On the role of the interface charge in non-ideal metal–semiconductor contacts

The bias dependent interface charge is considered as the origin of the observed non-ideality in current–voltage and capacitance–voltage characteristics. Using the simplified model for the interface electronic structure based on defects interacting with the continuum of interface states, the microscopic origin of empirical parameters describing the bias dependent interface charge function is investigated. The results show that in non-ideal metal–semiconductor contacts the interface charge function depends on the interface disorder parameter, density of defects, barrier pinning parameter and the effective gap center. The theoretical predictions are tested against several sets of published experimental data on bias dependent ideality factor and excess capacitance in various metal–semicoductor systems.     

Quantum Mechanics and Imprecise Probability

An extension of the Born rule, the quantum typicality rule, has recently been proposed [B. Galvan in Found. Phys. 37:1540–1562 (2007)]. Roughly speaking, this rule states that if the wave function of a particle is split into non-overlapping wave packets, the particle stays approximately inside the support of one of the wave packets, without jumping to the others. In this paper a formal definition of this rule is given in terms of imprecise probability. An imprecise probability space is a measurable space endowed with a set of probability measures ℘. The quantum formalism and the quantum typicality rule allow us to define a set of probabilities on (X ^T ,ℱ), where X is the configuration space of a quantum system, T is a time interval and ℱ is the σ-algebra generated by the cylinder sets. Thus, it is proposed that a quantum system can be represented as the imprecise stochastic process , which is a canonical stochastic process in which the single probability measure is replaced by a set of measures. It is argued that this mathematical model, when used to represent macroscopic systems, has sufficient predictive power to explain both the results of the statistical experiments and the quasi-classical structure of the macroscopic evolution.     

Exchange interaction between single magnetic adatoms

The magnetic coupling between single Co atoms adsorbed on a copper surface is determined by probing the Kondo resonance using low-temperature scanning tunneling spectroscopy. The Kondo resonance, which is due to magnetic correlation effects between the spin of a magnetic adatom and the conduction electrons of the substrate, is modified in a characteristic way by the coupling of the neighboring adatom spins. Increasing the interatomic distance of a Cobalt dimer from 2.56 to 8.1 A we follow the oscillatory transition from ferromagnetic to antiferromagnetic coupling. Adding a third atom to the antiferromagnetically coupled dimer results in the formation of a collective correlated state.     

Accurate, high-order representation of complex three-dimensional surfaces via Fourier continuation analysis

We present a new method for construction of high-order parametrizations of surfaces: starting from point clouds, the method we propose can be used to produce full surface parametrizations (by sets of local charts, each one representing a large surface patch – which, typically, contains thousands of the points in the original point-cloud) for complex surfaces of scientific and engineering relevance. The proposed approach accurately renders both smooth and non-smooth portions of a surface: it yields super-algebraically convergent Fourier series approximations to a given surface up to and including all points of geometric singularity, such as corners, edges, conical points, etc. In view of their C^∞ smoothness (except at true geometric singularities) and their properties of high-order approximation, the surfaces produced by this method are suitable for use in conjunction with high-order numerical methods for boundary value problems in domains with complex boundaries, including PDE solvers, integral equation solvers, etc. Our approach is based on a very simple concept: use of Fourier analysis to continue smooth portions of a piecewise smooth function into new functions which, defined on larger domains, are both smooth and periodic. The “continuation functions” arising from a function f converge super-algebraically to f in its domain of definition as discretizations are refined. We demonstrate the capabilities of the proposed approach for a number of surfaces of engineering relevance.