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1.
2.
G. H. Lushington P. J. Bruna F. Grein 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1996,36(3-4):301-309
Electron-spin magnetic moments, in the form ofg-shifts, have been computed at the ROHF level for theX 2∑+ states of LiH+, BeH2+, LiH?, BeH and BH+. A perturbative approach, complete to second-order in appropriate Breit-Pauli operators, has been used. Retention of two-centre integrals has proven vital. First-order terms are important, especially in describing the negativeg ∥ shifts observed experimentally in2∑+ molecules. The relativistic mass correction dominates in first-order, except for LiH? where the two-electron spin-Zeeman gauge correction supersedes. Second-order terms contribute negatively, and only to the Δg ⊥ component. Along the isoelectronic series LiH? → BeH → BH+, the magnitude of Δg ⊥ increases due to the dependence of spin-orbit coupling on nuclear charge. The relation ofg-shifts to electronic structure and bonding is explored. 相似文献
3.
Federica Mastroiacovo Francesca Biagioni Paola Lenzi Gloria Lazzeri Michela Ferrucci Stefano Puglisi-Allegra Alessandro Frati Ferdinando Nicoletti Francesco Fornai 《Molecules (Basel, Switzerland)》2022,27(10)
The brain area which surrounds the frankly ischemic region is named the area penumbra. In this area, most cells are spared although their oxidative metabolism is impaired. area penumbra is routinely detected by immunostaining of a molecule named Heat Shock Protein 70 (HSP70). Within the area penumbra, autophagy-related proteins also increase. Therefore, in the present study, the autophagy-related microtubule-associated protein I/II-Light Chain 3 (LC3) was investigated within the area penumbra along with HSP70. In C57 black mice, ischemia was induced by permanent occlusion of the distal part of the middle cerebral artery. Immunofluorescence and electron microscopy show that LC3 and HSP70 are overexpressed and co-localize within the area penumbra in the same cells and within similar subcellular compartments. In the area penumbra, marked loss of co-localization of HSP70 and LC3-positive autophagy vacuoles, with lysosomal-associated membrane protein 1 (LAMP1) or cathepsin-D-positive lysosome vacuoles occurs. This study indicates that, within the area penumbra, a failure of autophagolysosomes depends on defective compartmentalization of LC3, LAMP1 and cathepsin-D and a defect in merging between autophagosomes and lysosomes. Such a deleterious effect is likely to induce a depletion of autophagolysosomes and cell clearing systems, which needs to be rescued in the process of improving neuronal survival. 相似文献
4.
D. Hojman M. A. Cardona D. Bazzacco N. Blasi J. Davidson M. Davidson M. E. Debray A. J. Kreiner S. M. Lenzi G. Lo Bianco D. R. Napoli C. Rossi Alvarez 《The European Physical Journal A - Hadrons and Nuclei》2004,21(3):383-390
High-spin states in 163,164Ho were investigated by means of in-beam
-ray spectroscopy techniques using the multidetector array GASP. Excited states in 163,164Ho were populated predominantly through the incomplete-fusion mechanism in the 160Gd (11B
reaction at a beam energy of 61 MeV. Known rotational bands in 163
Ho have been extended to higher spins and a three-quasiparticle band has been observed in this nucleus. Rotational bands have been identified in 164Ho and their configurations have been discussed. Empirical Gallagher-Moszkowski (GM) splitting energies were extracted from the
and
GM doublets. Alignments, band crossing frequencies, and electromagnetic properties have been analyzed in the framework of the cranking model.Received: 13 February 2004, Revised: 18 March 2004, Published online: 14 September 2004PACS:
21.10.Re Collective levels - 21.60.Ev Collective models - 23.20.Lv
transitions and level energies - 27.70. + q
相似文献
5.
Nowadays we are often faced with huge databases resulting from the rapid growth of data storage technologies. This is particularly true when dealing with music databases. In this context, it is essential to have techniques and tools able to discriminate properties from these massive sets. In this work, we report on a statistical analysis of more than ten thousand songs aiming to obtain a complexity hierarchy. Our approach is based on the estimation of the permutation entropy combined with an intensive complexity measure, building up the complexity-entropy causality plane. The results obtained indicate that this representation space is very promising to discriminate songs as well as to allow a relative quantitative comparison among songs. Additionally, we believe that the here-reported method may be applied in practical situations since it is simple, robust and has a fast numerical implementation. 相似文献
6.
Chitosan (CTS), a biocompatible, biodegradable, non-toxic polymer, dissolves in water only if pH is lowered under 6.5, when a substantial fraction of the amino groups is protonated. Its range of application has been much extended by partially depolymerising it or converting it to water-soluble derivatives. Working under high-intensity ultrasound at 17.8-18.5 kHz, using either a simple horn or a cup horn, we achieved a controlled depolymerization of CTS, also prepared in high yields several derivatives that can be useful intermediates for further chemical modification, as well as several water-soluble derivatives that lend themselves to a host of industrial applications. Compared to conventional methods, all these reactions went to completion in considerably shorter times at lower temperatures. 相似文献
7.
C. Andreoiu M. Axiotis G. de Angelis J. Ekman C. Fahlander E. Farnea A. Gadea T. Kröll S.M. Lenzi N. Mărginean T. Martinez M.N. Mineva C. Rossi Alvarez D. Rudolph C.A. Ur 《The European Physical Journal A - Hadrons and Nuclei》2002,15(4):459-462
Excited states in 59Zn were observed for the first time following the fusion-evaporation reaction 24Mg + 40Ca at a beam energy of 60 MeV. The GASP array in conjunction with the ISIS Silicon ball and the NeutronRing allowed for the
detection of γ-rays in coincidence with evaporated light particles. The mirror symmetry of 59Zn and 59Cu is discussed.
Received: 28 May 2002 / Accepted: 10 July 2002 / Published online: 3 December 2002
RID="a"
ID="a"Present address: Oliver Lodge Laboratory, University of Liverpool, P.O. Box 147, Liverpool, L69 7ZE, United Kingdom; e-mail: ca@ns.ph.liv.ac.uk.
RID="b"
ID="b"Present address: Physik-Departament, Technische Universit?t München, D-85748 Garching, Germany.
Communicated by W. Henning 相似文献
8.
A longitudinal study of MR diffusion changes in normal appearing white matter of patients with early multiple sclerosis 总被引:12,自引:0,他引:12
Caramia F Pantano P Di Legge S Piattella MC Lenzi D Paolillo A Nucciarelli W Lenzi GL Bozzao L Pozzilli C 《Magnetic resonance imaging》2002,20(5):383-388
BACKGROUND AND PURPOSE: The stage at which normal appearing white matter (NAWM) abnormalities first appear in multiple sclerosis (MS) is not clear. The aim of our study was to monitor water diffusion changes over time in NAWM of patients with early MS.METHODS: Out of a consecutive series of patients enrolled in a MR study on clinically isolated syndrome (CIS), we selected 19 subjects who had completed a one year follow-up. The MR scans obtained at baseline and at 12 months were reviewed according to the new criteria on the diagnosis of MS. Lesion load on T2 and T1 weighted images and the trace of the apparent diffusion coefficient in NAWM were measured both at baseline and at 12 months in patients and in 12 healthy controls.RESULTS: In three patients the diagnosis of MS was done at baseline based on MR. Thirteen patients developed MS during the study and in three patients the diagnosis remained "possible MS." TADC in NAWM in patients was significantly higher than in controls at the 12 months' follow-up but not at baseline (controls mean tADC +/- sd = 0.745 +/- 0.02 mm(2)/sec x 10(-3); patients mean tADC(12) +/- sd = 0.767 +/- 0.02 mm(2)/sec x 10(-3); p < 0.02). TADC and T2 lesion load at 12 months were significantly correlated (p < 0.01). Patients exhibiting tADC(12) above a confidence interval had a significantly greater EDSS score at the same time period (EDSS(12) +/- sd = 1.9 +/- 0.5 and = 1.1 +/- 0.4 respectively; p < 0.01).CONCLUSIONS: This study suggests that diffusion MR cannot detect alterations in NAWM of patients with a CIS suggestive of MS. After one year, when most patients develop MS, diffusion MR abnormalities in NAWM become apparent. These abnormalities are correlated with T2 lesion load and may contribute to neurological impairment. 相似文献
9.
A. Gadea G. de Angelis C. Fahlander M. De Poli E. Farnea Y. Li D.R. Napoli Q. Pan P. Spolaore D. Bazzacco S.M. Lenzi S. Lunardi C.M. Petrache F. Brandolini P. Pavan C. Rossi Alvarez M. Sferrazza P.G. Bizzeti A.M. Bizzeti Sona J. Nyberg M. Lipoglavsek J. Persson J. Cederkäll D. Seweryniak A. Johnson H. Grawe F. Soramel M. Ogawa A. Makishima R. Schubart S. Frauendorf 《Zeitschrift für Physik A Hadrons and Nuclei》1997,358(2):193-194
The structure of 105Sn has been investigated through the 50Cr(58Ni,2pn) reaction at a beam energy of 210 MeV. In addition to an extension of the spherical level scheme, a regular sequence of dipole transitions has been found. The experimental results are in agreement with the prediction of Tilted Axis Cranking calculations, which satisfactorily explain the properties of the band. 相似文献
10.
Several properties are calculated for A2Πu of —the majority for the first time—including electric and magnetic moments, and fine/hyperfine structure (fs/hfs) parameters. The new results are compared with our previous ones for X2 and B2 of [P.J. Bruna, F. Grein, J. Mol. Spectrosc. 227 (2004) 67–80]. The electric quadrupole Θ and hexadecapole Φ moments, polarizability α, and hfs constants a, b, c, d, eQq0, eQq2 are evaluated at the density functional theory (DFT) level [B3LYP/aug-cc-pVQZ]. The fs constants (spin–orbit coupling AΠ, Λ-doubling p, q, spin-rotation γΠ), and magnetic moments (g-factors) are obtained via 2nd-order sum-over-states expansions, using wavefunctions and matrix elements obtained with a multireference configuration interaction (MRDCI) method, and the Breit–Pauli Hamiltonian. At equilibrium, 2nd-order properties of A2Πu are dominated by its coupling with B2. For the A state, two independent components are reported for traceless tensor properties (multipoles Θ and Φ; hfs parameters c/d and q0/q2) and three for traced properties (polarizability α and g-factors), i.e., one more component than for axially symmetric Σ states. The currently available experimental data on — limited to AΠ, p, and q—are well reproduced by our theoretical results. 相似文献