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51.
Barr JD Bell AJ Bird M Mundy JL Murrell J Timperley CM Watts P Ferrante F 《Journal of the American Society for Mass Spectrometry》2005,16(4):515-523
The fragmentations and reactions of Diazinon and related compounds have been studied by electrospray ionization ion trap mass spectrometry. Several novel fragmentation and rearrangements have been observed, including an intramolecular thiono-thiolo rearrangement. The stability, in the gas-phase, of the protomers of 2-isopropyl-4-methyl-6-pyrimidinol has been demonstrated. The complexity of the gas phase ion processes observed suggest that, at present, caution should be exercised in using this approach for the analysis of environmental and other samples until our understanding of these processes increases considerably. 相似文献
52.
We obtain massive and massless vector two-point functions in maximally symmetric spaces (and vacua) of any number of dimensions. These include de Sitter space and anti-de Sitter space, and their Euclidean analogsS
n andH
n. Our method is based on a simple way of constructing every possible maximally symmetric bitensorT
a...bc...d(x, x) which carries tangent-space indicesa...b atx andc...d atx. 相似文献
53.
Denis Bell 《Probability Theory and Related Fields》1986,72(3):417-424
Summary We give an elementary proof of the fact that a finite Borel measure on n is absolutely continuous with a C
1 density if and only if it has directional derivatives which are continuous almost everywhere. The Radon-Nikodym derivative of a differentiable measure is given in terms of the directional derivatives. 相似文献
54.
W. Bell K. Braune G. Claesson D. Drijard M. A. Faessler H. G. Fischer H. Frehse R. W. Frey S. Garpman W. Geist C. Gruhn P. Hanke M. Heiden W. Herr P. G. Innocenti T. J. Ketel E. E. Kluge I. Lund G. Mornacchi T. Nakada I. Otterlund M. Panter B. Povh A. Putzer E. Stenlund T. J. M. Symons R. Szwed O. Ullaland 《Zeitschrift fur Physik C Particles and Fields》1986,30(4):513-520
Properties of secondaries associated with a high-p T charged trigger particle (3<p T <5 GeV/c) were studied for αp and αα interactions at c.m. energies \(\sqrt s = 88\) GeV and 125 GeV, respectively. Thep T distributions of secondaries in the away-jet and trigger-jet regions were compared with those for high-p T pp interactions. No statistically significant differences were seen, except at lowp T . Momentum and angular distributions of spectator and leading protons were studied as a function of charge and rapidity of the trigger hadron. The observed correlations between trigger charge and number of spectator protons provide evidence of valence quark contributions to the trigger jet. 相似文献
55.
56.
Winny Dong Jeffrey Sakamoto Bruce Dunn 《Journal of Sol-Gel Science and Technology》2003,26(1-3):641-644
The electrochemical properties of high surface area transition metal oxide aerogels are extremely interesting because aerogels serve to amplify surface effects. As a result, the electrochemical properties are dominated by surfaces rather than by bulk behavior. In the case of vanadium oxide aerogels this leads to extraordinary electrochemical properties, including an extremely high capacity for lithium and electrochemical responses that are both battery-like and capacitor-like. By exploiting sol-gel synthesis, it is possible to synthesize nanocomposite electrodes in which aerogels are in intimate contact with carbon nanotubes. The resulting nanocomposites exhibit superior electrochemical properties, especially at high discharge. 相似文献
57.
M.I. Bruce O.M.Abu Salah R.E. Davis N.V. Raghavan 《Journal of organometallic chemistry》1973,64(3):C48-C50
In contrast to a related iron—copper compound, the complex (π-C5H5)Ru(PPh3)2(C2Ph)CuCl is shown to be monomeric, and contains linear dicoordinate copper(I); the reactions of this and similar complexes with metal carbonyls are sources of new mixed-metal clusters, such as (π-C5H5)Fe2 Ru(C2Ph)(CO)6 (PPh3). 相似文献
58.
The electrochemical activity of Li2MnO3 in non-aqueous media has been investigated and found to involve neither Mn(4+)-Mn5+ oxidation nor simultaneous O2- removal but exchange of Li+ by H+, the latter being generated in the electrolyte. 相似文献
59.
Although aryl hydroxamic acids are well-known to form coordination complexes with vanadate (V(V)), the nature of these complexes at neutral pH and submillimolar concentrations, the conditions under which such complexes inhibit various serine amidohydrolases, is not well established. A series of qualitative and quantitative experiments, involving UV/vis, (1)H NMR, and (51)V NMR spectroscopies, established that both 1:1 and 1:2 vanadate/hydroxamate complexes form at pH 7.5, with the former dominating at submillimolar concentrations. Formation constants for the complexes of several aryl and alkyl hydroxamic acids were determined; for example, for benzohydroxamic acid, the stepwise formation constants of the 1:1 and 1:2 complexes were 3000 and 400 M(-1), respectively. The (51)V chemical shift of the 1:1 4-nitrobenzohydroxamic acid complex was -497 ppm, and that of its unsubstituted analogue was -498 ppm. A (1)H-(15)N HSQC spectrum of the 4-nitrobenzo-(15)N-hydroxamic acid/vanadate complex indicated the presence of an N-H group with (15)N and (1)H chemical shifts of 115 and 5.83 ppm, respectively. A (13)C NMR spectrum of the complex of 4-nitrobenzo-(13)C-hydroxamic acid with vanadate displayed a resonance at 170.1 ppm and thus a coordination-induced shift (CIS) of +3.8 ppm. In contrast, the CIS value of an established 1:2 complex, thought to contain chelated hydroxamic acid ligands, was +11.9 ppm. These spectral data led to the following structural picture of 1:1 complexes of vanadate and aryl hydroxamic acids. They contain penta- or hexa-coordinated vanadium. The ligand is in the hydroxamate rather than hydroximate form. The ligand is presumably bound to vanadium through the hydroxamic hydroxyl oxygen, but the hydroxamic acid carbonyl oxygen interacts weakly with vanadium. These species are the most likely candidates for the inhibitors of serine amidohydrolases found in vanadate/hydroxamic acid mixtures. 相似文献
60.
We describe a convergent synthesis of eight 1,3,5- and 1,2,4,5-substituted benzene derivatives with long rigid arms containing 4-pyridyl, 2,2'-bipyridyl, and 2,2'-bipyrimidyl termini, meant to be used as trigonal or tetragonal connectors for the construction of large molecular structures. The synthesis involved copper-free Pd-mediated coupling of terminal acetylenes to aryl halides. First, one of the termini of 1,3-diethynylbicyclo[1.1.1]pentane was coupled with a brominated aza heterocycle, and second, 3 equiv of the resulting extended arm were coupled with 1,3,5-triiodobenzene or 4 with 1,2,4,5-tetraiodobenzene. An improved large-scale synthesis for 1,3-diethynylbicyclo[1.1.1]pentane is described. The structures of two of the arms were determined by single-crystal X-ray analysis. Several long molecular rods with 4-pyridyl termini were obtained as byproducts, and a single-crystal X-ray structure is reported for the shortest of these. 相似文献