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141.
Harrison E. Radford F.David Wayne John M. Brown 《Journal of Molecular Spectroscopy》1983,99(1):209-220
The detection of the free radicals ClSO and FSO by the technique of far infrared laser magnetic resonance is reported. Observations of the former have been made with several laser lines; the spectra are complicated and have not been assigned but are attributed to ClSO on the basis of several chemical tests. The FSO radical was generated by the reaction of carbon disulphide with the products of a discharge through CF4 + O2. Spectra have been observed with laser lines at 394, 419 and 513 μm. Using the results of a subsequent microwave study of FSO, the rotational transitions involved in these spectra have been identified. The spectrum at 513 μm has been studied in detail and is shown to arise through level anticrossings between the levels 145,Kc (the lower levels involved in the transition) and 154,Kc+2. All aspects of this spectrum are reproduced quantitatively by the parameters determined from the microwave spectrum. It is thought that the other two FSO spectra arise in a similar manner. Such anticrossing signals are likely to be widespread in LMR experiments, causing intense narrow lines to occur at high magnetic fields even for molecules with weakly coupled electron spin. 相似文献
142.
J. I. Prisciandaro P. F. Mantica B. A. Brown D. W. Anthony M. W. Cooper A. Garcia D. E. Groh A. Komives W. Kumarasiri P. A. Lofy A. M. Oros-Peusquens S. L. Tabor M. Wiedeking 《Physics letters. [Part B]》2001,510(1-4):17-23
An 879.9(2) keV γ-ray transition has been identified following the β decay of 58V and assigned as the 2+1→0+1 transition in 58Cr34. A peak in the energies of the first excited 2+ states for the even–even chromium isotopes is now evident at 56Cr32, providing empirical evidence for a significant subshell gap at N=32. The appearance of this neutron subshell closure for neutron-rich nuclides may be attributed to the diminished π1f7/2–ν1f5/2 monopole proton–neutron interaction as protons are removed from the 1f7/2 single-particle orbital. 相似文献
143.
The relationship between the transported ion current and the cathodic arc current is determined in a vacuum arc plasma source equipped with a curved magnetic filter. Our results suggest that the outer and inner walls of the duct interact with the plasma independently. The duct magnetic field is a critical factor of the plasma output. The duct transport efficiency is to maximize at a value of bias plate voltage in the range +10 V to +20 V, and independent (within our limit of measurement) of the magnetic field strength in the duct. The plasma flux is composed of two components: a diffusion flux in the transverse direction due to particle collisions, and a drift flux due to the ion inertia. The inner wall of the magnetic duct sees only the diffusion flux while the outer wall receives both fluxes. Thus, applying a positive potential to the outer duct wall can reflect the ions and increase the output current. Our experimental data also show that biasing both sides of the duct is more effective than biasing the outer wall alone. 相似文献
144.
M. Karny L. Batist B. A. Brown D. Cano-Ott R. Collatz A. Gadea R. Grzywacz A. Guglielmetti M. Hellstrm Z. Hu Z. Janas R. Kirchner F. Moroz A. Piechaczek A. P
ochocki E. Roeckl B. Rubio K. Rykaczewski M. Shibata J. Szerypo J. L. Tain V. Wittmann A. Whr 《Nuclear Physics A》2001,690(4):45
The Gamow–Teller β decays of the neutron-deficient indium isotopes 104–107In have been investigated by using total absorption γ-ray spectrometry on mass-separated sources. The experimental Gamow–Teller strength, deduced as a function of the excitation energy in the daughter nuclei 104–107Cd, is compared to shell-model predictions. 相似文献
145.
This paper describes the development of a non-contact system for measuring colour of printed material at web speeds. The system proposed uses a non-contact spectrophotometer based on a holographic grating, in conjunction with a conventional monochrome area scan camera, from which colour spectral data is extracted, whilst a xenon flash is used to illuminate colour samples. Software and hardware details of the system are given, along with the underlying mathematics for colour space conversion and measurement. Conversion equations from X, Y, Z chromaticity co-ordinates to the RGB system are presented, and also equations to convert from the L*a*b* colour space to X, Y, Z chromaticity co-ordinates. Experimental results are presented whereby the non-contact spectral system is shown to perform to a colour tolerance exceeding that of conventional colour video systems. 相似文献
146.
LCA groups with trivial multiplier group are characterized. It is found that every LCA group with nontrivial multiplier group has an “irreducible” quotient with the same property, and the irreducible groups are described. 相似文献
147.
Ochs MF Stoyanova RS Arias-Mendoza F Brown TR 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1999,137(1):161-176
A frequent problem in analysis is the need to find two matrices, closely related to the underlying measurement process, which when multiplied together reproduce the matrix of data points. Such problems arise throughout science, for example, in imaging where both the calibration of the sensor and the true scene may be unknown and in localized spectroscopy where multiple components may be present in varying amounts in any spectrum. Since both matrices are unknown, such a decomposition is a bilinear problem. We report here a solution to this problem for the case in which the decomposition results in matrices with elements drawn from positive additive distributions. We demonstrate the power of the methodology on chemical shift images (CSI). The new method, Bayesian spectral decomposition (BSD), reduces the CSI data to a small number of basis spectra together with their localized amplitudes. We apply this new algorithm to a 19F nonlocalized study of the catabolism of 5-fluorouracil in human liver, 31P CSI studies of a human head and calf muscle, and simulations which show its strengths and limitations. In all cases, the dataset, viewed as a matrix with rows containing the individual NMR spectra, results from the multiplication of a matrix of generally nonorthogonal basis spectra (the spectral matrix) by a matrix of the amplitudes of each basis spectrum in the the individual voxels (the amplitude matrix). The results show that BSD can simultaneously determine both the basis spectra and their distribution. In principle, BSD should solve this bilinear problem for any dataset which results from multiplication of matrices representing positive additive distributions if the data overdetermine the solutions. 相似文献
148.
149.
Baltrusaitis RM Becker JJ Blaylock GT Brown JS Bunnell KO Burnett TH Cassell RE Coffman D Cook V Coward DH Cui H Del Papa C Dorfan DE Duncan AL Einsweiler KF Eisenstein BI Fabrizio R Gladding G Grancagnolo F Hamilton RP Hauser J Heusch CA Hitlin DG Köpke L Mockett PM Moss L Mozley RF Nappi A Odian A Partridge R Perrier J Plaetzer SA Richman JD Roehrig JR Russell JJ Sadrozinski HF Scarlatella M Schalk TL Schindler RH Seiden A Sleeman JC Spadafora AL Thaler JJ Toki W Unno Y Villa F Wattenberg A 《Physical review letters》1985,55(17):1723-1726
150.
Jesper L. Mortensen Alan McWilliam Christopher G. Leburn Peter Tidemand-Lichtenberg Morten Thorhauge Jirí Janousek Christian T.A. Brown Alexander A. Lagatsky Preben Buchhave Wilson Sibbett 《Optics Communications》2006,260(2):637-640
Efficient generation of continuous-wave (CW) tunable light in the yellow region is reported. The method is based on sum-frequency mixing of a tunable Cr4+:forsterite laser with a Nd:YVO4 laser. A periodically poled lithium niobate crystal was placed intra-cavity in a Nd:YVO4 laser, and the Cr4+:forsterite laser was single-passed through the non-linear media. With this setup, it was possible to generate up to 3 mW of yellow light smoothly tunable from 573 to 587 nm. This is the highest output demonstrated to date for a tunable diode pumped solid-state CW laser in this wavelength region. The ways to improve the efficiency further are discussed. 相似文献