Synthesis and characterization of cerium and yttrium alkoxide complexes supported by ferrocene-based chelating ligands

Two series of Schiff base metal complexes were investigated, where each series was supported by an ancillary ligand incorporating a ferrocene backbone and different N=X functionalities. One ligand is based on an imine, while the other is based on an iminophosphorane group. Cerium(IV), cerium(III), and yttrium(III) alkoxide complexes supported by the two ligands were synthesized. All metal complexes were characterized by cyclic voltammetry. Additionally, NMR, Mo?ssbauer, X-ray absorption near-edge structure (XANES), and absorption spectroscopies were used. The experimental data indicate that iron remains in the +2 oxidation state and that cerium(IV) does not engage in a redox behavior with the ancillary ligand.     

Synthesis and use of a cost-effective,aqueous soluble diazo transfer reagent – m-carboxybenzenesulfonyl azide

Herein, we report the preparation and use of m-carboxybenzenesulfonyl azide as a diazo transfer reagent. This compound is an inexpensive and potentially scalable alternative to many of the diazo transfer reagents currently available, most of which have hazards associated with their use. Its usefulness and suitability as a diazo transfer reagent was assessed on the basis of cost, safety and its effectiveness in diazo transfer to a variety of different substrates.     

Synchronously pumped optical parametric oscillator driven by a femtosecond mode-locked fiber laser

A femtosecond all-fiber laser source incorporating a cw mode-locked Yb-doped silica fiber oscillator and amplifier has been used to synchronously pump an optical parametric oscillator based on periodically poled lithium niobate. The signal output, consisting of 330-fs pulses at a 54-MHz repetition rate and average powers up to 90 mW, was tuned from 1.55 to 1.95microm , with a corresponding idler range of 2.30-3.31microm .     

Nonlinearity in holey optical fibers: measurement and future opportunities

Holey fibers combine two-dimensional microstructuring with one-dimensional longitudinal propagation, resulting in fibers with tailorable dispersive and nonlinear properties. We measure the effective nonlinearity of a typical holey fiber. The small effective area that is possible in this type of fiber significantly enhances its effective nonlinearity relative to standard fiber.     

Nonlinear switching in a 20-cm-long fiber Bragg grating

We report experimental observation of nonlinear all-optical switching of a 20-cm-long fiber Bragg grating. The grating is self-switched owing to the optical Kerr effect and in the nonlinear regime shows a 20-dB increase in transmissivity. This increase is a marked improvement from the switching results obtained from shorter gratings.     

Transmission properties of microcoils based on twisted birefringent fibre

We model the linear transmission properties of birefringent optical microcoil resonators (OMRs) by numerically solving polarisation dependent coupled mode equations. When the fibre is twisted, results show spectral bands where strong coupling between the different polarisations occur. The extinction ratio of certain resonances is also found to be enhanced by the exchange of power into another polarisation. Compared to the standard OMR, the choice of fibre twist and level of birefringence provide additional flexibility in tailoring the OMR spectral properties as needed for applications such as filtering, signal processing and sensing.     

Self-assembled growth of nanostructural Ge islands on bromine-passivated Si(111) surfaces at room temperature

We have deposited relatively thick (∼60 nm) Ge layers on Br-passivated Si(111) substrates by thermal evaporation under high vacuum conditions at room temperature. Ge has grown in a layer-plus-island mode although it is different from the Stranski-Krastanov growth mode observed in epitaxial growth. Both the islands and the layer are nanocrystalline. This appears to be a consequence of reduction of surface free energy of the Si(111) substrate by Br-passivation. The size distribution of the Ge nanoislands has been determined. The Br-Si(111) substrates were prepared by a liquid treatment, which may not produce exactly reproducible surfaces. Nevertheless, some basic features of the nanostructural island growth are reasonably reproducible, while there are variations in the details of the island size distribution.     

Structural studies of Vgamma2Vdelta2 T cell phosphoantigens

Human gammadelta T cells containing the Vgamma2Vdelta2 (Vgamma9Vdelta2) T cell receptor are stimulated by a broad variety of small, phosphorus-containing antigenic molecules called phosphoantigens. The structures of several species present in both Mycobacteria (TUBags1-4) and in Escherichia coli have been reported to contain a formyl-alkyl diphosphate core. Here we report the synthesis of the lead member of the series, 3-formyl-1-butyl diphosphate. This compound has low activity for gammadelta T cell stimulation, unlike its highly active isomer (E)-4-hydroxy-3-methyl-but-2-enyl diphosphate, necessitating a revision of the structure of TUBag1. Likewise, the structure of the species identified as the pentyl analog (TUBag 2) is revised to 6-phosphogluconate. These results indicate that neither TUBag1 nor the m/e 275 species proposed for TUBag2 are 3-formyl-1-alkyl diphosphates, leading to the conclusion that none of the natural phosphoantigens (TUBags1-4) possess the structures reported previously.     

Brillouin characterization of holey optical fibers

We report the results of detailed measurements on the Brillouin frequency shift (BFS), gain bandwidth, and gain coefficients of several small-core holey optical fibers (HFs) of both uniform and axially varying structural characteristics and compare these with measurements on more conventional fibers. Our measurements show that the BFS of HFs is first-order proportional to the modal index for light propagating along the fiber and is thus extremely sensitive to its precise structural parameters. Our results highlight the possibility of using distributed Brillouin scattering measurements to perform nondestructive structural characterization of HFs, and the possibility of producing Brillouin-suppressed HFs using controlled structural variation along the fiber length.