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Sergi Garcia-Segura Alec Brockway Nienhauser Ana S. Fajardo Rishabh Bansal Christian L. Conrad John D. Fortner Mariana Marcos-Hernández Tanya Rogers Dino Villagran Michael S. Wong Paul Westerhoff 《Current Opinion in Electrochemistry》2020
Electrochemical water treatment is one of the key topics of environmental electrochemistry. Identifying electrocatalytic materials capable of electrogenerating high oxidant species in situ seems to have catalyzed researchers’ interest in these processes. While most studies have focused on ideal lab-made solutions, translation to higher technology readiness levels and commercialization requires reframing research questions in context of real water matrices. In this current opinion, we discuss disconnects that may occur when focusing on synthetic solution treatment rather than on real waters. Future research can fill the gaps identified herein, thus facilitating application of electrochemical water treatment technologies. 相似文献
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C. E. Brockway P. A. Seaberg 《Journal of polymer science. Part A, Polymer chemistry》1967,5(6):1313-1326
Acrylonitrile grafts readily to granular corn starch in aqueous slurry when initiated by hydrogen peroxide plus activator. Prime evidence for grafting lies in the ease of separating PAN from starch in high yield when the initiator is azobisisobutyronitrile rather than peroxide. Grafting efficiencies are determined by extraction with appropriate solvents: dimethylformamide for homo-PAN, and boiling water for ungrafted starch. Grafting efficiencies of PAN range from 78 to 95%, M?n values for grafted PAN are 4,000 to 90,000, and frequency of attachment of side chains range from 300 to 1100 glucose units per chain. Increasing the monomer level, at fixed initiator concentration, tends to result in longer rather than more frequent side chains. AN behaves much as has been previously found for MMA, but the somewhat more efficient grafting at more frequent intervals and the more nearly uniform distribution of polymer in the starch granule suggest that AN penetrates the starch granule more readily than MMA. 相似文献
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