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61.
Anna S. Bondarenko Ilias Patmanidis Riccardo Alessandri Paulo C. T. Souza Thomas L. C. Jansen Alex H. de Vries Siewert J. Marrink Jasper Knoester 《Chemical science》2020,11(42):11514
Supramolecular aggregates of synthetic dye molecules offer great perspectives to prepare biomimetic functional materials for light-harvesting and energy transport. The design is complicated by the fact that structure–property relationships are hard to establish, because the molecular packing results from a delicate balance of interactions and the excitonic properties that dictate the optics and excited state dynamics, in turn sensitively depend on this packing. Here we show how an iterative multiscale approach combining molecular dynamics and quantum mechanical exciton modeling can be used to obtain accurate insight into the packing of thousands of cyanine dye molecules in a complex double-walled tubular aggregate in close interaction with its solvent environment. Our approach allows us to answer open questions not only on the structure of these prototypical aggregates, but also about their molecular-scale structural and energetic heterogeneity, as well as on the microscopic origin of their photophysical properties. This opens the route to accurate predictions of energy transport and other functional properties.Multiscale modeling resolves the molecular structure of a synthetic light-harvesting complex, unraveling the microscopic origin of its photophysical properties.Supramolecular structures may self-assemble from a variety of building blocks, resulting in a wide range of advanced materials with attractive biomimetic, sensing, catalytic, optoelectronic and photonic functionalities.1–10 The close-packed nanoscale organization of the individual molecules within a supramolecular system, held together via noncovalent interactions, gives rise to the aggregate''s (collective) properties. Assemblies consisting of dye molecules often exhibit unique collective optical properties and are of interest for opto-electronic applications as well as artificial light-harvesting complexes that mimic natural antenna systems of photosynthetic bacteria and plants.11–13 For example, chlorosomal antenna complexes of photosynthetic green sulfur bacteria are self-assembled into multilayer tubular structures having bacteriochlorophyll pigments as building blocks.14–16 The structure of these antenna complexes and the underlying molecular arrangement ensures that the process of light-harvesting and excitation energy transport is very efficient, even under extremely low light conditions.17,18 The quest to recreate such efficiency under laboratory conditions has sparked numerous studies of synthetic self-assembled systems mimicking natural chlorosomes, e.g. using porphyrins,19 zinc chlorin,20 and cyanine dyes.21 Of particular interest are the tubular aggregates of 3,3′-bis(2-sulfopropyl)-5,5′,6,6′-tetrachloro-1,1′-dioctylbenzimidacarbocyanine (C8S3).22–25 Cryo-TEM reveals a hierarchy of supramolecular architectures, including double-walled nanotubes; under certain conditions, bundles of nanotubes arise.26 Thus, this system allows for the occurrence of electronic excitation energy transport at various levels: within one wall, between walls of one tube, and between different tubes, similar to the situation in natural systems.27,28To understand how such supramolecular systems work, as well as propose design rules for new materials, it is essential to determine the relationship between molecular structure and optical properties. Current experimental techniques, however, are unable to resolve the structure at the molecular level. This, in combination with the sensitivity of spectral properties to the details of the molecular packing, leads to a crucial role for theoretical modeling.29 For example, molecular dynamics (MD) simulations have been used to predict the molecular packing within a variety of supramolecular assemblies.30–34 However, synthetic amphiphiles with aromatic groups, such as cyanine dyes—often used to prepare aggregates with optical functionality—tend to fall into kinetic traps during spontaneous self-assembly simulations and the packing of the aromatic chromophores remains highly disordered on the accessible time scale, leading to predicted (optical) spectra that are not consistent with experimental data.35 This problem can be overcome by building assemblies based upon proposed architectures and assessing their stability in relatively short MD simulations.36–38 The drawback of this approach is the requirement of a thorough understanding of what to use as a starting point and how to validate the structure. In any case, proper validation requires the modeling of the optical spectra of the obtained structure, and finally, comparing it to the experiment. The demanding character of such methods explains why an important role is played by phenomenological modeling, in which a molecular packing is guessed and the optics is obtained from parametrizing an exciton model that describes the collective excited states of the assembly with interactions dictated by the guessed packing. By comparing the calculated spectra to experimental ones, the structure and exciton model may be fine-tuned. While this method has been successful in describing spectra,23,39 it is limited in its predictive power and also lacks access to essential microscopic parameters, such as tuning of the optical excitation energies imposed by the environment, disorder in these energies and structural heterogeneity.In this work, we use an advanced multiscale approach to determine structure–optical property relationships for the C8S3 double-walled nanotubes, guided by comparison to experiments. The optical spectrum of these aggregates, in which multiple exciton peaks may be discerned, suggests a rather complex underlying molecular packing. This fact, combined with their sheer size going up to many thousands of molecules, makes these systems exceptionally challenging to resolve and leaves important questions concerning structure–function relationships unanswered or under debate, for instance the origin of the splitting between the two lowest-energy spectral bands.23,38 Here, we answer these questions by iteratively combining MD simulations to capture the details of molecular packing and structural disorder, an exciton Hamiltonian approach to calculate optical signatures, and explicit microelectrostatic calculations to estimate energetic disorder and solvent shifts. Previous attempts to reveal the structure of cyanine-based nanotubes were limited to small-scale system sizes,37,38 modeling optical features phenomenologically rather than using atomistic information38 or featuring simpler, single-walled systems.37 In addition to answering important questions for the C8S3 double-walled nanotubes, our study opens the way to explain and predict at an unprecedented level of detail the functional properties of other highly complex molecular materials. 相似文献
62.
G. L. Kelley J. A. Wiley R. T. Bohm W. C. Wright H. H. Willard Florence Fenwick J. M. Kolthoff O. Tomicek H. Tusker W. Chlopin L. Kaufmann H. D. Newton J. L. Hughes K. Swoboda C. Gallego A. T. Etheridge Hammer Koch A. Fölsner K. Ries W. Singleton A. Kropf G. Misson W. Silberminz E. Roshkowa A. H. Low Julius Meyer O. Kropf S. G. Clarke G. E. F. Lundell J. I. Hoffman H. A. Bright A. Pawletta L. Pisarjewski P. Düllberg W. M. Hartmann 《Analytical and bioanalytical chemistry》1932,88(5-6):206-237
63.
64.
Three approaches to phase-resolved fluorimetric determination of mixtures of 1,4-bis(5-phenyloxazol-2-yl)benzene and its dimethyl derivatives are compared, including the use of measurements at the detector phase angles required to null the phase resolved intensity contribution of each component and the use of measurements at multiple detector phase angles which are either used in an indirect-nulling method or in simultaneous-equation approach. Best results were obtained using the latter method with eight detector phase angles, and both the indirect-nulling and simutaneous-equation methods were generally superior to the method involving measurements at the “nulling” detector phase angles. 相似文献
65.
A. Travers Maquenne Mathevet J. Vernay L. Bertiaux J. M. Kolthoff F. P. Treadwell Binay Chundra Mukerjee H. A. Bright C. P. Larrabee Carnegie Steel Co. Bureau of Stundards H. Beckurts L. E. Stout G. C. Whitaker J. Kassler und R. Lang 《Fresenius' Journal of Analytical Chemistry》1931,84(3-4):119-135
Ohne Zusammenfassung 相似文献
66.
Ch. Sannié W. G. Brown H. Flood Ch. Lapp K. Erali H. Brockmann Hella Schodder H. H. Strain P. Ruggli P. Jensen E. Waldschmitt-Leitz P. Fisher-Jørgensen M. Tønnesen G. Schramm J. Primosigh G. -M. Schwab K. Dockers G. Siewert H. Jungnickel Gretl Dattler A. N. Ghosh M. Venturello N. Agliardi H. Dahn H. Erlenmeyer W. Schoenauer und J. N. Wison 《Fresenius' Journal of Analytical Chemistry》1943,126(3):101-117
Ohne Zusammenfassung 相似文献
67.
68.
Lorraine M. Deck Jacob A. Greenberg Taylor S. Busby Elizabeth R. Bright Lisa J. Whalen David L. Vander Jagt Robert E. Royer 《Tetrahedron letters》2013
As part of ongoing research to investigate structural requirements for lactate dehydrogenase inhibition by highly substituted naphthoic and indenoic acids, certain naphthalene and indene precursors to those types of compounds are required. Described here are efficient preparations of 1-naphthoic acid precursors 6-benzyl-2,3-dimethoxy-1-propylnaphthalenes, including compounds with substituted benzyl groups and 7-benzyl-2,3-dimethoxy-1-propylnaphthalene. Also described are the syntheses of indenoic acid precursors 2-benzyl-5,6-dimethoxy-7-propyl-1H-indenes, including compounds with substituted benzyl groups. These compounds were made from the key intermediates 6,7-dimethoxy-5-propyl-1-tetralone, 6,7-dimethoxy-8-propyl-1-tetralone, and 5,6-dimethoxy-4-propyl-1-indanone. 相似文献
69.
The single crystals of pure and Potassium doped L-alanine cadmium chloride (LACC), a metallo organic nonlinear optical material
is grown by a slow evaporation technique. The grown crystals were confirmed by single crystal, powder XRD analyses and atomic
absorption studies. Dielectric measurements were carried out for different frequencies at different temperatures. The dielectric
constant decreases due to the introduction of large ionic radius K+ ion in the pure LACC crystal. The low dielectric constant and dielectric loss suggest that it can be used as inter-metal
dielectric material. 相似文献
70.
McCormick TM Calitree BD Orchard A Kraut ND Bright FV Detty MR Eisenberg R 《Journal of the American Chemical Society》2010,132(44):15480-15483
Rhodamine photosensitizers (PSs) substituting S or Se for O in the xanthene ring give turnover numbers (TONs) as high as 9000 for the generation of hydrogen via the reduction of water using [Co(III)(dmgH)(2)(py)Cl] (where dmgH = dimethylglyoximate and py = pyridine) as the catalyst and triethanolamine as the sacrificial electron donor. The turnover frequencies were 0, 1700, and 5500 mol H(2)/mol PS/h for O, S, and Se derivatives, respectively (Φ(H(2)) = 0%, 12.2%, and 32.8%, respectively), which correlates well with relative triplet yields estimated from quantum yields for singlet oxygen generation. Phosphorescence from the excited PS was quenched by the sacrificial electron donor. Fluorescence lifetimes were similar for the O- and S-containing rhodamines (~2.6 ns) and shorter for the Se analog (~0.1 ns). These data suggest a reaction pathway involving reductive quenching of the triplet excited state of the PS giving the reduced PS(-) that then transfers an electron to the Co catalyst. The longer-lived triplet state is necessary for effective bimolecular electron transfer. While the cobalt/rhodamine/triethanolamine system gives unprecedented yields of hydrogen for the photoreduction of water, mechanistic insights regarding the overall reaction pathway as well as system degradation offer significant guidance to developing even more stable and efficient photocatalytic systems. 相似文献