Photopolymerization of 1,6‐hexanedioldiacrylate initiated by three‐component systems based on N‐arylphthalimides

Three‐component photoinitiators comprised of an N‐arylphthalimide, a diarylketone, and a tertiary amine were investigated for their initiation efficiency of acrylate polymerization. The use of an electron‐deficient N‐arylphthalimide resulted in a greater acrylate polymerization rate than an electron‐rich N‐arylphthalimide. Triplet energies of each N‐arylphthalimide, determined from their phosphorescence spectra, and the respective rate constants for triplet quenching by the N‐arylphthalimide derivatives (acquired via laser flash photolysis) indicated that an electron–proton transfer from an intermediate radical species to the N‐arylphthalimide (not energy transfer from triplet sensitization) is responsible for generating the initiating radicals under the conditions and species concentrations used for polymerization. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4009–4015, 2004     

A compact shock-assisted free-piston driver for impulse facilities

A free-piston driver that employs entropy-raising shock processes with diaphragm rupture has been constructed, which promises significant theoretical advantages over isentropic compression. Results from a range of conditions with helium and argon driver gases are reported. Significant performance gains were achieved in some test cases. Heat losses are shown to have a strong effect on driver processes. Measurements compare well with predictions from a quasi-one-dimensional numerical code. Received 7 September 1996 / Accepted 5 October 1996     

Achievable sets, brambles, and sparse treewidth obstructions

One consequence of the graph minor theorem is that for every k there exists a finite obstruction set Obs(TW?k). However, relatively little is known about these sets, and very few general obstructions are known. The ones that are known are the cliques, and graphs which are formed by removing a few edges from a clique. This paper gives several general constructions of minimal forbidden minors which are sparse in the sense that the ratio of the treewidth to the number of vertices n does not approach 1 as n approaches infinity. We accomplish this by a novel combination of using brambles to provide lower bounds and achievable sets to demonstrate upper bounds. Additionally, we determine the exact treewidth of other basic graph constructions which are not minimal forbidden minors.     

Isoperimetric estimates in products

In a product M ₁ × M ₂ of Riemannian manifolds, the least perimeter required to enclose given volume among general regions is at least 1/√ 2 times that among regions of product form, assuming that the isoperimetric profiles of M ₁ and M ₂ are concave. This result sharpens earlier work of Grigor'yan, generalizes results of Bollobás and Leader and of Barthe, and yields a lower bound on the Cheeger isoperimetric constant of a product.     

Regular unbounded set functions

Set functions which are unbounded on an algebra of sets arise naturally by taking the products of bounded operators and spectral measures acting on a space of square integrable functions. The purpose of this note is to show that, provided a certain regularity condition is satisfied, there is a natural integration structure associated with such a set function and an auxiliary measure, so providing a complete space of integrable functions. Several examples illustrate the extent and limitations of the approach.     

The tetrahedron algebra and its finite-dimensional irreducible modules

Recently Terwilliger and the present author found a presentation for the three-point sl₂ loop algebra via generators and relations. To obtain this presentation we defined a Lie algebra ? by generators and relations and displayed an isomorphism from ? to the three-point sl₂ loop algebra. In this paper we classify the finite-dimensional irreducible ?-modules.     

Ordered OLPS and CF Nth numerators

Definitions, theorems and examples are established for a general model of Laurent polynomial spaces and ordered orthogonal Laurent polynomial sequences, ordered with respect to ordered bases and orthogonal with respect to inner products ·=L°⊙ decomposed into transition functional ⊙ and strong moment functional, or, more generally, sample functional L couplings. Under this formulation that is shown to subsume those in the existing literature, new fundamental results are produced, including necessary and sufficient conditions for ordered OLPS to be sequences of nth numerators of continued fractions, in contrast to the classical result concerning nth denominators which is shown to hold only in special cases.