Reactivity of phenyl esters of phosphorus acids in alkaline hydrolysis

Conclusions A study was made of the kinetics of the alkaline hydrolysis of some phenyl esters of phosphorus acids. An estimate was made of the contribution made by the induction effect and the p–d conjugation of the phenoxyl group to the free activation energy of the alkaline hydrolysis of the investigated esters.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2794–2796, December, 1972.     

Influence of the degree of branching of the O-alkyl radical on the anticholinesterase properties of O-alkyl S-n-butyl methylphosphonothioates

Russian Chemical Bulletin -     

Die quantitative Bestimmung von Vanadin mittels aktivierter Katalyse

Zusammenfassung Es wurden zwei Verfahren ausgearbeitet, um Vanadin mit Hilfe von aktivierter Katalyse zu bestimmen. Die Methodik ist geeignet, kleinste Spuren von Vanadin (bis herab zu 0,0006) mit ausreichender Genauigkeit zu ermitteln. Es werden Beleganalysen mitgeteilt.

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Summary Two procedures for the determination of vanadium have been worked out, based on activated catalysis, which allow minimal traces (down to 0,0006) of vanadium to be determined with adequate accuracy. Comparison analyses are given in the paper.

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Résumé On a élaboré deux procédés pour exécuter le dosage du vanadium à l'aide d'une catalyse activée. La méthode est apte à la détermination des plus petites traces de vanadium (jusqu'à 0,0006) avec une précision suffisante. On communique des analyses documentaires.

     

O-nitration of alcohols. Communication 2. Selective nitration of primary hydroxy groups in polyhydric alcohols

Russian Chemical Bulletin -     

Effect of phase composition of palladium-ruthenium membrane catalyst on selectivity of dehydrolinalool hydrogenation

Conclusions When the hydrogenation of dehydrolinalool to linalool is run on a Pd alloy containing 6 wt.% of Ru, which is lean in the -hydrogen phase, the selectivity is much greater than when the amount of the -hydrogen phase is greater. A high selectivity of the hydrogenation is achieved by reducing to a definite limit the amount of hydrogen in the membrane catalyst without using inhibitors of the side reactions, which can contaminate the hydrogenation products.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 926–928, April, 1984.     

Basicities of phosphinylalkylamines in water and ethanol

Conclusions The pK_a values of various phosphinylalkylamines in water and ethanol were determined. The inductive effect of phosphinyl groups on the basicities of the investigated amines was demonstrated. The inductive constants of a series of substituents were estimated.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1265–1267, June, 1982.