关于平面二次系统的极限环

关于常微分方程二次系统的极限环及分布结构,本文得到下述定理: 设有一个三阶细焦点,并且无限远奇点是唯一的简单的奇点,则必存在另外一个粗焦点。在粗焦点外有奇数个极限环,无限远奇点为鞍点,全局结构已定。 在上述的基础上对方程作参数的微小变化,使三阶细焦点跳出三个极限环,则得二个粗焦点,每个外面有奇数个极限环,总极限环数为偶数个,并至少为4个,全局结构已定。     

From second to first order transitions in a disordered quantum magnet

The cross sections and transverse spin asymmetries in the hard exclusive electroproduction of decuplet baryons are calculated in the large N(c) limit and found to be comparable to that of octet baryons. Large N(c) selection rules for the production amplitudes are derived, leading to new sensitive tests of the spin aspects of the QCD chiral dynamics both in the nonstrange and strange sectors. Importance of such studies for the reliable extraction of the pion form factor from pion electroproduction is explained.     

甲氧羰基亚甲基三苯基胂与氟代烯烃的反应

本文报道甲氧羰基亚甲基三苯基胂(Ⅰ)与氟代烯烃反应生成加成物,Ⅰ与4,4-二氯六氟丁烯-[1]反应,生成甲氧羰基-[4,4-二氯五氟丁烯-1]-基亚甲基三苯基胂(Ⅲ)和甲氧羰基4,4-二氯2,3,3,4-四氟丁酰基亚甲基三苯基肿(Ⅳ),Ⅲ通过氧化铝柱或经湿苯回流都转化为Ⅳ,Ⅰ与四氟乙烯和六氟丙烯都能发生反应,粗产物通过氧化铝柱后,分离得到相应的羰基化合物Ⅶ和Ⅷ,所有产物的结构都经元素分析、红外光谱、核磁共振谱和质谱分析证明。     

论Ore图的泛连通性

符合Ore条件的简单图称为Ore图,Ore条件指图的两个不相邻的顶点的度数之和不小于图的顶点数。本文搞清了Ore图的泛连通性,同时得到了Ore图的点(边)泛圈性的结果,推广了Bondy的一个结论。     

On the 17O correction for CO2 mass spectrometric isotopic analysis

To calculate delta(13)C from raw CO(2) isotope data, the ion beam ratio of m/z 45 to 44 is corrected for the contribution arising from the contribution of (17)O-bearing molecules. First, a review on the current state of (17)O-corrections for CO(2) mass spectrometry is presented. The three correction algorithms that are generally in use, however, do produce biased delta(13)C values, and the bias is actually larger than the precision of modern isotope ratio mass spectrometers. The origin of this bias is twofold: different values for (17)R(VPDB-CO2) as well as different values for lambda are used in the correction algorithms. Despite both values being of high importance, large discrepancies between the absolute values published for (17)R(VPDB-CO2) appear to be the main reason for the delta(13)C biases. Next, the question of how to choose the value of lambda to best be used is considered. Natural (e.g. tropospheric) CO(2) as well as primary reference materials (PDB and NBS-19), having been in isotope exchange with water, are assumed to lie on the fractionation line for waters. On this ground, lambda = 0.5281 +/- 0.0015, as determined for waters (Meijer and Li, Isot. Environ. Health Stud., 1998; 34: 349-369), is suggested to be a base for the (17)O-correction algorithm. Finally, an approach to determine the absolute value for (17)R(VPDB-CO2), based on data of relative isotope measurements on two CO(2) gases having a large (17)O difference, is discussed and algebraic formulas are considered. Experimental data and new numerical values determined for (17)R(VPDB-CO2) and (17)R(VSMOW) are given in a companion paper.     

The position dependent 15N enrichment of nitrous oxide in the stratosphere.

The position dependent 15N fractionation of nitrous oxide (N2O), which cannot be obtained from mass spectrometric analysis on molecular N2O itself, can be determined with high precision using isotope ratio mass spectrometry on the NO+ fragment that is formed on electron impact in the source of an isotope ratio mass spectrometer. Laboratory UV photolysis experiments show that strong position dependent 15N fractionations occur in the photolysis of N2O in the stratosphere, its major atmospheric sink. Measurements on the isotopic composition of stratospheric N2O indeed confirm the presence of strong isotope enrichments, in particular the difference in the fractionation constants for 15N14NO and 14N15NO. The absolute magnitudes of the fractionation constants found in the stratosphere are much smaller, however, than those found in the lab experiments, demonstrating the importance of dynamical and also additional chemical processes like the reaction of N2O with O(1D).     

158 A Ge V p-Pb Pb-Pb碰撞中的单奇异和多奇异粒子产生

用描写相对论性核 核碰撞的LUCIAE模型及相应的MonteCarlo事例产生器分析了WA97最近发表的 1 5 8AGeVp Pb和Pb Pb碰撞中单奇异粒子 (Λ ,Λ)和多奇异粒子 (Ξ-,Ξ-,Ω-,Ω-)的多重数和横质量分布 .由于LUCIAE模型包含了弦碎裂微观过程中奇异夸克压低因子随碰撞体系的能量、中心度和质量的增大而增大 ,以及由它导致的相对论性核 核碰撞宏观过程中奇异粒子产额随上述三因素之增而增的物理机制 ;LUCIAE模型计算结果能较好描写WA97实验所揭示的相对论性核 核碰撞中奇异粒子产额随中心度之增而增和奇异粒子增强随奇异夸克数之增而增的实验事实 ,以及单奇异和多奇异粒子的横质量分布 .     

分子内结构环境对解离能的影响

为了理解化学键的这一结构效应, 本文对具有相同化学键而分子内结构环境不同的系列分子进行了计算研究, 讨论了化学键结构环境对解离能的影响.