Some Krasnosel'skii numbers for finitely starlike sets in the plane

Let S be a subset of the plane. In case (int cl S) S = , then S is finitely starlike if and only if every 4 points of S see via S a common point. In case (int cl S) S has at most countably many components, each a singleton set, then S is finitely starlike if and only if every 5 points of S see via S a common point. Each of the numbers 4 and 5 is best possible. Examples show that these results fail without suitable restrictions on (int cl S) S. Moreover, a final example shows that if a general Krasnosel'skii number . exists to characterize finitely starlike sets in the plane, then > 9.     

Krasnosel'skii numbers for bounded finitely starlike sets inR d

For eachk andd, 1kd, definef(d, d)=d+1 andf(d, k)=2d if 1kd–1. The following results are established:Let be a uniformly bounded collection of compact, convex sets inR ^d . For a fixedk, 1kd, dim {MM in }k if and only if for some > 0, everyf(d, k) members of contain a commonk-dimensional set of measure (volume) at least.LetS be a bounded subset ofR ^d . Assume that for some fixedk, 1kd, there exists a countable family of (k–l)-flats {H _i :i1} inR ^d such that clS S {H_i i 1 } and for eachi1, (clS S) H _i has (k–1) dimensional measure zero. Every finite subset ofS sees viaS a set of positivek-dimensional measure if and only if for some>0, everyf(d,k) points ofS see viaS a set ofk-dimensional measure at least .The numbers off(d,d) andf(d, 1) above are best possible.Supported in part by NSF grant DMS-8705336.     

Enhanced para-xylene selectivity in the toluene alkylation reaction at ultralow contact time

Dramatic improvements in the para-xylene selectivity of the toluene alkylation reaction can be effected by operating the catalytic reaction at ultralow contact time. Unexpectedly, the rate of alkylation is sustained, while unwanted side reactions are suppressed. By demonstrating that contact time directly influences the fate of para-xylene, which is known to form and diffuse preferentially within the zeolite catalyst, we conclude that external mass transfer is a key parameter in controlling selectivity. Even non-optimized catalysts can be made to achieve near-perfect selectivity, without sacrificing conversion.     

Simply connected orthogonal polygons as unions of two orthogonally starshaped sets

Let S be a simply connected orthogonal polygon in the plane. The set S is a union of two sets which are starshaped via staircase paths (i.e., orthogonally starshaped) if and only if for every three points of S, at least two of these points see (via staircase paths) a common point of S. Moreover, the simple connectedness condition cannot be deleted.     

A family of examples showing that no Krasnosel’skii number exists for orthogonal polygons starshaped via staircase n-paths

Let S be a simply connected orthogonal polygon in the plane. A family of examples will establish the following result. For every n ≥ 2, there exists no Krasnosel’skii number h(n) which satisfies this property: If every h(n) points of S are visible via staircase n-paths from a common point, then S is starshaped via staircase n-paths.