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161.
Trichloroethylene has been found to act as a rate enhancing co-factor in the liquid phase, tantalum (V) halide catalyzed, fluorine-for-chlorine exchange reaction of 1,2-dichloro-1,1-difluoroethane (R-132b) to 2-chloro-1,1,1-trifluorethane (R-133a). Several trifluoromethyl substituted benzenes have also been found to be rate-enhancing solvents. 相似文献
162.
163.
Any system that approximates an infinite lattice by a family of finite clusters (with periodic boundary conditions) passes through an intermediate region with enlarged (hidden) symmetry as the system size is increased. The hidden symmetry allows for extra degeneracies and level crossings and has application to exact-diagonalization studies, Monte Carlo simulations, lattice gauge theories, and renormalization group calculations. 相似文献
164.
F. Seiffert R. Schwengner G. Winter L. Funke W. Lieberz R. Reinhardt K. P. Schmittgen D. Weil R. Wrzal K. O. Zell P. von Brentano 《Zeitschrift für Physik A Hadrons and Nuclei》1991,340(2):141-153
Excited states of73Se have been investigated up to spin, 21/2 using techniques of in-beamγ-ray spectroscopy in connection with the70Ge(α, n) reaction. Mean lifetimes of 12 levels have been determined applying Doppler-shift andγ-RF-methods. Five different bands have been identified that reflect a variety of different excitation modes. The decoupled 9/2+ band is likely to correspond to an oblate deformation while the 5/2+ band is interpreted as a strongly coupled prolate band built on the Nilsson configuration [422] 5/2+. The 3/2? band is a strongly coupled band built on the [301] 3/2} configuration.Nuclear reactions:70Ge(α,n),E=14, 16, 18, 19, 20MeV; measuredE γ,I γ,σ(E γ,θ),γγ-coin, linear polarization, DSA,γ(t).75Se deduced levels,I, π, τ, δ(E2/M1), B(σλ). Enriched targets, Ge detectors. 相似文献
165.
We review a little-used but powerful method of solving the scalar wave equation. It uses a modification of the well-known Airy functions, which are easily calculated on desktop computers. The techniques are reminiscent of the WKBJ methodology, but the solution, although approximate, is much more useful than the traditional WKBJ solution and can be used with almost as much ease. Re method is extremely powerful but, to our knowledge, is not used in the optics community. It is useful in analyzing integrated optical waveguide components. 相似文献
166.
P. Dawson J. W. Haas III K. B. Alexander J. Thompson T. L. Ferrell 《Surface science》1991,250(1-3):L383-L388
The intensity of surface enhanced Raman scattering from benzoic acid derivatives on mildly roughened, thermally evaporated Ag films shows a remarkably strong dependence on metal grain size. Large grained (slowly deposited) films give a superior response, by up to a factor of 10, to small grained (quickly deposited) films, with films of intermediate grain size yielding intermediate results. The optical field amplification underlying the enhancement mechanism is due to the excitation of surface plasmon polaritons (SPPs). Since surface roughness characteristics, as determined by STM, remain relatively constant as a function of deposition rate, it is argued that the contrast in Raman scattering is due to differences in elastic grain boundary scattering of SPPs (leading to different degrees of internal SPP damping), rather than differences in the interaction of SPPs with surface inhomogeneities. 相似文献
167.
The object of the paper is to study the absolute matrix summability problem of Fourier series, conjugate series and some associated
series under a new set of conditions on matrix methods, generalising many known results in the literature. 相似文献
168.
Ulrich Mayerhofer T. von Egidy J. Jolie H. G. Börner G. Colvin S. Judge B. Krusche S. J. Robinson K. Schreckenbach S. Brant V. Paar 《Zeitschrift für Physik A Hadrons and Nuclei》1991,341(1):1-8
Gamma rays of199Au obtained after double neutron capture in197Au were measured at the ILL high flux reactor. A level scheme up to 1770 keV excitation energy is established. The result is compared with IBFM and Boson-Fermion-Symmetry calculations. 相似文献
169.
The study of Wiener-Levinson digital filters leads to certain classes of polynomials orthogonal on the unit circle (Szeg
polynomials). Here we present theorems that show that the unknown frequencies in a periodic discrete time signal can be determined from the limiting behavior (as N → ∞) of the zeros of fixed degree Szeg
polynomials that are orthogonal with respect to a distribution defined from N successive samples of the signal. This proves an essential part of a conjecture due to Jones, Njåstad, and Saff concerning the frequency analysis problem. 相似文献
170.