Nuclear structure functions and heavy flavour leptoproduction off the nucleus at small x in perturbative QCD

Nuclear structure functions and cross-sections for heavy flavour production in lepton–nucleus collisions are investigated in the low x region accessible now or in the near future. The scattering on a heavy nucleus is described by the sum of fan diagrams of BFKL pomerons, which is exact in the high-colour limit. The initial condition for the evolution at x=0.01 is taken from a saturation model, which reproduces the experimental data on the proton. The dependence of the structure functions is well described by a power factor , with reaching values as low as 1/2 at extremely low x. The total cross-sections for heavy flavour production reach values of the order of mb, and the corresponding transverse momentum distributions are sizable up to transverse momenta larger than the initial large scale . Received: 10 July 2001 / Revised version: 23 September 2001 / Published online: 5 November 2001     

Perceiving unstressed vowels in foreign-accented English

This paper investigated how foreign-accented stress cues affect on-line speech comprehension in British speakers of English. While unstressed English vowels are usually reduced to /?/, Dutch speakers of English only slightly centralize them. Speakers of both languages differentiate stress by suprasegmentals (duration and intensity). In a cross-modal priming experiment, English listeners heard sentences ending in monosyllabic prime fragments--produced by either an English or a Dutch speaker of English--and performed lexical decisions on visual targets. Primes were either stress-matching ("ab" excised from absurd), stress-mismatching ("ab" from absence), or unrelated ("pro" from profound) with respect to the target (e.g., ABSURD). Results showed a priming effect for stress-matching primes only when produced by the English speaker, suggesting that vowel quality is a more important cue to word stress than suprasegmental information. Furthermore, for visual targets with word-initial secondary stress that do not require vowel reduction (e.g., CAMPAIGN), resembling the Dutch way of realizing stress, there was a priming effect for both speakers. Hence, our data suggest that Dutch-accented English is not harder to understand in general, but it is in instances where the language-specific implementation of lexical stress differs across languages.     

Kinematic power corrections in off-forward hard reactions

We develop a general approach to the calculation of kinematic corrections ∝t/Q(2), m(2)/Q(2) in hard processes which involve momentum transfer from the initial to the final hadron state. As the principal result, the complete expression is derived for the time-ordered product of two electromagnetic currents that includes all kinematic corrections to twist-four accuracy. The results are immediately applicable, e.g., to the studies of deeply virtual Compton scattering.     

Investigation of noble metal nanoparticle ζ-potential effects on single-cell exocytosis function in vitro with carbon-fiber microelectrode amperometry

Since noble metal nanoparticles are increasingly found in consumer goods, there is a need for information about potential impacts of these nanoparticles on cellular function to avoid environmental and health risks associated with exposure. In this study, spherical Au and Ag nanoparticles of similar size were synthesized and modified to assess the effects of ζ-potential on immune cell function. Nanoparticle ζ-potential was controlled by employing surfactant exchange to generate nanoparticles with positive or negative surface charge. Mouse peritoneal mast cells (MPMCs) were then exposed to 5-15 μg ml(-1) of these nanomaterials, and uptake was assessed by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Uptake for positively charged nanoparticles was more efficient than for negatively charged nanomaterials, and all nanoparticles were taken up in a concentration-dependent manner. Following uptake, MPMC degranulation function was assessed using carbon-fiber microelectrode amperometry (CFMA), showing decreased quantal secretion of serotonin by MPMCs exposed to the positively charged Au nanoparticles and negatively charged Ag nanoparticles. The overall efficiency of the degranulation process (indicated by amperometric spike frequency) decreased for all Au-exposed MPMCs. However, only the negatively charged version of the Ag nanomaterial resulted in decreased MPMC degranulation efficiency. Further studies revealed that ionic Ag was partially responsible for the observed effects. Overall, these studies reveal the complex nature of interactions between noble metal nanomaterials and cells that result in perturbed cellular function and illustrate the necessity of thorough nanoparticle characterization for interpretation of cellular function assays.     

Solvent quality effects on scaling behavior of poly(methyl methacrylate) brushes in the moderate- and high-density regimes

Herein, we give a detailed experimental analysis for scaling law behavior in the "moderately dense" and "high-density" brush regimes for poly(methyl methacrylate) brushes swollen in a range of solvent conditions. This expansive experimental analysis aims to validate decades of mean field theory predictions on power law scaling behavior of grafted polymer chains. Brushes with grafting densities (σ) ranging from 0.1 to 0.8 nm(-2) are prepared by atom-transfer radical polymerization. The swollen thickness (h) is characterized using liquid cell ellipsometry, and the solvent quality is varied using mixtures of acetone and methanol. In a good solvent, the exponential scaling behavior (h ∝ σ(n)) has the typical n = 1/3 dependency for grafting densities of σ ≤ 0.4 nm(-2). For grafting densities of >0.4 nm(-2), n increases, indicating the transition from the moderately dense to the high-density brush regime. However, in a poor solvent, the scaling behavior is independent of σ and scales as h ∝ σ(0.80), approaching the theoretical expectations of h ∝ σ(1). An abrupt transition between these scaling law behaviors occurs at the Θ-solvent condition of ～45% (v/v) methanol in acetone. While our experimental results parallel trends predicted by mean field theory, differences are observed and appear to be attributed to self-solvation of the polymer, polydispersity in the molecular weight, and chain termination.     

Time-optimal control of spin 1/2 particles in the presence of radiation damping and relaxation

We consider the time-optimal control of an ensemble of uncoupled spin 1/2 particles in the presence of relaxation and radiation damping effects, whose dynamics is governed by nonlinear equations generalizing the standard linear Bloch equations. For a single spin, the optimal control strategy can be fully characterized analytically. However, in order to take into account the inhomogeneity of the static magnetic field, an ensemble of isochromats at different frequencies must be considered. For this case, numerically optimized pulse sequences are computed and the dynamics under the corresponding optimal field is experimentally demonstrated using nuclear magnetic resonance techniques.     

On the traveling waves governed by the Camassa–Holm equation

The Camassa–Holm equation admits undistorted traveling waves that are either smooth or exhibit peaks or cusps. All three wave types can be periodic or solitary. Also waves of different types may be combined. In the present paper it is shown that, apart from peaks and cusps, the traveling waves governed by the Camassa–Holm equation can be found from some simpler equation. In the case of peaked solutions, this reduced equation is even linear. The governing equation of traveling waves in its original form can be interpreted as a nonlinear combination of the reduced equation and its first integral. For a small range of the integration constant, the reduced equation admits bounded solutions, which then are directly inherited by the Camassa–Holm equation. In general, the solutions of the reduced equation are unbounded and cannot be considered to represent traveling waves. The full equation, however, has a nonlinearity in the highest derivative, which is characteristic for the Camassa–Holm and some other equations. This nonlinear term offers the possibility of constructing bounded traveling waves from the unbounded solutions of the reduced equation. These waves necessarily have discontinuities in the slope and are, therefore, solutions only in a generalized sense.     

Numerical simulation of pollutant dispersion in street canyons: Geometric and thermal effects

Numerical investigations on pollutant dispersion in street canyons with emission sources located near the ground level are performed in the present work. Pollutant dispersion problems in urban areas are usually studied considering the street canyon model, which consists of long streets laterally confined by buildings. Significant changes can be observed in wind flow patterns and pollutant concentration fields when thermal and geometric effects are considered. Thus, the objective of this study is to investigate numerically the wind flow and pollutant dispersion for the following cases: (a) a two-dimensional street canyon model considering three different aspect ratios and four different wall heating configurations; (b) a flow domain with two immersed buildings arranged in two distinct configurations; (c) a three-dimensional urban area model composed of a building set and street intersections. Expected flow structures were obtained inside the canyon when different aspect ratios and wall heating configurations were considered. Flow phenomena such as separation/reattachment were observed when two-buildings models were analyzed. Finally, three-dimensional flow structures, with some characteristic that are not observed in two-dimensional models, affecting the pollutant removal, were simulated in the last case, highlighting the relevance of model dimensionality. The wind flow and pollutant dispersion are investigated using a numerical model based on the finite element formulation utilized by some of the authors of this work, which is extended here to deal with problems of heat and mass transport in the urban micro-scale. Turbulence is reproduced using Large Eddy Simulation (LES) and thermal effects on the momentum equations are considered as a buoyancy force, according to Boussinesq approximation.     

Multimodal Interaction with BCL-2 Family Proteins Underlies the Proapoptotic Activity of PUMA BH3

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