全文获取类型
收费全文 | 383篇 |
免费 | 4篇 |
国内免费 | 4篇 |
专业分类
化学 | 270篇 |
晶体学 | 8篇 |
力学 | 7篇 |
数学 | 77篇 |
物理学 | 29篇 |
出版年
2021年 | 6篇 |
2018年 | 2篇 |
2017年 | 4篇 |
2016年 | 4篇 |
2015年 | 3篇 |
2014年 | 13篇 |
2013年 | 16篇 |
2012年 | 15篇 |
2011年 | 8篇 |
2010年 | 10篇 |
2009年 | 10篇 |
2008年 | 14篇 |
2007年 | 15篇 |
2006年 | 20篇 |
2005年 | 12篇 |
2004年 | 11篇 |
2003年 | 8篇 |
2002年 | 9篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 12篇 |
1998年 | 29篇 |
1997年 | 26篇 |
1996年 | 13篇 |
1995年 | 12篇 |
1994年 | 7篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 7篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1987年 | 7篇 |
1986年 | 2篇 |
1985年 | 8篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1977年 | 4篇 |
1976年 | 5篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 4篇 |
1970年 | 2篇 |
1969年 | 2篇 |
1968年 | 2篇 |
1964年 | 4篇 |
1963年 | 3篇 |
1962年 | 2篇 |
1954年 | 2篇 |
排序方式: 共有391条查询结果,搜索用时 15 毫秒
81.
Branko Grünbaum 《Discrete and Computational Geometry》1997,18(1):13-52
The study of the polyhedra (in Euclidean 3-space) in which faces may be self-intersecting polygons, and distinct faces may
intersect in various ways, was quite fashionable about a century ago. The Kepler—Poinsot regular polyhedra, and several of
their generalizations, were investigated about that time by Cayley, Wiener, Badoureau, Fedorov, Hess, Pitsch, and others;
the accumulated wisdom was presented in Max Brückner's well-known book Vielecke und Vielflache in 1900. Despite the intrinsic interest of the topic, and its relations to various other disciplines, there have been very
few additional investigations during the intervening century, except for discussions of uniform polyhedra. In particular,
there has been no mention or clarification of the many errors and other shortcomings of Brückner's book. One of our aims is
to point out the extent of these inadequacies; they are illustrated by a discussion of isogonal prismatoids, the investigation of which is our main objective. A prismatoid is a polyhedron having all its vertices in two parallel planes. Familiar examples are prisms and antiprisms. A polyhedron
P is isogonal if all its vertices form one transitivity class under isometric symmetries of P. Although these restrictions appear very severe, there exist many different kinds of isogonal prismatoids. Some general concepts
concerning polyhedra with possible self-intersections are presented, and several classes of isogonal prismatoids are discussed
in some detail.
Received April 5, 1995. 相似文献
82.
Branko Guberina Blaženka Melić 《The European Physical Journal C - Particles and Fields》1998,2(4):697-703
We have quantitatively reanalyzed the inclusive charmed-baryon decays. New ingredients are the Voloshin preasymptotic effects
in semileptonic decays and the Cabibbo-subleading contributions to both semileptonic and nonleptonic decays. It has been found
that the Cabbibo-subleading Voloshin contribution essentially improves the theoretical semileptonic branching ratio of , in agreement with experiment. The semileptonic branching ratios for and are found to be large, i.e., of the order of 20%. The lifetimes hierarchy is in a good qualitative and even quantitative
agreement with experiment except for the lifetime, which is somewhat smaller than the experimental value. Future measurements, especially measurements of the semileptonic
branching ratios for , and should be decisive for the check of this approach.
Received: 29 April 1997 / Revised version: 25 June 1997 / Published online: 20 February 1998 相似文献
83.
Integral Equations and Operator Theory - 相似文献
84.
85.
Branko S. Jursic 《Journal of heterocyclic chemistry》1997,34(5):1383-1386
Theoretical studies of the aspects of an azoxide addition to olefins is presented. The stability of the 1,2,3-oxadiazolidine ring is discussed in regard to its capability to undergo a retro cycloaddition reaction. The structural features necessary to increase the stability of the heterocycle is proposed and evaluated. The computational results are supported with experimental observations. 相似文献
86.
Ilija N. Cvijetić Miloš P. Pešić Miljana D. Todorov Branko J. Drakulić Ivan O. Juranić Tatjana Ž. Verbić Mire Zloh 《Structural chemistry》2018,29(2):423-434
Aryldiketo acids (ADKs) exhibit the variety of biological activities, mainly due to large affinity toward divalent metal ions. Metal complexation ability of ADKs, as well as interactions with proteins, depend on tautomeric form present in solution. The main aim of this study was to fully explore the tautomeric preferences of 4-phenyl-2,4-dioxobutanoic acid (4PDA), as ADKs representative, in aqueous media at different pH values. 1D and 2D NMR spectroscopy in combination with quantum chemical calculations was applied in order to better understand the tautomeric preferences of 4PDA. The data in highly acidic media are especially interesting since there are no such findings in the literature due to low solubility of ADKs in molecular form. At low pH values, where 4PDA is unionized, the most abundant tautomeric form is enol with keto group closer to phenyl ring. At higher pH values, mixture of two 4PDA ionic forms coexists in solution. Their ratio calculated according to NMR data fits the values predicted using two experimentally determined pK a values. Based on the complexity of 1H NMR spectrum of monoanionic 4PDA form, coexistence of two stable rotamers was assumed. In an alkaline media, 4PDA is mostly present in dianionic form. As π-electrons of dianion are delocalized over an entire keto-enol moiety, spectral distinction between tautomers was not possible. Quantum chemical calculations were used to predict relative stability of tautomers. The predictions were in good accordance with experimental results only in case when explicit water molecule was included in calculations. 相似文献
87.
Dijana Jelić Saša Zeljković Branko Škundrić Slavko Mentus 《Journal of Thermal Analysis and Calorimetry》2018,133(1):77-86
The present study reports the results of investigation on the role of metakaolin in the formation of ettringite in a model relevant to Portland cement. The model consists of ternary system (Trio) metakaolin–lime–gypsum. Five samples of defined ternary system were cured at different temperatures 20, 30, 40, 50 and 60 °C. Conduction calorimeter TAM AIR was mainly used to capture heat evolution at different temperatures. Thermoanalytical (simultaneous TGA/DSC) and X-ray diffraction methods were used to identify different products after curing. It results that ettringite is the main hydration product supplemented by calcium silicate and calcium aluminosilicate hydrates according to sample composition. The mechanism and kinetics of hydration, as displayed by calorimetric curves, depend on composition of samples and curing temperatures. Two main types of processes have been elucidated: reaction of aluminum ions with sulfate ones in the presence of calcium ions in aqueous solution to form ettringite supplemented by pozzolanic activity leading to the formation of calcium silicate and calcium aluminosilicate hydrates. Concomitant condensation of alumina and silica species and carbonation have influenced the course of hydration. Activation energy E a depends slightly on composition of ternary system. 相似文献
88.
Alkyl 2-(substituted cinnamoylamino)-3-dimethylaminopropenoates 5, prepared either from glycine ( 1 ) and substituted cinnamoyl chlorides 2 via oxazol-5(4H)-ones 4 , or from cinnamoylglycinate with t-butoxy-bisdimethylaminomethane, were transformed by nitrosation into 5-substituted-1,2,4-oxadiazole-3-carboxylates 8 . The formation of alkyl N-cinnamoyloxalic acid hydroxyimidic amides 7, which were isolated as intermediates, represent a novel synthesis of N-acyl substituted hydroxyimidic amides. 相似文献
89.
The hydrazones 3a,b , prepared from phenylhydrazine ( 1 ) and dialkyl 2‐oxopropane‐1,3‐dicarboxylate ( 2a,b ) were converted in concentrated sulfuric acid at ?5 °C into a mixture of alkyl (3‐carboxyindol‐2‐yl)acetates ( 5a,b ), and ethyl (5‐ethoxy‐1‐phenyl‐1H‐pyrazol‐3‐yl)acetate 6 . The hydrazone 8 , prepared from 1 and ethyl acetoacetate ( 7 ) was transformed under the same conditions into a mixture of five compounds: ethyl 2‐methylindol‐3‐carboxylate ( 9 ), 2‐methylindol‐3‐carboxylic acid ( 10 ), 2‐methylindol ( 11 ), 5‐ethoxy‐3‐methyl‐1‐phenyl‐1H‐pyrazole ( 12 ), and 3‐methyl‐1‐phenyl‐1H‐pyrazol‐5‐one ( 13 ). 相似文献
90.
Mario Merslavič Branko Stanovnik Miha Tišler 《Monatshefte für Chemie / Chemical Monthly》1985,116(12):1447-1458
New syntheses of oxazolo[4,5—d]pyridazine derivatives7 and11 were achieved by the cyclization of substituted N-pyridazin-5-ylformamide oximes6 and10. Under mild reaction conditions the transformations of the substituted amino group at position 2 of the oxazolo[4,5—d]pyridazine system7 occured to produce the compounds11, 14, and15, while under more drastic reaction conditions the nucleophilic attack at carbon at position 2 followed by the ring opening of the oxazole part of the molecule was observed to give the compounds13, 16, 17 and18.
Transformationen von N-Heteroarylformamidinen und N-Heteroarylformamidinoximen. Neue Synthesen und Transformationen von Oxazolo[4,5—d]pyridazinen
Zusammenfassung Mittels Cyclisierung substituierter N-Pyridazin-5-ylformamidoxime6 und10 wurden neue Synthesemöglichkeiten von Oxazolo[4,5—d]pyridazinderivaten erschlossen. Bei milden Reaktionsbedingungen trat Transformation der substituierten Aminogruppe an Position 2 des Oxazolo[4,5—d]pyridazin-Systems unter Bildung der Verbindungen11, 14 und15 ein, währenddessen unter drastischeren Reaktionsbedingungen ein nucleophiler Angriff am Kohlenstoff-2, gefolgt von einer Ringöffnung unter Bildung der Verbindungen13, 16, 17 und18 eintrat.相似文献