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排序方式: 共有163条查询结果,搜索用时 31 毫秒
11.
Kolar Tjaša Mušič Branka Korošec Romana Cerc Kokol Vanja 《Cellulose (London, England)》2021,28(14):9441-9460
Cellulose - Differently structured aluminum (tri/mono) hydroxide (Al(OH)3 /AlO(OH)) nanoparticles were prepared and used as thermal-management additives to microfibrillated cellulose (MFC),... 相似文献
12.
Branka M. Ladanyi 《Current Opinion in Colloid & Interface Science》2013,18(1):15-25
Recent developments in the computer simulation studies of the effects of counterions on the properties of ionic surfactant systems in contact with aqueous solution phase are discussed. The article deals with three types of systems: normal micelles, monolayers at the air/aqueous solution interface, and reverse micelles, i.e., water-in-oil microemulsions. 相似文献
13.
A study of crystal structures from the Cambridge Structural Database (CSD) and DFT calculations reveals that parallel pyridine–pyridine and benzene–pyridine interactions at large horizontal displacements (offsets) can be important, similar to parallel benzene–benzene interactions. In the crystal structures from the CSD preferred parallel pyridine–pyridine interactions were observed at a large horizontal displacement (4.0–6.0 Å) and not at an offset of 1.5 Å with the lowest calculated energy. The calculated interaction energies for pyridine–pyridine and benzene–pyridine dimers at a large offset (4.5 Å) are about 2.2 and 2.1 kcal mol?1, respectively. Substantial attraction at large offset values is a consequence of the balance between repulsion and dispersion. That is, dispersion at large offsets is reduced, however, repulsion is also reduced at large offsets, resulting in attractive interactions. 相似文献
14.
The He I and He II photoelectron spectra of 4-methylmorpholine, 4-morpholinecarbonitrile, and 4-morpholinepropionitrile have been measured. The electronic structure and heteroatom lone pair interactions, in particular, were analyzed with the aid of HeII/HeI intensity variations, comparison with the spectra of related compounds, and AM1 semiempirical calculations. We present an example of combined inductive and resonance interactions operating in the morpholine ring system. 相似文献
15.
The aim of this work was to investigate the influence of initial pH value (pH0) on the isothermal adsorption of Reactive Black 5 (RB5) dye on commercial powdered activated carbon. Four initial pH values were chosen for this experiment: pH0 = 2.00, 4.00, 8.00, and 10.00. In order to investigate the mechanism of adsorption kinetic, studies have been performed using pseudo-first-order and pseudo-second-order kinetic models as well as an intraparticle diffusion model. In addition, thermodynamic parameters of adsorption were determined for pH0 = 4.00. Results of this research showed that the initial pH value significantly influences the adsorption of RB5 dye onto activated carbon. The highest adsorption capacities (qe) and efficiencies of decolouration were observed for initial pH values of pH0 = 2.00 (qe = 246.0 mg g−1) and 10.00 (qe = 239.1 mg g−1) due to strong electrostatic interactions and attractive π···π interactions, respectively. It was also shown that the adsorption of RB5 dye on activated carbon at all initial pH values is kinetically controlled, assuming a pseudo-second-order model, and that intraparticle diffusion is not the only process that influences on the adsorption rate. 相似文献
16.
17.
Zhong-Zhi Yang Branka Kova
Edgar Heilbronner Jacques Lecoultre Chin Wing Chan Henry N. C. Wong Henning Hopf Fritz Vgtle 《Helvetica chimica acta》1987,70(2):299-307
The PE spectroscopic data for a series of [2.2]paracyclophanes with olefinic and/or aromatic bridges, and of a few related molecules are reported, together with tentative assignments based on simple MO models. 相似文献
18.
The existence of ferromagnetism in Zn-Mn-O semiconductor samples and dependence on the preparation condition were investigated. We systematically examined the samples with manganese concentration ranging from 0 to 10 at.%, prepared by a solid state reaction route using (ZnC2O4·2H2O)1−x and (MnC2O4·2H2O)x as precursors. Thermal treatment was carried out in air at temperatures ranging from 400 to 900 °C. The samples were investigated by X-ray diffraction, transmission electron microscopy, magnetization measurements and XPS spectroscopy. XPS surface composition, chemical analysis and depth profiling were successfully employed on powder revealing the chemical composition at the surface of the grains and underneath. The present investigation suggests that physical properties and observed room temperature ferromagnetism might be due to grain surface effects. It seems that the ferromagnetic phase is correlated with oxygen build up at the surface. 相似文献
19.
Aleksandra Radoičić Radivoj Petronijević Filip Andrić Živoslav Tešić 《液相色谱法及相关技术杂志》2017,40(5-6):297-303
ABSTRACTA new method for the extraction and quantitative determination of amygdalin has been proposed. Accelerated solvent extraction was applied for the extraction, and reversed-phase high-performance thin-layer chromatography method was developed, validated, and applied for the determination of amygdalin in the extracts of apricot, plum, almond, and peach kernels. The chromatographic system used was RP-18 silica, as stationary phase and acetonitrile/water (50:50, v/v), as mobile phase. Densitometric scanning was performed at 210 nm. The method was validated with respect to specificity, linearity, precision, and accuracy. The results showed that the peak area responses were linear within the concentration range of 2.5–50.0 µg/spot (R2 = 0.9984). The limit of quantification was 4.28 µg/spot, and the detection limit 1.28 µg/spot. The intra-day and inter-day reproducibility, in terms of %RSD, were in the range of 0.81–1.15 and 1.32–1.89, respectively. The accuracy data were in the range from 99.98 to 100.56%. The method is linear, quantitative and reproducible, and could be used as an efficient and economical green chromatographic procedure for the determination of amygdalin in the fruit kernel. 相似文献
20.
A.C. Branka Piotr Pieranski K.W. Wojciechowski 《Journal of Physics and Chemistry of Solids》1982,43(9):817-818
A system of N = 169 hard cyclic hexamers is studied by an experimental modelling method. Results obtained suggest phase transitions connected with the rotational degree of freedom. 相似文献