The L1 subshell orbital electron capture probability PL1 in the decay of 33.4 y 207Bi to the 2339.89 keV level in 207Pb is measured to be 0.518 ± 0.081 (95% confidence) by a new method in which L1 subshell characteristic X-rays in the Lγ X-ray peak are observed in an Xγt coincidence mode with 1770.23 keV γ-rays. The value of PL2is 0.047 ± 0.015 (95% confidence). From these results a value of QEC = 39-8+21 keV is obtained for capture transitions to the 2339.89 keV level. The absence of K-capture to this level also is established by absence of K X-rays in coincidence with 1770.23 keV γ-rays. 相似文献
An exchange-correlation potential model to be used in connection with the multiple scattering method is presented. Retaining the main advantages of the multiple scattering method with the Xα potential, particularly its low computational requirements, this new formalism does not require any adjustable parameter. Test calculations on the NiF64? system are reported and compared with experimental and ab initio results. 相似文献
In this paper, we study nonlinear embeddings between Banach spaces. More specifically, the goal of this paper is to study weaker versions of coarse and uniform embeddability, and to provide suggestive evidences that those weaker embeddings may be stronger than one would think. We do such by proving that many known results regarding coarse and uniform embeddability remain valid for those weaker notions of embeddability. 相似文献
In the phase separation occurring at the miscibility gap (at the spinodal region) of an alloy a discrete symmetry is spontaneously broken and a domain wall network is formed. Field theory simulations are often used to study the dynamics of topological defects networks appearing in different physical contexts. In this work, we focus on the dynamics of the two immiscible liquids appearing on the phase diagram of the Bi–Zn system, one of the basic systems of lead free solders. We use phase field simulations to quantitatively simulate the dynamics of the two liquids separation in the Bi–Zn system, at different temperatures and for different concentrations. We obtain the miscibility gap curve and the domain morphologies of the system as a function of time, temperature and component concentrations using simulations. 相似文献
The use of agricultural wastes for energy conversion has been widely studied as renewable and carbon neutral energy sources. This paper aims to evaluate the energetic potential of six agricultural wastes—sugarcane bagasse, bean pods, corn stover, pineapple crown leaves, white cotton and natural coloured cotton stalks, through their characterization and pyrolysis kinetic study. The energetic potential of biomasses was evaluated by ultimate and proximate analysis, higher heating value (HHV), apparent density, and kinetic parameters of conversion and apparent activation energy (Ea) determined by Model-Free kinetics though thermogravimetric analysis data. The results indicate energetic density for dry basis biomasses, such as moisture content less than 7%, volatiles higher than 77% and moderate ash content. The HHVs were higher for the biomass with low O:C ratio. The Ea values increased with increasing O:C ratio and were also influenced by the biomass ash content. Among the studied biomasses, PCL are less explored for energy application, although the results confirm its potential for application in thermochemical processes such as pyrolysis or combustion.
Quantitative nuclear magnetic resonance (qNMR) is an analytical technique that offers numerous advantages in pharmaceutical applications including minimum sample preparation and rapid data collection times with no need for response factor corrections, being a powerful tool for assaying drug content in both drug discovery and early drug development. In the present work, we have applied qNMR, using both the internal standard and the electronic reference to access in vivo concentrations 2 calibration methods, to assess the purity of RI76, a novel antifungal drug candidate. NMR acquisition and processing parameters were optimized in order to obtain spectra with intense, well-resolved signals of completely relaxed nuclei. The analytical method was validated following current guidelines, demonstrating selectivity, linearity, accuracy, precision, and robustness. The calibration approaches were statistically compared, and no significant difference was observed when comparing the obtained results and their dispersion in terms of relative standard deviation. The proposed qNMR method may, therefore, be used for both qualitative and quantitative assessments of RI76 in early drug development and for characterization of this compound. 相似文献
The structures and solid-state dynamics of the supramolecular salts of the general formula [(12-crown-4)2 ⋅ DABCOH2](X)2 (where DABCO=1,4-diazabicyclo[2.2.2]octane, X=BF4, ClO4) have been investigated as a function of temperature (from 100 to 360 K) and pressure (up to 3.4 GPa), through the combination of variable-temperature and variable-pressure XRD techniques and variable-temperature solid-state NMR spectroscopy. The two salts are isomorphous and crystallize in the enantiomeric space groups P3221 and P3121. All building blocks composing the supramolecular complex display dynamic processes at ambient temperature and pressure. It has been demonstrated that the motion of the crown ethers is maintained on lowering the temperature (down to 100 K) or on increasing the pressure (up to 1.5 GPa) thanks to the correlation between neighboring molecules, which mesh and rotate in a concerted manner similar to spiral gears. Above 1.55 GPa, a collapse-type transition to a lower-symmetry ordered structure, not attainable at a temperature of 100 K, takes place, proving, thus, that the pressure acts as the means to couple and decouple the gears. The relationship between temperature and pressure effects on molecular motion in the solid state has also been discussed. 相似文献