Plastic flow and dislocation structure at small strains in OFHC copper deformed in tension,torsion and combined tension-torsion

OFHC copper specimens of 39 μm grain size were deformed to small strains (up to 8%) in tension, torsion and combined tension-torsion at 300 K and the resulting dislocation structures, distributions and densities were determined using transmission electron microscopy. Employing the von Mises yield criterion and the plastic-work hypothesis good agreement was obtained for the three testing conditions for (i) equivalent stress $\text{}\text{?}$gs vs equivalent strain $\text{}\text{?}$g3^p curves, (ii) the dislocation structure, distribution and density ρ as a function of $\text{}\text{?}$g3^p, and (iii) $\text{}\text{?}$gs as a function of $\text{ρ}\text{1}\text{2}$. Furthermore, upon comparing the $\text{}\text{?}$gs vs $\text{ρ}\text{1}\text{2}$ curve for polycrystalline copper with the τ_RSS vs $\text{ρ}\text{1}\text{2}$ curve for single crystals, an average Taylor factor M= (σ/τ_RSS) of approximately 3.2 was obtained, which is in good accord with that predicted theoretically for FCC metals. Almost equally good correlations for the stressstrain curves and for the dislocation density were obtained on the basis of maximum shear stress τ_max and maximum shear strain γ^p_max as on the basis of $\text{}\text{?}$gs and $\text{}\text{?}$g3^P. Therefore, the present results do not permit a positive decision on the question whether the dislocation density correlates better with $\text{}\text{?}$gs and $\text{}\text{?}$g3^P or with τ_max and γ^P_max.A single test in which the direction of straining in torsion was reversed yielded a density and distribution of dislocations (and a corresponding value of $\text{}\text{?}$gs) equivalent to those that developed at a smaller strain in unidirectional straining.     

求解双参数层状地基模型的积分变换法

计算弹性地基梁板时，大都采用文克尔地基模型。由于该模型过于简化，不能正确反映土的工程性质，为此本文提出了一种双参数层状地基模型。该模型由一系列的弹性层组成，并对每一层中应力应变分布做了假设。通过积分变换的方法可以求出每一层表面处位移与力之间的关系，进而形成层刚度矩阵。按照有限元法的原理，可把每一层的刚度矩阵凝聚成总体刚度矩阵进行求解。本文模型是V1azov模型的延伸和发展。通过与V1azov模型计算结果的比较，证明本文方法是正确的。并且本文得到了荷载作用于层状模型内部时的解答，为将双参数地基模型用于桩基分析打下了理论基础。     

Synthesis, spectroscopic and electrochemical property of an unsymmetrical porphyrin and its Zn compound

<正>In this article,a new 5-(p-maleicaminophenyl)-10,15,20-triphenylporphyrin(H_2P) and relative zinc compound(ZnP) were synthesized and characterized by means of elemental analyses,UV-vis,IR,MS and ~1H NMR spectroscopies.Furthermore,we have investigated the fluorescence spectroscopy of these compounds.The oxidation and reduction properties of the compounds were studied by the cyclic voltarnmetry,the oxidation-reduction potentials were obtained.     

Convenient synthesis of chiral H4-BINOL via direct hydrogenation of BINOL

<正>A simple,highly effective hydrogenation of chiral BINOL to provide H_4-BINOL in multigram scale with good yield(up to 78% yield) was developed.A series of heterogeneous catalysts was tested in the hydrogenation;;the best result was obtained with 5%Pd/ C in EtOH under the H_2 pressure of 50 bar for 2 h.This method is a more useful method for practical synthesis of optically pure H_4- BINOL than other available methods.     

Catalytic oxidation of soot particulates over MnOx-CeO2 oxides prepared by complexation-combustion method

MnOx-CeO2 oxides prepared by complexation-combustion method were used for soot oxidation. The highest conversion rate of soot was obtained on a MnOx-CeO2 oxide prepared under mild acid condition of pH = 4, where the oxidation temperature corresponding to maximum activity was decreased more than 150℃ compared with that of un-catalytic soot oxidation. The structure and property of the catalysts were investigated by X-ray powder diffraction (XRD) and temperature programmed reduction (TPR). The results indicate...     

Vapor–liquid equilibria and density measurement for binary mixtures of o-xylene + NMF, m-xylene + NMF and p-xylene + NMF at 333.15 K, 343.15 K and 353.15 K from 0 kPa to 101.3 kPa

Isothermal vapor–liquid equilibria at 333.15 K, 343.15 K and 353.15 K for three binary mixtures of o-xylene, m-xylene and p-xylene individually mixed with N-methylformamide (NMF), have been obtained at pressures ranged from 0 kPa to 101.3 kPa over the whole composition range. The Wilson, NRTL and UNIQUAC activity coefficient models have been employed to correlate experimental pressures and liquid mole fractions. The non-ideal behavior of the vapor phase has been considered by using the Peng–Robinson equation of state in calculating the vapor mole fraction. Liquid and vapor densities were measured by using two vibrating tube densitometers. The excess molar volumes of the liquid phase were also determined. Three systems of o-xylene + NMF, m-xylene + NMF and p-xylene + NMF mixtures present large positive deviations from the ideal solution and belong to endothermic mixings because their excess Gibbs energies are positive. Temperature dependent intermolecular parameters in the NRTL model correlation were finally obtained in this study.     

大黄酸键合硅胶固定相的简便制备及色谱性能评价

以大黄酸为原料,γ-氨丙基三乙氧基硅烷(KH-550)为偶联剂,简便制备了一种新型羧基键合硅胶固定相(RBSP),并用红外光谱、热重分析及元素分析对其结构进行表征.考察了流动相中甲醇含量对键合固定相色谱性能的影响,并以含酸性、中性和碱性化合物的混合物为溶质,评价了RBSP的色谱性能.以甲醇-水为流动相,用C18柱作参比,研究了该键合硅胶作为HPLC固定相对两种大豆异黄酮化合物和几种生物碱基的分离,并对其色谱分离机理进行了初步探讨.实验结果表明,该固定相(RBSP)具有较好的反相色谱性能,同时由于键合相中含有酚羟基及酰胺基团,能为多种溶质提供作用位点,对极性化合物的分离具有明显优势,且分离速度快,可有效用于极性化合物的分离分析.     

An investigation of the microstructure,optical and electrical properties of ZITO thin film using the sol–gel method

The multi-compound ZITO transparent conductive oxide (TCO) thin films were synthesized using the sol–gel method. The ZITO thin films with various volume ratios of ZnO to ITO (1:1, 2:1 and 9:1) were crystallized at different temperatures (600–700 °C). The results showed that the crystalline characteristics and optical transmittance were mainly dependent on ITO content and crystallization. Notably, the 650 °C Z₉ITO film not only had better conductivity but also possessed excellent optical transmittance. In addition, the surface roughness of the ZITO films and optoelectric properties of IZO (indium doped ZnO) films were analyzed to confirm the contribution of indium dopants on the optical transmittance. Also, the ZITO films were subjected to the effects of indium and tin dopants and this improved the related characteristics of ZnO films.     

Glucose concentration determination based on silica sol-gel encapsulated glucose oxidase optical biosensor arrays

Optical biosensor arrays for rapidly determining the glucose concentrations in a large number of beverage and blood samples were developed by immobilizing glucose oxidase (GOD) on oxygen sensor layer. Glucose oxidase was first encapsulated in silica based gels through sol-gel approach and then immobilized on 96-well microarrays integrated with oxygen sensing film at the bottom. The oxygen sensing film was made of an organically modified silica film (ORMOSIL) doped with tris(4,7-diphenyl-1,10-phenanthroline) ruthenium dichloride (Ru(dpp)₃Cl₂). The oxidation reaction of glucose by glucose oxidase could be monitored through fluorescence intensity enhancement due to the oxygen consumption in the reaction. The luminescence changing rate evaluated by the dynamic transient method (DTM) was correlated with the glucose concentration with the wide linear range from 0.1 to 5.0 mM (Y = 13.28X − 0.128, R = 0.9968) and low detection limit (0.06 mM). The effects of pH and coexisting ions were systemically studied. The results showed that the optical biosensor arrays worked under a wide range of pH value, and normal interfering species such as Na⁺, K⁺, Cl⁻, PO₄³⁻, and ascorbic acid did not cause apparent interference on the measurement. The activity of glucose oxidase was mostly retained even after 2-month storage, indicating their long-term stability.     

A two-photon excited luminescence of water-soluble rhodamine-platinum(II) complex: fluorescent probe specific for Hg2+ detection in live cell

The first example of cyclometalated platinum(II)-containing rhodamine probe (1) with two-photon induced luminescent properties was synthesized and investigated for mercury detection. A highly selective color change of 1, from light yellow to pink, is observed only in the presence of Hg²⁺ due to the formation of 1,3,4-oxadiazole ring in 2. This selectivity of Hg²⁺ with color changes can be observed easily by the naked-eye. Meanwhile, a remarkable turn-on and selective 20-fold fluorescent enhancement of 1 upon binding with Hg²⁺ over the other tested metal ions was observed. The water-soluble probe 1 was successfully applied in the visualizing of the site of Hg²⁺ accumulation as well as estimating of trace amounts of mercury ions in live HeLa cells by two-photon microscopy.