全文获取类型
收费全文 | 139篇 |
免费 | 4篇 |
国内免费 | 2篇 |
专业分类
化学 | 84篇 |
晶体学 | 4篇 |
力学 | 11篇 |
数学 | 21篇 |
物理学 | 25篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 8篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 6篇 |
2014年 | 9篇 |
2013年 | 18篇 |
2012年 | 10篇 |
2011年 | 11篇 |
2010年 | 5篇 |
2009年 | 5篇 |
2008年 | 9篇 |
2007年 | 5篇 |
2006年 | 5篇 |
2005年 | 9篇 |
2004年 | 3篇 |
2003年 | 4篇 |
2002年 | 3篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1989年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1980年 | 2篇 |
排序方式: 共有145条查询结果,搜索用时 31 毫秒
101.
Alkyl α-(hydroxymethyl)acrylates are prepared in high yields on a synthetic scale by hydroxymethylation of the corresponding acrylates using 30% aqueous formaldehyde in THF or DME as solvent and DABCO as the catalyst. 相似文献
102.
103.
Tahani M. Almutairi Nadjet Rezki Mohamed Reda Aouad Mohamed Hagar Basant A. Bakr Moaaz T. Hamed Maha Khairy Hassen Bassma H. Elwakil Esraa Abdelhamid Moneer 《Molecules (Basel, Switzerland)》2022,27(7)
Nitrogen-containing atoms in their core structures have been exclusive building blocks in drug discovery and development. One of the most significant and well-known heterocycles is the 1,3,4-thidiazole nucleus, which is found in a wide range of natural products and therapeutic agents. In the present work, certain tris-1,3,4-thiadiazole derivatives (6, 7) were synthesized through a multi-step synthesis approach. All synthesized compounds were characterized using different spectroscopic tools. Previously, thiadiazole compounds as anti-Toxoplasma gondii agents have been conducted and reported in vitro. However, this is the first study to test the anti-Toxoplasma gondii activity of manufactured molecular hybrids thiadiazole in an infected mouse model with the acute RH strain of T. gondii. All the observed results demonstrated compound (7)’s powerful activity, with a considerable reduction in the parasite count reaching 82.6% in brain tissues, followed by liver and spleen tissues (65.35 and 64.81%, respectively). Inflammatory and anti-inflammatory cytokines assessments proved that Compound 7 possesses potent antiparasitic effect. Furthermore, docking tests against TgCDPK1 and ROP18 kinase (two major enzymes involved in parasite invasion and egression) demonstrated compound 7’s higher potency compared to compound 6 and megazol. According to the mentioned results, tris-1,3,4-thiadiazole derivatives under test can be employed as potent antiparasitic agents against the acute RH strain of T. gondii. 相似文献
104.
Samia Yahyaoui Rached Ben Hassen Bruno Donnadieu Jean‐Claude Daran Abdelhamid Ben Salah 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(11):i109-i111
The title compound, namely octaaquaytterbium(III) aquanonachlorotricadmate(II) hexahydrate, [Yb(H2O)8][Cd3Cl9(H2O)]·6H2O, was prepared by evaporation at 278 K from an aqueous solution of the ternary system YbCl3–CdCl2–H2O and was characterized by elemental chemical analysis and by X‐ray powder and single‐crystal diffraction studies. The crystal structure can be viewed as being built from layers of double chains of CdCl6 and CdCl5(H2O) octahedra separated by antiprismatic [Yb(H2O)8]3+ cations. The stabilization of the structure is ensured by O—H⋯O and O—H⋯Cl hydrogen bonds. A comparison with the structures of SrCd2Cl6·8H2O and CeCd4Cl11·13H2O is presented. 相似文献
105.
Ameni Brahmia Riadh Marzouki Jan Rohlicek Ahmad Irfan Abdullah G. Al-Sehemi Rached Ben Hassen 《Acta Crystallographica. Section C, Structural Chemistry》2019,75(12):1617-1627
The new aminocoumarin derivatives 3‐[1‐(3‐hydroxyanilino)ethylidene]‐3H‐chromene‐2,4‐dione, ( 1 ), 3‐[1‐(4‐hydroxyanilino)ethylidene]‐3H‐chromene‐2,4‐dione, ( 2 ), and 3‐[1‐(2‐hydroxyanilino)ethylidene]‐3H‐chromene‐2,4‐dione, ( 3 ), all C17H13NO4, were synthesized by reacting an equimolar amount of 3‐acetyl‐4‐hydroxycoumarin and the corresponding aminophenol in absolute ethanol. Structural and spectroscopic analysis of these phases revealed that derivatives ( 1 ) and ( 2 ) are isomers of previously reported ( 3 ) [Brahmia et al. (2013). Acta Cryst. E 69 , o1296]. The crystal structures of meta derivative ( 1 ) and para derivative ( 2 ) were ab initio determined from powder X‐ray diffraction data using the direct‐space approach. Both ( 1 ) and ( 2 ) adopt the orthorhombic space group P212121. These isomers show hydrogen bonds and rich π–π stacking, together with π…H interactions, which are built by conjugated systems of coumarin and phenol rings. In the crystalline lattice, the packing of ( 1 ) and ( 3 ) are mainly stabilized through O—H…O hydrogen bonding between neighbouring coumarin molecules, while hydrogen bonds between coumarin and water molecules build the stable crystal structure of derivative ( 2 ). A big similarity in the skeletons of the IR spectra of these isomers was noticed. Derivative ( 2 ) exhibits two weak bands which were not present in the spectra of the other two derivatives, at 2370 and 2948 cm?1, which can be assigned to the O—H vibrations of the solvent (H2O) trapped in the structure of ( 2 ). These aminocoumarin derivatives display absorption maxima in the visible region, attributed to π–π delocalization involving the whole electronic system of the compounds with a considerable charge‐transfer character originating from the aminophenyl ring and pointing towards the coumarin system which is characterized by a high electron‐accepting character. Additionally, the isolated molecular ground‐state geometries were optimized at the PBE0/TZP level and the electronic properties, molecular electrostatic potential and Hirshfeld charges were determined. 相似文献
106.
Hassen Suleman Esmael MOHAMMED Tongtong LI Huixiang CHEN 《Frontiers of Mathematics in China》2015,10(6):1415
We study the Hopf *-algebra structures on the Hopf algebra H(1, q) over ? . It is shown that H(1, q) is a Hopf *-algebra if and only if |q| = 1 or q is a real number. Then the Hopf *-algebra structures on H(1, q) are classified up to the equivalence of Hopf *-algebra structures. 相似文献
107.
Nonlinear Dynamics - The objective of the present study is to examine the effect of nonlinearity on the efficiency enhancement of a capacitive energy harvester. The model consists of a cantilever... 相似文献
108.
Darda Sharif Abu Gabbar Hossam A. Damideh Vahid Aboughaly Mohamed Hassen Isaac 《Journal of Radioanalytical and Nuclear Chemistry》2021,329(1):15-31
Journal of Radioanalytical and Nuclear Chemistry - Radioactive wastes are the byproduct of nuclear technology and industrial processes. Unlike any other waste stream, radioactive wastes are... 相似文献
109.
Samia Yahyaoui Rached Ben Hassen Vaclav Petí
ek Michal Duek Abdelhamid Ben Salah 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(3):i24-i26
The ternary system SrBr2–CdBr2–H2O was investigated at room temperature. The title phase, SrCd2Br6·8H2O, has been isolated from this system and its structure determined by single‐crystal X‐ray diffraction. The structure consists of infinite double chains of CdBr6 octahedra and chains of Sr(H2O)9 polyhedra packed along the b axis. The interaction between these two isolated chains occurs through O—H⃛O and O—H⃛Br hydrogen bonds. The structure is compared with that of SrCd2Cl6·8H2O. 相似文献
110.