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61.
G. M. Gavrilova S. V. Amosova B. A. Trofimov E. I. Kositsyna B. Z. Pertsikov V. I. Gostevskaya G. K. Musorin M. L. Al'pert N. M. Borodina 《Chemistry of Heterocyclic Compounds》1986,22(5):572-577
The heterocyclization of divinyl sulfide with N-monoalkyl- and N-monoarylthioureas and 2-vinyl propen-1-yl sulfide and di(propen-1-yl) sulfide with thiourea in the presence of equimolar amounts of inorganic acids leads to new nitrogen heterocycles 2H,6H-2,6-dialkyl-4-alkylamino- and 2H,6H-2,6-dialkyl-4-imino-5-N-phenyl-1,3,5-dithiazines in salt form. The action of bases on the diathiazine salts gives the corresponding 1,3,5-dithiazines. These heterocycles were found more sensitive to the action of nucleophiles causing ring opening than 1,3,5-dithiazines unsubstituted at the nitrogen atom.For 14, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 697–703, May, 1986. 相似文献
62.
Kuznetsova IE Zaitsev BD Borodina IA Teplyh AA Shurygin VV Joshi SG 《Ultrasonics》2004,42(1-9):179-182
This paper presents theoretical investigation of higher order acoustic plate waves propagating in single crystals of lithium niobate. The dependencies of wave velocity and electromechanical coupling coefficient of antisymmetric, symmetric, and shear horizontal modes on the parameter hf (h=plate thickness, f=operating frequency) are calculated as a function of propagation direction on X-, Y-, and Z-cut lithium niobate plates. It is found that several modes can provide values of K2 that are much greater than can be obtained with surface acoustic waves (SAWs). For example, K2 as high as 0.26 and 0.38 can be obtained from SH1 and A2 modes, respectively. This compares with a maximum value of K2=0.055 for SAWs. It is further shown that there are several crystal cut and propagation directions that can allow efficient excitation and detection of a single mode with minimal interference due to other modes. 相似文献
63.
Effects of Coke Deposits on the Catalytic Performance of Large Zeolite H‐ZSM‐5 Crystals during Alcohol‐to‐Hydrocarbon Reactions as Investigated by a Combination of Optical Spectroscopy and Microscopy
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Dr. Emily C. Nordvang Dr. Elena Borodina Dr. Javier Ruiz‐Martínez Prof. Dr. Rasmus Fehrmann Prof. Dr. Bert M. Weckhuysen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(48):17324-17335
The catalytic activity of large zeolite H‐ZSM‐5 crystals in methanol (MTO) and ethanol‐to‐olefins (ETO) conversions was investigated and, using operando UV/Vis measurements, the catalytic activity and deactivation was correlated with the formation of coke. These findings were related to in situ single crystal UV/Vis and confocal fluorescence micro‐spectroscopy, allowing the observation of the spatiotemporal formation of intermediates and coke species during the MTO and ETO conversions. It was observed that rapid deactivation at elevated temperatures was due to the fast formation of aromatics at the periphery of the H‐ZSM‐5 crystals, which are transformed into more poly‐aromatic coke species at the external surface, preventing the diffusion of reactants and products into and out of the H‐ZSM‐5 crystal. Furthermore, we were able to correlate the operando UV/Vis spectroscopy results observed during catalytic testing with the single crystal in situ results. 相似文献
64.
L. M. Delitsin V. A. Sinelshchikov V. M. Batenin T. I. Borodina G. E. Valiano 《Doklady Chemistry》2015,465(2):303-307
In the course of segregation smelting of rare-earth and rare metal raw materials with a fluxing agent (NaF), two immiscible melts form, one of which is a silicate melt and the other is a phosphate–salt melt. The silicate melt is enriched with Fe2O3, Al2O3, SiO2, and Nb2O5, and the phosphate–salt melt is dominated by P2O5, TR2O3, Sc2O3, and Y2O3, and also with Ca, Sr, and Ba oxides. Chemical reactions between lanthanum orthophosphate and sodium fluoride in the LaPO4–NaF system were studied for developing a technology for processing the phosphate–salt (rare-earth metal) melt. It was found that a metathesis reaction gives double phosphate Na3La[PO4]2 and binary fluoride NaLaF4. The products of crystallization of melts in the LaPO4–NaF system decompose in weak mineral acids unlike those in conventional technology for processing monazite raw material. 相似文献
65.
Yu. V. Borodina 《Moscow University Mathematics Bulletin》2007,62(4):163-167
A new method for synthesis of easy tested diagrams of functional elements in the basis {&;, ∨, ?} is proposed for systems of m Boolean functions differing from constants and representable as disjunctive normal forms containing l variables x 1,...,x l , l > 0, without negations and the other variables x l+1,...,x n with negations only. All faults are assumed to be stack-at-1 faults at the outputs of elements. It is proved that the length of a complete verification test is not greater than min {m, l} for such diagrams. 相似文献
66.
67.
MV Muftakhov YV Vasil'ev VA Mazunov 《Rapid communications in mass spectrometry : RCM》1999,13(12):1104-1108
Appearance energies of [M-H](-) ions from carbonyl compounds R-CO-R' (R,R' = H, CH(3), NH(2), OH) have been measured by means of negative ion mass spectrometry in resonant electron capture mode. Values of electron affinity of the corresponding radicals, CH(2)&dbond;C(X)O, NH&dbond;C(X)O and O&dbond;C(X)O, have been determined. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
68.
Svetlana V. Martynovskaya Arsalan B. Budaev Igor A. Ushakov Tatyana N. Borodina Andrey V. Ivanov 《Molecules (Basel, Switzerland)》2022,27(8)
This article shows that two extremely important families of fused heterocyclic assemblies, namely 6-methylbenzo[4,5]imidazo[1,2-a]pyrrolo[2,1-c]pyrazine and 5a-methyl-5a,6-dihydro-5H,12H-benzo[4,5]imidazo[1,2-a]pyrrolo[1,2-d]pyrazine, can be synthesized from only two available building blocks (N-allenylpyrrole-2-carbaldehyde and o-phenylenediamine) by controlling only one reaction parameter (water content of the medium). It should be emphasized that the latter class of compounds (with an a/d arrangement) is previously unknown. If the allene group is introduced not into the starting compound, but during the reaction (in superbase media), a heterocyclic ensemble, 5-methylbenzo[4,5]imidazo[1,2-a]pyrrolo[2,1-c]pyrazines, with a different position of the methyl group is formed. 相似文献
69.
Igor B. Rozentsveig Valentina S. Nikonova Victor V. Manuilov Igor A. Ushakov Tatyana N. Borodina Vladimir I. Smirnov Nikolay A. Korchevin 《Molecules (Basel, Switzerland)》2022,27(20)
The article is devoted to heterocyclization of bis(2-chloroprop-2-en-1-yl)sulfide which proceeds in hydrazine hydrate–alkali medium and leads to formation of thiophene and pyrrole derivatives: previously described 4,5,9,10-tetrahydrocycloocta[1,2-c;5,8-c’]dithiophene, as well as unknown hydrazone of 5-methylidene-3-methyldihydrothiophen-2-one and 1-amino-2-(propynylsulfanylpropenylsulfanyl)-3,5-dimethylpyrrole. Tentative mechanisms for the formation of the heterocyclic products are discussed. Obtained hydrazone of 5-methylidene-3-methyldihydrothiophen-2-one was used for the synthesis of a range of azine derivatives and in oxidation process with SeO2. The found reactions open up expedient approaches to the formation of various hardly accessible thiophene and pyrrole compounds from 2,3-dichloropropene and elemental sulfur as starting reagents. 相似文献
70.
K. Tsukada P. Achenbach C. Ayerbe Gayoso R. Böhm O. Borodina D. Bosnar V. Bozkurt L. Debenjak M. Distler A. Esser I. Friščić Y. Fujii T. Gogami M. Gomez O. Hashimoto S. Hirose E. Kim A. Margaryan H. Merkel U. Müller S. Nagao S. N. Nakamura J. Pochodzalla C. Rappold J. Reinhold A. Sanchez Lorente T. Saito B. S. Schlimme M. Schoth F. Schulz C. Sfienti S. Širca L. Tang 《Few-Body Systems》2013,54(1-4):375-379
The investigation of light hypernuclei is quite important for understanding the basic YN interaction and the mechanism of hypernuclear structure. We started the commissioning of the decay pion spectroscopy of light hypernuclei at MAMI-C in 2011. In order to realize the K+ tagging efficiently, some detectors on KAOS spectrometer were upgraded or newly installed. The existing and well-studied spectrometers, SpekA, SpekC were used as pion spectrometers. The analysis is ongoing to estimate the detectors performance and develop the spectrometers for future experiments with higher beam intensity. The preliminary results of the particle identification are presented in this article. 相似文献