全文获取类型
收费全文 | 334篇 |
免费 | 1篇 |
专业分类
化学 | 114篇 |
晶体学 | 2篇 |
力学 | 21篇 |
数学 | 48篇 |
物理学 | 150篇 |
出版年
2022年 | 6篇 |
2021年 | 6篇 |
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 6篇 |
2017年 | 9篇 |
2016年 | 9篇 |
2015年 | 10篇 |
2014年 | 6篇 |
2013年 | 17篇 |
2012年 | 10篇 |
2011年 | 16篇 |
2010年 | 17篇 |
2009年 | 17篇 |
2008年 | 10篇 |
2007年 | 11篇 |
2006年 | 14篇 |
2005年 | 18篇 |
2004年 | 13篇 |
2003年 | 13篇 |
2002年 | 8篇 |
2001年 | 10篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 5篇 |
1997年 | 7篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 6篇 |
1991年 | 6篇 |
1990年 | 9篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1983年 | 3篇 |
1981年 | 3篇 |
1978年 | 2篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1972年 | 4篇 |
1971年 | 2篇 |
1970年 | 2篇 |
1969年 | 4篇 |
1968年 | 2篇 |
1967年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有335条查询结果,搜索用时 31 毫秒
61.
A. A. Borisenko 《Mathematical Notes》2016,100(3-4):526-530
It is proved that a real complete convex Kähler submanifold in Euclidean space splits as a metric product of two-dimensional surfaces of positive Gaussian curvature in Euclidean 3-space and a Euclidean subspace. A theorem of V. K. Beloshapka and S. N. Bychkov is generalized to the case of convex submanifolds of any codimension. 相似文献
62.
63.
Shao-Ju Shih Lan-Yun Shery Chang Chin-Yi Chen Konstantin B. Borisenko David J. H. Cockayne 《Journal of nanoparticle research》2009,11(8):2145-2152
The microstructure and geometry of yttrium-doped ceria particles, synthesized by spray pyrolysis (SP), were characterized
by transmission electron microscopy, and the distribution of yttrium was investigated by energy-dispersive X-ray spectroscopy
(EDX). The yttrium distribution was investigated by considering an electron interaction volume and geometry of the particle
in an EDX profile analysis. Two models, linear and non-linear, for the yttrium concentration gradient were tested against
the experimental EDX data for hollow particles. The results showed that the linear concentration distribution of yttrium fits
the EDX profiles appreciably better than the non-linear concentration gradient model. This suggests that yttrium distribution
is mainly controlled by the different diffusion rates of the precursors from the centre to the surface of the particle, which
could be related to their different solubilities, during the heating process in SP. 相似文献
64.
AlexeiD. Averin OlesyaA. Ulanovskaya IlyaA. Fedotenko AnatoliiA. Borisenko MarinaV. Serebryakova IrinaP. Beletskaya 《Helvetica chimica acta》2005,88(7):1983-2002
Pd‐Catalyzed amination of 3,5‐dibromo‐ and 3,5‐dichloropyridine ( 1a and 1b , resp.) with linear polyamines 2 leads to the formation of a new family of pyridine‐containing macrocycles 3 with an ‘exo’‐oriented pyridine N‐atom (Schemes 1 and 2). The dependence of the macrocycle yield on the nature of the halogen atom, the length of the polyamine chain and C/N atom ratio, and the composition of the catalytic system is studied. The synthesis of mono‐ and bis(5‐halopyridin‐3‐yl)‐substituted polyamines 4, 5, 8, 9 , and of 3,5‐bis(polyamino)‐substituted pyridines 6 is described (Schemes 3 and 4), and the use of these compounds as intermediates on the way to the macrocycles 7, 16 , and 18 with larger cavity (‘cyclodimers’ and ‘cyclotrimers’) is demonstrated (Schemes 5–10). 相似文献
65.
E. D. Matveeva T. A. Podrugina I. N. Kolesnikova A. A. Borisenko N. S. Zefirov 《Russian Chemical Bulletin》2009,58(1):119-125
6h-Aminophosphonates containing alicyclic, aromatic, and heterocyclic fragments were obtained in high yields by the Kabachnick—Fields
reaction of the corresponding carbonyl compounds with 2-, 3- and 4-aminopyridines and diethyl phosphite using tetra- tert-butyl- phthalocyanine aluminum chloride as the catalyst. 2-, 3-, 4-Aminopyridines were found to vary in their reactivity
with ketones and diethyl phosphite in the catalytic three-component one-pot process. 相似文献
66.
Hnyk D Bühl M Holub J Hayes SA Wann DA Mackie ID Borisenko KB Robertson HE Rankin DW 《Inorganic chemistry》2006,45(15):6014-6019
The molecular structures of the three heterodecaboranes arachno-6,9-C2B8H14, arachno-6,9-N2B8H12, and arachno-6,9-Se2B8H10 have been determined by ab initio MO theory. In addition, the structure of arachno-6,9-C2B8H14 was experimentally determined using gas-phase electron diffraction (GED). The accuracy of all four of these structures has been confirmed by the good agreement of the (11)B chemical shifts calculated at the GIAO-MP2 level with the experimental values. A comparison of the GIAO-HF and GIAO-MP2 methods shows that for these heteroborane clusters, electron correlation effects on the computed delta((11)B) values are quite substantial and that it is necessary to go beyond the HF level in the NMR computation. 相似文献
67.
I. A. Semerikov I. V. Zalivako A. S. Borisenko K. Y. Khabarova N. N. Kolachevsky 《Journal of Russian Laser Research》2018,39(6):568-574
We propose a method for EIT ground state cooling of 171Yb+ ion, which involves three light fields with detuning on a MHz scale. The steady-state mean vibrational quantum number is calculated to be less than 0.005. Efficient cooling is achievable in a motional-mode frequency range of 2π · (1.5 ± 0.5 MHz). 相似文献
68.
Konstantin B. Borisenko Yixin Chen Se Ahn Song Duc Nguyen-Manh David J.H. Cockayne 《Journal of Non》2009,355(43-44):2122-2126
Reverse Monte Carlo refinements using electron diffraction data and density functional theory calculations of the local atomic structure of amorphous Ge2Sb2Te5 confirm presence of a noticeable number of four-membered rings with the general Ge(Sb)TeGe(Sb)Te composition similar to the building blocks of its cubic crystalline phase. The persistence of these rings, as well as the presence of the medium range order at the scale of about 1 nm, suggests that the amorphization/crystallization transition in Ge2Sb2Te5 can be modelled with a concerted rotation of the sheets of atom-squares in {1 0 0} faces of cubic subcells of the cubic crystalline phase, similar to Rubik’s cube rotation. This mechanism can produce large models of material that agree with a range of the previous experimental and theoretical studies and also with the experimental electron diffraction data. 相似文献
69.
A. M. Petrzhik V. V. Demidov G. A. Ovsyannikov I. V. Borisenko A. V. Shadrin 《Journal of Experimental and Theoretical Physics》2012,115(5):876-884
Magnetic bicrystal films and junctions of magnetic La0.67Sr0.33MnO3 (LSMO) and La0.67Ca0.33MnO3 (LCMO) films epitaxially grown on NdGaO3 substrates with the (110) planes of their two parts misoriented (tilted) at angles of 12°, 22°, 28°, and 38° are investigated. For comparison, bicrystal boundaries with a 90° misorientation of the axes of the NdGaO3 (110) planes were fabricated. The directions of the axes and the magnetic anisotropy constants of the films on both sides of the boundary are determined by two independent techniques of magnetic resonance spectroscopy. The magnetic misorientation of the axes in the substrate plane has been found to be much smaller than the crystallographic misorientation for tilted bicrystal boundaries, while the crystallographic and magnetic misorientation angles coincide for boundaries with rotation of the axes. An increase in the magnetoresistance and characteristic resistance of bicrystal junctions with increasing misorientation angle was observed experimentally. The magnetoresistance of bicrystal junctions has been calculated by taking into account the uniaxial anisotropy, which has allowed the contributions from the tunneling and anisotropic magnetoresistances to be separated. The largest tunneling magnetoresistance was observed on LCMO bicrystal junctions, in which the characteristic resistance of the boundary is higher than that in LSMO boundaries. 相似文献
70.
A. D. Pogrebnyak M. K. Kylyshkanov Yu. N. Tyurin A. Sh. Kaverina I. V. Yakushchenko A. A. Borisenko B. A. Postol’ny I. A. Kulik 《Technical Physics》2012,57(6):840-848
The results of new studies of creating protective oxide coatings based on Al2O3 (Si, Mn) and deposited onto aluminum alloys using electrolyte-plasma oxidation are presented. An analysis is performed by scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), X-ray diffraction, Rutherford backscattering of 4He+ and protons, nanoindentation, scratching, friction coefficient measurements, and acoustic emission measurements. The results demonstrate that the deposited coatings have a high quality, hardness, and wear resistance and a low thermal diffusivity. Apart from Al2O3, the coatings are found to have Si, Mn, C, and Ca. The stoichiometry of the coatings is determined. The density and hardness of the coatings are close to those of ??-Al2O3 in the coating on an Al-Cu (D-16) substrate, and these values of the coating on an Al-Mg (S006) are lower by a factor of 1.5. 相似文献