Highly Axial Magnetic Anisotropy in a N3O5 Dysprosium(III) Coordination Environment Generated by a Merocyanine Ligand

A spiropyran‐based switchable ligand isomerizes upon reaction with lanthanide(III) precursors to generate complexes with an unusual N₃O₅ coordination sphere. The air‐stable dysprosium(III) complex shows a hysteresis loop at 2 K and a very strong axial magnetic anisotropy generated by the merocyanine phenolate donor.     

Time-resolved imaging of hydrogel printing via laser-induced forward transfer

In this work, the printing mechanism of an alginate-based hydrogel via laser-induced forward transfer (LIFT) is investigated by spatial and temporal high-resolved stroboscopic imaging. First, the generation of the liquid jet is studied at two different laser fluences in a process without collector slide. Furthermore, the impingement process onto the collector slide at the same fluence levels is observed. With the help of these images the development of the jet is explained. Besides the influences of the collector slide as well as the applied laser fluence on the transfer are demonstrated.     

On Time Dynamics of Coagulation-Fragmentation Processes

We establish a characterization of coagulation-fragmentation processes, such that the induced birth and death processes depicting the total number of groups at time t≥0 are time homogeneous. Based on this, we provide a characterization of mean-field Gibbs coagulation-fragmentation models, which extends the one derived by Hendriks et al. As a by-product of our results, the class of solvable models is widened and a question posed by N. Berestycki and Pitman is answered, under restriction to mean-field models.     

Stabilization of spatiotemporal solitons in second-harmonic-generating media

We report the results of a systematic analysis of the existence and stability of spatiotemporal (two-dimensional) solitons (STSs) in the model of a planar waveguide with the intrinsic χ⁽²⁾ nonlinearity. Fundamental obstacles to the creation of STSs under physically realistic conditions are the normal sign of the group-velocity dispersion (GVD) at the second harmonic (SH), and the significant group-velocity mismatch (GVM) between the SH and fundamental-frequency (FF) components. To construct STS solutions in a numerical form, we adjust the iterative method, which was recently used for finding temporal (one-dimensional) χ⁽²⁾ solitons in a similar setting. We identify effective existence borders for the STSs, within which the energy loss to the generation of extended “tails” in the SH component (due to the normal sign of the GVD) is negligible. It is demonstrated that the existence region can be made much broader by means of the GVD-management and GVM-management techniques. We also explore interactions between the STSs, and find robust two-soliton bound states, with a moderate separation in the longitudinal (temporal) direction. Head-on collisions between the STSs are always destructive.     

Gradient‐based solvent suppression methods on a benchtop spectrometer

Benchtop NMR emerges as an appealing alternative to widely extend the scope of NMR spectroscopy in harsh environments and for on‐line monitoring. Obviously, the use of low‐field magnets induces a dramatic reduction of the spectral resolution leading to frequent peak overlaps. This issue is even more serious because applications such as chemical process monitoring involve the use of non‐deuterated solvents, leading to intense and broad peaks overlapping with the signals of interest. In this article, we highlight the need for efficient suppression methods compatible with flowing samples, which is not the case of the common pre‐saturation approaches. Thanks to a gradient coil included in our benchtop spectrometer, we were able to implement modern and efficient solvent suppression blocks such as WET or excitation sculpting to deliver quantitative spectra in the conditions of the on‐line monitoring. While these methods are commonly used at high field, this is the first time that they are investigated on a benchtop setting. Their analytical performance is evaluated and compared under static and on‐flow conditions. The results demonstrate the superiority of gradient‐based methods, thus highlighting the relevance of implementing this device on benchtop spectrometers. The comparison of major solvent suppression methods reveals an optimum performance for the WET‐180‐NOESY experiment, both under static and on‐flow conditions. Copyright © 2016 John Wiley & Sons, Ltd.     

Entropy and equilibrium property of QCD-instanton induced final state in deep-inelastic scattering

The scaling and additivity properties of Rényi entropy in rapidity space of the instanton final state (IFS) and current jet identified by the r-sorting method from the QCDINS Monte Carlo event sample are to saturation with decreasing phase space scale. Furthermore, it is found that the additivity of H2 holds well for the IFS in narrow rapidity windows at different positions. These results indicate that the IFS produced in the instanton-induced process of deep inelastic scattering has reached local equilibrium.