全文获取类型
收费全文 | 2979篇 |
免费 | 118篇 |
国内免费 | 36篇 |
专业分类
化学 | 1688篇 |
晶体学 | 13篇 |
力学 | 52篇 |
数学 | 761篇 |
物理学 | 619篇 |
出版年
2023年 | 21篇 |
2022年 | 34篇 |
2021年 | 64篇 |
2020年 | 42篇 |
2019年 | 60篇 |
2018年 | 82篇 |
2017年 | 52篇 |
2016年 | 113篇 |
2015年 | 110篇 |
2014年 | 113篇 |
2013年 | 190篇 |
2012年 | 180篇 |
2011年 | 229篇 |
2010年 | 120篇 |
2009年 | 143篇 |
2008年 | 171篇 |
2007年 | 167篇 |
2006年 | 153篇 |
2005年 | 147篇 |
2004年 | 159篇 |
2003年 | 108篇 |
2002年 | 98篇 |
2001年 | 46篇 |
2000年 | 32篇 |
1999年 | 29篇 |
1998年 | 40篇 |
1997年 | 37篇 |
1996年 | 45篇 |
1995年 | 32篇 |
1994年 | 26篇 |
1993年 | 23篇 |
1992年 | 25篇 |
1991年 | 24篇 |
1990年 | 14篇 |
1989年 | 7篇 |
1988年 | 9篇 |
1986年 | 12篇 |
1985年 | 14篇 |
1984年 | 15篇 |
1983年 | 8篇 |
1982年 | 14篇 |
1981年 | 13篇 |
1980年 | 9篇 |
1979年 | 10篇 |
1978年 | 8篇 |
1977年 | 11篇 |
1976年 | 8篇 |
1975年 | 7篇 |
1971年 | 7篇 |
1930年 | 6篇 |
排序方式: 共有3133条查询结果,搜索用时 15 毫秒
41.
Topological indices are graph invariants used in computational chemistry to encode molecules. A frequent problem when performing structure-activity studies is that topological indices are inter-correlated. We consider a simple topological index and show asymptotic independence for a random tree model. This continues previous work on the correlation among topological indices. These findings suggest that a size-dependence in a certain class of distance-based topological indices can be eliminated.AMS subject classification: 05C80, 60E10, 92E10 相似文献
42.
N-(2-Nitro)benzoylamino acids were prepared by 2-nitrobenzoylation of amino acids via the mixed ethylcarbonic anhydride procedure. They were reduced catalytically to N-(2-amino)benzoylamino acids which underwent cyclization to the corresponding lactams under a variety of conditions. The use of this reaction sequence for stepwise degradation of peptides seems possible. 相似文献
43.
Mikhail Ivanovich Barnik Ivan Vladimirovich Simdyankin Boris Alexandrovich Umanskii Serguei Petrovich Palto 《Liquid crystals》2020,47(2):273-283
ABSTRACT Electro-optical switching and the liquid crystal (LC) director distribution are studied in spatially periodic electric field for vertically aligned LC with negative dielectric anisotropy. Two electro-optical switching modes characterised by different switching times are observed. These modes are well distinguished optically by choosing proper geometry for the polarisers axes orientation. One of these modes is significantly faster as compared to the other. The fast switching is explained in terms of localised near-to-surface director reorientation. The 3D-numerical simulation shows very good agreement with the experiment: it points out the existence of the disclination lines and field-stabilised walls responsible for the localised director field switching and its relaxation. Possibilities of enhancing the fast mode for high-speed light modulators are discussed. 相似文献
44.
Boris Shivachev Rosica Petrova Petja Marinova Neyko Stoyanov Anife Ahmedova Mariana Mitewa 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(4):o211-o215
The crystal structures of four cycloalkanespiro‐4′‐imidazolidine‐2′,5′‐dithiones, namely cyclopentanespiro‐4′‐imidazolidine‐2′,5′‐dithione {systematic name: 1,3‐diazaspiro[4.4]nonane‐2,4‐dithione}, C7H10N2S2, cyclohexanespiro‐4′‐imidazolidine‐2′,5′‐dithione {systematic name: 1,3‐diazaspiro[4.5]decane‐2,4‐dithione}, C8H12N2S2, cycloheptanespiro‐4′‐imidazolidine‐2′,5′‐dithione {systematic name: 1,3‐diazaspiro[4.6]undecane‐2,4‐dithione}, C9H14N2S2, and cyclooctanespiro‐4′‐imidazolidine‐2′,5′‐dithione {systematic name: 1,3‐diazaspiro[4.7]dodecane‐2,4‐dithione}, C10H16N2S2, have been determined. The three‐dimensional packing in all of the structures is based on closely similar chains, in which hydantoin moieties are linked through N—H⋯S hydrogen bonding. The size of the cycloalkane moiety influences the degree of its deformation. In the cyclooctane compound, the cyclooctane ring assumes both boat–chair and boat–boat conformations. 相似文献
45.
Express detection of nonylphenol in water samples by fluorescence polarization immunoassay 总被引:6,自引:0,他引:6
Yakovleva JN Lobanova AY Shutaleva EA Kourkina MA Mart'ianov AA Zherdev AV Dzantiev BB Eremin SA 《Analytical and bioanalytical chemistry》2004,378(3):634-641
The development of express method for detection of endocrine-disrupting chemicals (EDC) such as alkylphenols is required for ecological monitoring. Several attempts have been made to produce antibodies against 4-nonylphenol (NP) in recent years. This work describes the production of new antibodies against NP and also summarizes the characterization of antibodies obtained earlier. Three approaches used to produce alkylphenol-specific antibodies are compared; these are based on: 1. omega-(4-hydroxyphenyl)nonanoic or omega-(4-hydroxyphenyl)heptanoic acid NP derivatives designed to mimic the linear NP isomer; 2. 4-aminophenol, which potentially mimics various substituted phenolic compounds with different side-chain structures at position 4 of the benzene ring; and 3. a mixture of branched NP isomers, conjugated to the carrier protein via a benzene ring by the Mannich reaction, and expected to be the closest mimic of NP structure by preserving its natural alkyl moiety.Fluorescence polarization immunoassays based on different combinations of antibody and labeled antigen for screening detection of NP were developed and structural aspects of assay sensitivity and specificity were investigated. The assays based on the antisera raised against omega-(4-hydroxyphenyl)nonanoic acid and NP conjugate via Mannich reaction are capable of express detection of NP with detection limit of 7 microg mL(-1 )and assay dynamic range of 18-300 microg mL(-1). 相似文献
46.
Boris Rubin 《Journal d'Analyse Mathématique》1994,63(1):55-102
The purpose of the paper is to introduce and to investigate a new class of fractional integrals connected with balls in ?n. A Riesz potentialI Ω α ρ over a ball Ω is represented by a composition of such integrals. Using this representation we obtain necessary and sufficient solvability conditions for the equationI Ω α ρ =f in the space Lp(Ωw) with a power weight w(x) and solve the equation in a closed form. The investigation is based on a special Fourier analysis adopted for operators commuting with rotations and dilations in ?n. 相似文献
47.
48.
We define a quantum-algebra associated to
as an associative algebra depending on two parameters. For special values of the parameters, this algebra becomes the ordinary-algebra of
, or theq-deformed classical-algebra algebra of
. We construct free field realizations of the quantum-algebra and the screening currents. We also point out some interesting elliptic structures arising in these algebras. In particular, we show that the screening currents satisfy elliptic analogues of the Drinfeld relations in.The research of the second author was partially supported by NSF grant DMS-9501414. 相似文献
49.
Vladimir A. KaminskiiOleg Yu. Slabko Andrey V. Kachanov Boris V. Buhvetskii 《Tetrahedron letters》2003,44(1):139-140
A simple and convenient route for the synthesis of 1,1,2,3,3-pentacyanopropene salts is reported. These salts are formed by interaction of malononitrile with SeO2 in presence of organic N-containing bases or pyridinium salts. 相似文献
50.
Lieve A. De Bock Boris Treiger Ludo Van der Auwera René E. Van Grieken 《Mikrochimica acta》1998,128(3-4):191-200
To reveal useful environmental information which is contained in large analytical data sets, an approach, based on the successive application of hierarchical cluster analysis and factor analysis, is proposed. Estimation criteria to determine the most suitable number of clusters and/or factors, are discussed and the interpretation of the cluster and factor analyses results is performed using visual techniques. The data sets were obtained by scanning electron microscope-energy-dispersive X-ray analysis of individual North Sea aerosol particles. 相似文献