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81.
Bonnet E. Letartre X. Cachard A. Tishchenko A.V. Parriaux O. 《Optical and Quantum Electronics》2003,35(11):1025-1036
High resonant reflection of a free space wave from a deeply corrugated slab waveguide is shown to take place in the case of a focused free space beam under normal incidence. It is described as a result of a strong intra-guide coupling coefficient allowing the coupled wave to be closely localized under the incident beam, therefore to interfere with it with high contrast effects. The coupled mode inspired analysis gives the possibility of optimizing the resonant structure; it is related and compared with the photonic crystal vision of the same functional structure to which it confers more intelligibility. 相似文献
82.
Roland Bonnet 《Interface Science》1997,4(3-4):169-179
Elastic fields of translation and misfit dislocations (resp. TD's and MD's) are investigated for two types of inhomogeneous materials.First, a multilayer formed by parallel heterointerfaces or free surfaces and containing one periodic array of interfacial MD's. In the more simple case of a thin layer on a substrate, analytic solutions can be found for the displacement field u relative to a single or a hexagonal periodic array of MD's. In the less simple case of a thin bicrystal and a layer sandwiched between two semi-infinite media, explicit solutions can still be extracted. For the general case of a multilayer material which involves a number N>2 heterointerfaces, analytic expressions become intractable. Solutions can nevertheless be obtained from the numerical inversion of linear equations which express the limiting boundary conditions along the heterointerfaces.Second, a thin bicrystal containing an heterointerface perpendicular to the two free surfaces of a foil. Starting from the elastic field of an edge TD parallel to the free surfaces, it is shown how to derive that of (i) a coherent heterointerface, (ii) a semicoherent heterointerface containing a single MD, and (iii) two close and parallel coherent heterointerfaces. Numerical calculations and graphs illustrate the solutions for metals (Al, Al2Cu), semiconductor materials (CoSi2, Si, GaAs), thin foils of the GaAs/Si type and a / superalloy. 相似文献
83.
Bonnet F Visseaux M Barbier-Baudry D Hafid A Vigier E Kubicki MM 《Inorganic chemistry》2004,43(12):3682-3690
The reaction of Ln(BH(4))(3)(THF)(3) or LnCl(3)(THF)(3) with 1 equiv of KCp*' ligand (Cp' = C(5)Me(4)n-Pr) afforded the new monocyclopentadienyl complexes Cp*'LnX(2)(THF)(n) (X = BH(4), Ln = Sm, n = 1, 1a, Ln = Nd, n = 2, 1b; X = Cl, Ln = Sm, n = 1, 3a) and [Cp*'LnX(2)](n') (X = BH(4), n' = 6, Ln = Sm, 2a, Ln = Nd, 2b; X = Cl, Ln = Nd, 4b). All these compounds were characterized by elemental analysis and (1)H NMR. Crystals of mixed borohydrido/chloro-bridged [Cp*'(6)Ln(6)(BH(4))(12-x))Cl(x)(THF)(n')] (x = 10, n' = 4, Ln = Sm, 2a', Ln = Nd, 2b'; x = 5, n = 2, Ln = Sm, 2a' ') were also isolated. Compounds 2a, 2b, 2a', 2b', and 2a' were structurally characterized; they all exhibit a hexameric structure in the solid state containing the [Cp*(3)Ln(3)X(5)(THF)] building block. The easy clustering of THF adducts first isolated is illustrative of the well-known bridging ability of the BH(4) group. Hexameric 2a was found to be unstable in the presence of THF vapors; this may be correlated to the opening of unsymmetrical borohydride bridges observed in the molecular structure. 相似文献
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The crystal structure of NaSbF4 has been redetermined by X-ray diffraction. The coordination about antimony is AX6E with a 2.2.2.1 geometry. The units are linked by fluorine bridges and form a double layer perpendicular to the a axis. Infrared and Raman spectra were recorded and are discussed in terms of the distorted octahedral arrangement of fluorines about each antimony. 相似文献
89.
Marc Bonnet 《International Journal of Solids and Structures》2009,46(11-12):2275-2292
This article concerns an extension of the topological derivative concept for 2-D potential problems involving penetrable inclusions, whereby a cost function J is expanded in powers of the characteristic size ε of a small inclusion. The O(ε4) approximation of J is established for a small inclusion of given location, shape and conductivity embedded in a 2-D region of arbitrary shape and conductivity, and then generalized to several such inclusions. Simpler and more explicit versions of this result are obtained for a centrally-symmetric inclusion and a circular inclusion. Numerical tests are performed on a sample configuration, for (i) the O(ε4) expansion of potential energy, and (ii) the identification of a hidden inclusion. For the latter problem, a simple approximate global search procedure based on minimizing the O(ε4) approximation of J over a dense search grid is proposed and demonstrated. 相似文献
90.
Isoprene–Styrene Chain Shuttling Copolymerization Mediated by a Lanthanide Half‐Sandwich Complex and a Lanthanidocene: Straightforward Access to a New Type of Thermoplastic Elastomers 下载免费PDF全文
Dr. Andreia Valente Dr. Gregory Stoclet Dr. Fanny Bonnet Prof. André Mortreux Prof. Marc Visseaux Prof. Philippe Zinck 《Angewandte Chemie (International ed. in English)》2014,53(18):4638-4641
A lanthanide half‐sandwich complex and a ansa lanthanidocene have been assessed for isoprene–styrene chain shuttling copolymerization with n‐butylethylmagnesium (BEM). In the presence of 1 equiv BEM, a fully amorphous multiblock microstructure of soft and hard segments is achieved. The microstructure consists of poly(isoprene‐co‐styrene) blocks, with hard blocks rich in styrene and soft blocks rich in isoprene. The composition of the blocks and the resulting glass transition temperatures (Tg) can be easily modified by changing the feed and/or the relative amount of the catalysts, highlighting a new class of thermoplastic elastomers (TPEs) with tunable transition temperatures. The materials self‐organize into nanostructures in the solid state. 相似文献