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排序方式: 共有235条查询结果,搜索用时 31 毫秒
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Abrams GS Adolphsen CE Aleksan R Alexander JP Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D de Boer W Bonvicini G Boyarski A Brabson B Breakstone A Brom JM Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drell PS Drewer DC Elia R Fay J Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G 《Physical review letters》1989,63(15):1558-1561
134.
Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Brom JM Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R Harral B Harris FA 《Physical review letters》1989,63(20):2173-2176
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Abrams GS Adolphsen CE Aleksan R Alexander JP Allen MA Atwood WB Averill D Ballam J Bambade P Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D de Boer W Bonvicini G Boyarski A Brabson B Breakstone A Breidenbach M Brom JM Brown JL Brown KL Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Clendenin J Cords D Coupal DP Dauncey P Dean NR DeStaebler HC Dorfan DE Dorfan JM Drell PS Drewer DC Dydak F Ecklund S Elia R Erickson RA Fay J Feldman GJ Fernandes D Field RC Fieguth TH 《Physical review letters》1989,63(7):724-727
137.
Carmelo De Maria Julio Rincon Alonso A. Duarte Giovanni Vozzi Thomas Boland 《先进技术聚合物》2013,24(10):895-902
Agarose hydrogels find wide applications in different fields such as biological sciences, tissue engineering and food industry, and its use has been investigated in many fields ranging from electronics to crystallography. Usually, agarose structures are made by casting, and more recently some attempts have been made to build agarose structures by additive manufacturing. All of the fabrication methods are based on thermo‐reversible gelling properties of agarose gel. A new method to fabricate agarose microstructures in a binary solvent composed of water and dimethyl sulfoxide is presented and modelled in this paper. This new method allows building agarose structures by an additive layer‐by‐layer approach using a modified inkjet printer. The fabrication method and printing device are described in detail. Furthermore, finite‐element model simulations, which predict with high confidence the final line width of the printed structures, are discussed and analysed. Mechanical properties of printed gel structures are comparable with those obtained by gel casting, as demonstrated by tensile testing. The presented results demonstrate the feasibility of this approach to fabricate agarose structures with more complex shapes that can be done by casting. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
138.
Peter A. Jenkins Susan Boland Paul Kavanagh Dnal Leech 《Bioelectrochemistry (Amsterdam, Netherlands)》2009,76(1-2):162
We are interested in investigating the applications of biocatalytic mediated reduction of oxygen by oxygenases in films on electrode surfaces, as such reactions can form the basis for biosensors or biocatalytic fuel cell development. Here we present approaches aimed at improving the stability and signal output of such films. These include selection of oxygen reducing biocatalysts which are active under physiological conditions and development of redox mediators which offer the opportunity to tailor the mediator to each enzyme. It was found that for each enzyme Melanocarpus albomyces laccase (MaL), Trametes hirsutus laccase (ThL) or bilirubin oxidase (MvBOD) it was the biocatalytic films mediated by Os(2,2′-bipyridine)2Cl·PVI that not only generated the highest current densities compared to Os(4,4′-dimethyl-2,2′-bipyridine)2Cl·PVI and Os(4,4′-dichloro-2,2′-bipyridine)2Cl·PVI, but also proved to be the most stable over 48 h. Under physiological conditions electrodes constructed from MvBOD generated the highest initial current densities for each of the osmium redox polymers, however these films proved to be the least stable over 48 h. Stability could be improved using surface pre-treatment. 相似文献
139.
Minasian SG Keith JM Batista ER Boland KS Clark DL Conradson SD Kozimor SA Martin RL Schwarz DE Shuh DK Wagner GL Wilkerson MP Wolfsberg LE Yang P 《Journal of the American Chemical Society》2012,134(12):5586-5597
Chlorine K-edge X-ray absorption spectroscopy (XAS) and ground-state and time-dependent hybrid density functional theory (DFT) were used to probe the electronic structures of O(h)-MCl(6)(2-) (M = Ti, Zr, Hf, U) and C(4v)-UOCl(5)(-), and to determine the relative contributions of valence 3d, 4d, 5d, 6d, and 5f orbitals in M-Cl bonding. Spectral interpretations were guided by time-dependent DFT calculated transition energies and oscillator strengths, which agree well with the experimental XAS spectra. The data provide new spectroscopic evidence for the involvement of both 5f and 6d orbitals in actinide-ligand bonding in UCl(6)(2-). For the MCl(6)(2-), where transitions into d orbitals of t(2g) symmetry are spectroscopically resolved for all four complexes, the experimentally determined Cl 3p character per M-Cl bond increases from 8.3(4)% (TiCl(6)(2-)) to 10.3(5)% (ZrCl(6)(2-)), 12(1)% (HfCl(6)(2-)), and 18(1)% (UCl(6)(2-)). Chlorine K-edge XAS spectra of UOCl(5)(-) provide additional insights into the transition assignments by lowering the symmetry to C(4v), where five pre-edge transitions into both 5f and 6d orbitals are observed. For UCl(6)(2-), the XAS data suggest that orbital mixing associated with the U 5f orbitals is considerably lower than that of the U 6d orbitals. For both UCl(6)(2-) and UOCl(5)(-), the ground-state DFT calculations predict a larger 5f contribution to bonding than is determined experimentally. These findings are discussed in the context of conventional theories of covalent bonding for d- and f-block metal complexes. 相似文献
140.
Self-assembled monolayers (SAMs) have become a standard tool for exploring surface interactions. Although well characterized, SAMs are known to undergo structural and conformational changes in the presence of solution, yet the ability to quantify these changes remains an obstacle due to limited analytical techniques. In this study, we determine changes in structure and conformation of CH3, OH, and COOH terminated hexadecanethiols on gold in water by means of a new technique known as evanescence reflection spectroscopy. This FTIR application, in conjunction with a semiempirical formalism, is capable of providing both qualitative and quantitative understanding of the molecular structure and orientation at the solid/liquid interface. 相似文献