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971.
The time-dependent wave packet method is used to study the exchange and abstraction processes for the H+H2O reaction with both OH bonds in the H2O reactant treated as reactive bonds in full dimension. The calculation clearly shows that it is necessary to treat both OH bonds in this way in order to accurately investigate the exchange process. However, for the abstraction process, the spectator model works very well. Nonreactive treatment of one OH bond by using a few vibrational basis functions or even freezing the bond can yield very accurate abstraction reaction probability. 相似文献
972.
Bai JZ Ban Y Bian JG Chen AD Chen HF Chen HS Chen JC Chen XD Chen YB Cheng BS Chi SP Chu YP Choi JB Cui XZ Dai YS Dong LY Du ZZ Dunwoodie W Fu HY Fu LP Gao CS Gu SD Guo YN Guo ZJ Han SW Han Y Harris FA He J He JT He KL He M He X Hong T Heng YK Hu GY Hu HM Hu QH Hu T Huang GS Huang XP Huang YZ Izen JM Ji XB Jiang CH Jin Y Jones BD Kang JS Ke ZJ Kim HJ Kim SK Kim TY Kong D Lai YF Li D Li HB Li HH Li J Li JC Li PQ Li QJ Li RY Li W Li WG Li XN Li XQ Liu B Liu F Liu F Liu HM Liu J Liu JP Liu TR 《Physical review letters》2002,88(10):101802
We report values of R = sigma(e(+)e(-)-->hadrons)/sigma(e(+)e(-)-->mu(+)mu(-)) for 85 center-of-mass energies between 2 and 5 GeV measured with the upgraded Beijing Spectrometer at the Beijing Electron-Positron Collider. 相似文献
973.
974.
国产45 MW速调管是在原国产30 MW HK-1型速调管的基础上改进和发展起来的,其聚焦磁场设计也是参照30 MW速调管聚焦磁场设计并在其基础上加工改造完成。为此必须对旧聚焦系统进行改造,设计出符合需要的磁场分布,以满足45 MW速调管工作的需要。首先从理论上找出速调管工作时的理想磁场值,根据该磁场分布设计出相应的线圈结构;其次根据45 MW速调管的结构尺寸,对30 MW速调管的线圈支架进行改造,利用旧线圈和新支架组成新的聚焦系统;最后,根据理论模拟和测试结果,调整和优化各组线圈的电流值,给出速调管工作时的各组聚焦电源运行参考值。叙述了新聚焦线圈的理论设计和测试分析,包括新线圈支架的设计、水冷系统与线圈的结构安排和整体的测试结果,最后根据速调管高功率测试运行状态给出速调管工作时的聚焦线圈电流的参考值。 相似文献
975.
Capillary zone electrophoresis is employed for the determination of caffeine using end-column amperometric detection with a carbon fiber microdisk array electrode at a constant potential of 1.45 V versus a saturated calomel electrode. The optimum conditions of separation and detection are 0.1 52mM NaH2PO4-0.648mM Na2HPO4 for the buffer solution, 20 kV for the separation voltage, 5 kV for the injection voltage, and 10s for the injection time. The limit of detection is 2.9 x 10(-4)mM or 1.2 fmol (signal-to-noise ratio = 2). The relative standard deviation is 0.68% for the migration time and 2.3% for the electrophoretic peak current. The method is applied to determining caffeine in human serum and a cola drink. 相似文献
976.
分析了校园MIS及数据资源的特征,针对校园信息资源范围广、关联复杂的状况,提出了数据资源统一访问策略——分层访问.数据访问分为七层,各层完成数据访问独立性的特定功能,使不同的访问软件能透明访问全部数据资源.为保证传统应用能基于网络计算访问统一数据资源,又提出了“数据访问管道”和数据库访问服务器的技术.文章分析了以应用服务器为基础的N-Tiers计算的弊端,设计了“虚拟应用服务器”WUV-APPS,将数据访问对象构造成数据对象组件. 相似文献
977.
The Schrödinger equation for stationary states is studied in a central potential V(r) proportional to r
– in an arbitrary number of spatial dimensions. The presence of a single term in the potential makes it impossible to use previous algorithms, which only work for quasi-exactly-solvable problems. Nevertheless, the analysis of the stationary Schrödinger equation in the neighbourhood of the origin and of the point at infinity is found to provide relevant information about the desired solutions for all values of the radial coordinate. The original eigenvalue equation is mapped into a differential equation with milder singularities, and the role played by the particular case = 4 is elucidated. In general, whenever the parameter is even and larger than 4, a recursive algorithm for the evaluation of eigenfunctions is obtained. Eventually, in the particular case of two spatial dimensions, the exact form of the ground-state wave function is obtained for a potential containing a finite number of inverse powers of r, with the associated energy eigenvalue. 相似文献
978.
0IntroductionPhenanthrolinederivativescontainingaminegroupshavebothsoftandhardsitesandaregooddonorsformetalions.1,10鄄phenanthrolineanditsderivativeshavebeenextensivelyusedasligandsinbothanalyticalandpreparativecoordinationchemis鄄try[1].Mostoftheseworksh… 相似文献
979.
In this paper we study the oscillations for a class of functional differential inequalities. By using these properties some forced oscillations to the boundary value problems of functional partial differential equations are established. 相似文献
980.
Qinghua Zhao Thi Tuyet Mai Dang Dong‐Cheol Shin Hong You Soon‐Ki Kwon 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):341-347
Diphenylaminobiphenylated stryl based alternating copolymers with phenyl or fluorene, which were expected to have a terphenylene vinylene backbone containing an (N,N‐diphenylamino)biphenyl pendant and a phenyl/fluorene/phenylene vinylene backbone containing an (N,N‐diphenylamino)biphenyl pendant, were synthesized by a Suzuki coupling reaction. The obtained copolymers were confirmed with various types of spectroscopy. The alternating copolymers showed good hole‐injection properties because of their low oxidation potential and good solubility and high thermal stability with a high glass‐transition temperature. The alternating copolymers showed blue emissions because of the adjusted conjugation lengths; the maximum wavelength was 460 nm for poly{4,4′‐biphenylene‐α‐[4″‐(N,N′‐diphenylamino)diphenyl]vinylene‐alt‐5‐(2′‐ethylhexyloxy)‐2‐methoxybenzene} and 487 nm for poly{4,4′‐biphenylene‐α‐[4″‐(N,N′‐diphenylamino)diphenyl] vinylene‐alt‐9,9‐dihexylfluorene}. The maximum brightness of indium tin oxide/poly(3,4‐ethylene dioxythiophene)/polymer/LiF/Al devices with poly{4,4′‐biphenylene‐α‐[4″‐(N,N′‐diphenylamino)diphenyl]vinylene‐alt‐5‐(2′‐ethylhexyloxy)‐2‐methoxybenzene} or poly{4,4′‐biphenylene‐α‐[4″‐(N,N′‐diphenylamino)diphenyl]vinylene‐alt‐9,9‐dihexylfluorene} as the emitting layer was 250 or 1000 cd/m2, respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 341–347, 2007 相似文献