全文获取类型
收费全文 | 15512篇 |
免费 | 2565篇 |
国内免费 | 1870篇 |
专业分类
化学 | 11608篇 |
晶体学 | 184篇 |
力学 | 800篇 |
综合类 | 99篇 |
数学 | 1384篇 |
物理学 | 5872篇 |
出版年
2024年 | 53篇 |
2023年 | 278篇 |
2022年 | 519篇 |
2021年 | 577篇 |
2020年 | 657篇 |
2019年 | 649篇 |
2018年 | 574篇 |
2017年 | 477篇 |
2016年 | 769篇 |
2015年 | 721篇 |
2014年 | 865篇 |
2013年 | 1212篇 |
2012年 | 1386篇 |
2011年 | 1351篇 |
2010年 | 933篇 |
2009年 | 939篇 |
2008年 | 1047篇 |
2007年 | 945篇 |
2006年 | 849篇 |
2005年 | 761篇 |
2004年 | 616篇 |
2003年 | 523篇 |
2002年 | 570篇 |
2001年 | 396篇 |
2000年 | 291篇 |
1999年 | 303篇 |
1998年 | 249篇 |
1997年 | 222篇 |
1996年 | 200篇 |
1995年 | 168篇 |
1994年 | 141篇 |
1993年 | 110篇 |
1992年 | 108篇 |
1991年 | 102篇 |
1990年 | 71篇 |
1989年 | 57篇 |
1988年 | 40篇 |
1987年 | 32篇 |
1986年 | 34篇 |
1985年 | 34篇 |
1984年 | 20篇 |
1983年 | 16篇 |
1982年 | 14篇 |
1981年 | 17篇 |
1980年 | 9篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1973年 | 5篇 |
1971年 | 4篇 |
1936年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
141.
142.
C. Z. Dong S. Fritzsche B. Fricke 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,40(3):317-323
Recent high precision measurements on the lifetime of
the metastable 6s[3/2]2 state of atomic xenon display a
difference with previous predictions by a factor of 2–3. In the
present work, a systematic relaxation and correlation approach,
which has been developed on the basis of a widely used
multi-configuration Dirac-Fock method, is applied to study the
electric dipole allowed E1 and forbidden M1, E2 and M2 transitions
between the 5p5 6s and
5p6 configurations. We systematically include the correlation effects
which arise from all the single and double excitations from the
occupied
shells into the
(n=6–10) active sets and the relaxation effects caused by change
of the electron density between the radiative initial- and final-states. This study not only reduces greatly the existing
discrepancy in the lifetime of the 6s[3/2]2 state, but also
presents rather consistent results for both the lifetime of the
metastable 6s'[1/2]0 state and the oscillator strength of the
5p5 6s - 5p6 E1 resonant transitions. 相似文献
143.
Dong Zhengchao 《中国科学G辑(英文版)》2006,49(5):597-605
We study the Zeeman effect on the d-wave superconductor and tunneling spectrum in normal-metal(N)/d-wave superconductor(S) junction by applying a Zeeman magnetic field to the S. It is shown that: (1) the Zeeman magnetic field
can lead to the S gap decreasing, and with the increase in Zeeman energy, the superconducting state is changed to the normal
state, exhibiting a first-order phase transition; (2) the Zeeman magnetic field may make the zero-bias conductance peak split
into two peaks, and the energy difference between the two splitting peaks in the conductance spectrum is equal to 2h
0 (h
0 is the Zeeman energy); (3) both the barrier strength of interface scattering and the temperature can lower the magnitudes
of splitting peaks, of which the barrier strength can lead to the splitting peaks becoming sharp and the temperature can smear
out the peaks, however, neither of them can influence the Zeeman effect. 相似文献
144.
采用密度泛函方法(B3P86)对 Fe_2分子结构进行了优化.计算结果中未观察到自旋污染,基态波函数与高态波函数并未混杂,结果表明,Fe_2中有8个未配对电子,这些电子空间分布不同和自旋平行产生的自旋极化效应,使 Fe_2能量最低.计算结果表明,Fe_2分子的基态是~9∑_g~ ,并非~7Δ_u,进而表明 Fe_2的自旋平行效应比电子自旋配对效应要强.计算得到该分子基态的二阶、三阶和四阶力常数分别为1.4115×10~(-2)aJ/nm~2、-37.1751×10~3aJ/nm~3和 98.7596×10~4aJ/nm~4;光谱数据ω_eχ_e、B_e、α_e分别为0.3522、0.0345、 0.4963×10~(-4)cm~(-1);离解能为3.5522eV,平衡键长为0.2137nm,振动频率为292.914cm~(-1);并得到了 Murrel-Sorbie 函数. 相似文献
145.
Junxiang Zhang Yabin Dong Haihong Wang Jiangrui Gao 《量子光学学报》2006,12(B08):74-74
The quantum coherence effects of the transition Fe = 2←→Fg = 3 depending on the polarization of the coupling and probe beam are observed in a Cs vapor cell. The splitting of electromagnetically induced transparency (EIT) window is observed when the degeneracy of two-level system is broken using a magnetic field. It is also shown that the splitted transparency points of two of three windows are shifted with the intensity of magnetic field ( i. e. Zeeman splitting in the upper and lower levels ) increasing. On the contrary, when we fix the intensity of magnetic field, and increase the Rabi frequency of the coupling beam, the splitted transparency peaks become wider. A qualitative agreement between experiment and theory is found. 相似文献
146.
采用多靶磁控溅射法制备了一系列具有不同Al2O3调制层厚度的TiN/Al2O3纳米多层膜.利用X射线能量色散谱、X射线衍射、扫描电子显微镜、高分辨透射电子显微镜和微力学探针表征了多层膜的成分、微结构和力学性能.研究结果表明,在TiN/Al2O3纳米多层膜中,单层膜时以非晶态存在的Al2O3层在厚度小于1.5 nm时因TiN晶体层的模板效应而晶化,并与TiN层形成共格外延生长,相应地,多层膜产生硬度明显升高的超硬效应,最高硬度可达37.9 GPa.进一步增加多层膜中Al2O3调制层的层厚度,Al2O3层逐渐形成非晶结构并破坏了多层膜的共格外延生长,使得多层膜的硬度逐步降低. 相似文献
147.
利用SHS等离子喷涂技术,将经过机械团聚法制备的Fe2O3-Al复合粉体送入等离子焰流,沉积出厚度约为400 μm的复合涂层.利用XRD,SEM 和TEM等检测手段对涂层的成分和组织进行了分析,测定了涂层的显微硬度、断裂韧性以及耐磨性.结果表明涂层为具有纳米结构的FeAl2O4-Al2O3-Fe纳米复合组织;涂层的显微硬度为HV100g870;断裂韧性是普通Al2O3涂层的2倍;无润滑磨损的耐磨性是普通Al2O3涂层的2.5倍. 相似文献
148.
以丙醇锆(ZrPr)为锆源,二乙醇胺(DEA)为络合剂,原位引入聚乙烯吡咯烷酮(PVP),在乙醇体系中成功地合成了PVP掺杂-ZrO2溶胶.采用旋涂法在K9玻璃基片上制备了PVP-ZrO2单层杂化薄膜.用不同掺杂量的PVP-ZrO2高折射率膜层与相同的SiO2低折射率膜层交替沉积四分之一波堆高反射膜.借助小角X射线散射研究胶体微结构,用红外光谱、原子力显微镜、紫外/可见/近红外透射光谱、椭圆偏振仪以及1064nm的强激光辐照实验对薄膜的结构、光学和抗激光损伤性能进行表征.研究发现,体系组成的适当配置可以在溶胶稳定的前提下实现ZrPr的充分水解,赋予薄膜良好的结构、光学和抗激光损伤性能.杂化体系中,DEA与ZrPr之间强的配合作用大大降低了ZrO2颗粒表面羟基的活性,使得PVP大分子只是以微弱的氢键与颗粒的表面羟基作用而均匀分散于ZrO2颗粒的周围,对颗粒的形成和生长无显著影响.因而在实验研究范围内,随PVP含量的增大,PVP-ZrO2杂化膜层的折射率和激光损伤阈值均无显著变化.但是,薄膜中均匀分布的PVP柔性链可以有效促进膜层应力松弛,显著削弱不同膜层之间的应力不匹配程度、大大方便多层光学薄膜的制备.当高折射率膜层中PVP的质量分数达到15%-20%时,膜层之间良好的应力匹配使得多层高反射膜的沉积周期数可达到10以上.沉积1O个周期的多层反射膜,在中心波长1064nm处透射率约为1.6%-2.1%,接近全反射特征,其激光损伤阈值为16.4-18.2J/cm2(脉冲宽度为1ns). 相似文献
149.
Temperature-insensitive dynamic pressure measurement using a single fiber Bragg grating (FBG) based on reflection spectrum bandwidth modulation and optical power detection is proposed. A specifically designed double-hole cantilever beam is used to provide a pressure-induced axial strain gradient along the sensing FBG and is also used to modulate the reflection bandwidth of the grating. The bandwidth modulation is immune to spatially uniform temperature effects, and the pressure can be unambiguously determined by measuring the reflected optical power, avoiding the complex wavelength interrogation system. The system acquisition time is up to 85 Hz for dynamic pressure measurement, and the thermal fluctuation is kept less than 1.2% full-scale for a temperature range of -10 degrees C to 80 degrees C. 相似文献
150.
We propose and experimentally demonstrate a simple and practical scheme for simultaneous measurement of bending and temperature based on a single sampled chirped fiber Bragg grating with multiple resonant peaks, which is embedded on a flexible cantilever beam. The wavelength spacing of the grating can be changed by adjusting the bending curvature change, since the compressive strain gradient induced by the bending of the cantilever beam changes the chirp ratio of the fiber grating. However, the wavelength spacing of the fiber grating is not changed by the temperature variation; the multiple resonant wavelengths are only shifted into the longer wavelength because of the positive thermal-expansion and thermo-optic coefficients of the fiber grating. Consequently, the proposed scheme allows for discrimination between two effects of bending and temperature. 相似文献