全文获取类型
收费全文 | 1096篇 |
免费 | 19篇 |
国内免费 | 5篇 |
专业分类
化学 | 741篇 |
晶体学 | 6篇 |
力学 | 25篇 |
数学 | 167篇 |
物理学 | 181篇 |
出版年
2022年 | 27篇 |
2021年 | 27篇 |
2020年 | 27篇 |
2019年 | 19篇 |
2018年 | 24篇 |
2017年 | 15篇 |
2016年 | 32篇 |
2015年 | 23篇 |
2014年 | 49篇 |
2013年 | 87篇 |
2012年 | 69篇 |
2011年 | 82篇 |
2010年 | 43篇 |
2009年 | 58篇 |
2008年 | 68篇 |
2007年 | 50篇 |
2006年 | 57篇 |
2005年 | 58篇 |
2004年 | 41篇 |
2003年 | 35篇 |
2002年 | 30篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 17篇 |
1998年 | 10篇 |
1997年 | 9篇 |
1996年 | 16篇 |
1995年 | 7篇 |
1994年 | 15篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 9篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 8篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1968年 | 2篇 |
1967年 | 2篇 |
排序方式: 共有1120条查询结果,搜索用时 0 毫秒
71.
Kyle M. McCall Bogdan M. Benin Michael Wörle Thomas Vonderach Detlef Günther Maksym V. Kovalenko 《Helvetica chimica acta》2021,104(1):e2000206
Inorganic, lead-free metal halides are widely sought after following the rise of the halide perovskites as outstanding optoelectronic materials, due to their enhanced stability and reduced toxicity. Herein, we report on the solvothermal synthesis of Rb7Sb3Br16, which exhibits a 0D structure comprised of [SbBr6]3− octahedra and edge-sharing bioctahedra [Sb2Br10]4− dimers that order into layers along the c-axis. This all-inorganic material is air-stable and exhibits weak orange photoluminescence (PL) at room temperature. Low-temperature PL and PL excitation (PLE) measurements reveal the presence of two distinct emission bands that originate from these structural units, with the high-energy emission quenching as temperature rises beyond 150 K. We are also able to obtain Rb7Bi3Br16 and Rb7Bi3I16 which both crystallize in orthorhombic symmetry, with Rb7Bi3Br16 presenting weak low-temperature luminescence while Rb7Bi3I16 is non-luminescent. This work expands the library of emissive inorganic metal halides and provides further evidence for the efficacy of low-dimensional Sb−X luminescent centers based on octahedral and edge-sharing [Sb2X10]4− dimers. 相似文献
72.
A. N. Kalenchuk A. E. Koklin V. I. Bogdan L. M. Kustov 《Russian Chemical Bulletin》2017,66(7):1208-1212
Catalytic hydrogenation of benzene, biphenyl, and ortho-, metha-, and para-isomers of terphenyl over a 3 wt.% Pt/C at 180 °C and 70 atm was studied. The directions of hydrogenation of each substrate were revealed. Relationships between structures of the substrate and hydrogen consumption rates were found. It was shown that hydrogenation rate decreases on going from benzene to terphenyl and with increasing degree of the substrate hydrogenation. Hydrogenation rate of terphenyl isomers decreases in the following order: p-terphenyl > > m-terphenyl > o-terphenyl. 相似文献
73.
D. Bogdan T. Cretu G. Macarie M. I. Chernej 《Zeitschrift für Physik A Hadrons and Nuclei》1973,263(2):121-128
The wave functions yielded by the microscopical non-adiabatic treatment of the Coriolis interaction proposed in Dubna by Pyatov, Chernej and Baznat have been used in order to calculate the beta decay observables of some allowed transitions of the155Eu nucleus. The Coriolis interaction effects are important especially for the absoluteft values (an important improvement is obtained) and for theβ-γ circular polarization correlation. 相似文献
74.
Efficient solution-phase protocols for the high-throughput synthesis of 6-(1,2,3-triazol-1-yl)-dihydropyrimidones are reported. The multistep sequence involves the initial bromination of dihydropyrimidones precursors (DHPMs, Biginelli compounds) at the C6-methyl position, using a recyclable polymer-supported brominating agent under rapid flow-through conditions (residence time of 1 min). The 6-bromomethyldihydropyrimidone intermediates were subsequently subjected to a microwave-assisted azidation step (25 min), providing the key 6-azidomethyldihydropyrimidone precursors. In the final step of the sequence, the azides were treated with terminal acetylenes under Cu(I) catalysis (azide-acetylene ligation, "click chemistry") to provide the target 6-(1,2,3-triazol-1-yl)-dihydropyrimidones in a regiospecific fashion (1,4-triazoles) in moderate overall yield utilizing controlled microwave irradiation (20 min). In total, a library of 27 compounds was prepared with 4 points of diversity. 相似文献
75.
Gologan B Takáts Z Alvarez J Wiseman JM Talaty N Ouyang Z Cooks RG 《Journal of the American Society for Mass Spectrometry》2004,15(12):1874-1884
Protein ions, after mass spectrometric separation, can be soft-landed into liquid surfaces with preservation of their native structures. Retention of biological activity is strongly favored in glycerol-based surfaces but not in self-assembled monolayer solid surfaces. Soft-landing efficiency for multiply-charged hexokinase ions was found to be some four times higher for a glycerol/fructose liquid surface than for a fluorinated self-assembled monolayer surface. Soft-landing into liquid surfaces is also shown to allow (1) protein purification, (2) on-surface identification of the soft-landed material using MALDI, and (3) protein identification by in-surface tryptic digestion. Pure lysozyme was successfully isolated from different mixtures including an oxidized, partially decomposed batch of the protein and a partial tryptic digest. Liquid glycerol/carbohydrate mixtures could be used directly to record MALDI spectra on the soft-landed compounds provided they were fortified in advance with traditional MALDI matrices such as p-nitroaniline and alpha-cyano-4-hydroxycinnamic acid. Various proteins were soft-landed and detected on-target using these types of liquid surface. Soft-landing of multiply-charged lysozyme ions onto fluorinated self-assembled monolayer surfaces was found to occur with a limited amount of neutralization, and trapped multiply-charged ions could be desorbed from the surface by laser desorption. Initial data is shown for a new approach to protein identification that combines top-down and bottom-up approaches by utilizing protein ion soft-landing from a protein mixture, followed by tryptic digestion of the landed material and detection of characteristic tryptic fragments by MALDI. 相似文献
76.
Cichocki B Ekiel-Jezewska ML Nägele G Wajnryb E 《The Journal of chemical physics》2004,121(5):2305-2316
A system of many spherical particles, suspended in a quiescent fluid and touching a planar free fluid-gas interface, is considered. Stick fluid boundary conditions at the sphere surfaces are assumed. The free surface boundary conditions are taken into account with the use of the method of images. For such a quasi-two-dimensional system, the one-sphere resistance operator is calculated numerically. Moreover, the corresponding friction and mobility tensors are constructed from irreducible multipole expansion. Finally, the long-distance terms of the two-sphere mobility tensor are evaluated explicitly up to the order of 1/r3, where r is the interparticle distance. Experiments which have motivated this work are outlined. 相似文献
77.
Linear conductance across a large quantum dot via a single level epsilon(0) with large hybridization to the contacts is strongly sensitive to quasibound states localized in the dot and weakly coupled to epsilon(0). The conductance oscillates with the gate voltage due to interference of the Fano type. At low temperature and Coulomb blockade, Kondo correlations damp the oscillations on an extended range of gate voltage values, by freezing the occupancy of the epsilon(0) level itself. As a consequence, the antiresonances of Fano origin are washed out. The results are in good correspondence with experimental data for a large quantum dot in the semiopen regime. 相似文献
78.
79.
Hodgson DM Stefane B Miles TJ Witherington J 《Chemical communications (Cambridge, England)》2004,(19):2234-2235
Organolithium-induced ring-opening of aziridines of 2,5-dihydrofuran (5 and 8) and 1,4-dimethoxybut-2-ene (16, 17 and 23) gives 3-substituted 2-aminobut-3-en-1-ols 9-15 and amino ethers 18-20 and 24-26. 相似文献
80.
A pulse sequence is proposed for the suppression of the strong homonuclear scalar coupling in the case of AB spin systems. The theoretical treatment is presented in terms of the average Hamiltonian theory in the case of aperiodic perturbations. The zero-order and the first-order correction terms in the full average Hamiltonian are calculated. It is shown that the chemical shift interaction for one of the spins is completely refocused and the conditions in which the interactions bilinear in spin operators are efficiently suppressed are analyzed. 相似文献