全文获取类型
收费全文 | 1093篇 |
免费 | 22篇 |
国内免费 | 5篇 |
专业分类
化学 | 741篇 |
晶体学 | 6篇 |
力学 | 25篇 |
数学 | 167篇 |
物理学 | 181篇 |
出版年
2022年 | 27篇 |
2021年 | 27篇 |
2020年 | 27篇 |
2019年 | 19篇 |
2018年 | 24篇 |
2017年 | 15篇 |
2016年 | 32篇 |
2015年 | 23篇 |
2014年 | 49篇 |
2013年 | 87篇 |
2012年 | 69篇 |
2011年 | 82篇 |
2010年 | 43篇 |
2009年 | 58篇 |
2008年 | 68篇 |
2007年 | 50篇 |
2006年 | 57篇 |
2005年 | 58篇 |
2004年 | 41篇 |
2003年 | 35篇 |
2002年 | 30篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 17篇 |
1998年 | 10篇 |
1997年 | 9篇 |
1996年 | 16篇 |
1995年 | 7篇 |
1994年 | 15篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 9篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 8篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1968年 | 2篇 |
1967年 | 2篇 |
排序方式: 共有1120条查询结果,搜索用时 15 毫秒
101.
Bogdan Kaźmierczak Kazimierz Piechór 《Mathematical Methods in the Applied Sciences》2011,34(3):325-337
We study traveling wave solutions to a system of four non‐linear partial differential equations, which arise in a tissue interaction model for skin morphogenesis. Under the assumption that the strength of attachment of the epidermis to the basal lamina is sufficiently large, we prove the existence and uniqueness (up to a translation) of traveling wave solutions connecting two stationary states of the system with the dermis and epidermis cell densities being positive. We discuss the problem of the minimal wave speed. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
102.
Bogdan Tiţa Eleonora Marian Adriana Fuliaş Tunde Jurca Dumitru Tiţa 《Journal of Thermal Analysis and Calorimetry》2013,112(1):367-374
The application of thermal method is of great importance regarding the pharmaceutical problems such as the control of raw materials, the determination of purity, the qualitative and quantitative analysis of drug formulation, tests of thermal stability and compatibility and the determination of kinetic parameters etc. The purpose of a kinetic investigation is to calculate the kinetic parameters and the determination of the kinetic model for the studied process. The results are further used to predict the system’s behaviour in various circumstances. A kinetic study regarding the piroxicam—active substance’s thermal decomposition was performed under isothermal conditions and nitrogen atmosphere, for the temperature steps: 200, 205, 210, 215 and 220 °C. The TG/DTG data were processed by three differential methods: isothermal—isoconversional, Friedman’s isothermal isoconversional and isothermal model-fitting. The obtained results are in good accord between them, as well as with those obtained under non-isothermal conditions from a previous work and confirm the necessity of the kinetic parameters determining in different thermal conditions, by the adequate calculation methods. 相似文献
103.
104.
Ion Grosu Lo?c Toupet Gerard Plé Sorin Mager Eugen Mesaros Andreea Varga Elena Bogdan 《Monatshefte für Chemie / Chemical Monthly》2000,54(5):277-286
The synthesis and stereochemistry of new dibrominated spiro-1,3-dioxane derivatives are reported. Investigations by means
of NMR methods and single crystal X-ray diffraction for two compounds revealed the high regio- and diastereoselectivity of
the bromination reaction of some new spiro-1,3-dioxanes and the asymmetric induction of the chiral carbon atom located in
the spiro skeleton. 相似文献
105.
Our efforts in construction the 1,2-dioxane ring of plakortolides through two approaches are described. The first one involved as a key step an acid catalyzed 6-endo ring closure of β-hydroperoxy trans-epoxides directed by a vinyl group adjacent to the epoxide function. By this route, an advanced intermediate of plakortolides was obtained in six steps and 35% overall yield. The second approach featured a 1,2-dioxane ring forming by a double opening of bis-epoxides by ethereal hydrogen peroxide. This reaction did not proceed in the expected sense and exclusive formation of hydroperoxy tetrahydropyran derivatives was observed via a tandem oxacyclization–hydroperoxidation sequence. 相似文献
106.
Hans E. Miltner Christophe Block Guy Van Assche Kurt Van Durme Bogdan Bogdanov 《European Polymer Journal》2010,46(5):984-996
A comprehensive overview of available methods for assessing nanofiller dispersion is presented for a wide range of layered silicate-based poly(ε-caprolactone) (PCL) nanocomposites. Focusing on their respective strengths and weaknesses, rheological, mechanical and thermal characterization approaches are evaluated in direct relation to morphological information. Pronounced changes in the rheological and mechanical properties of the materials are only observed for nanocomposites displaying the highest nanofiller dispersion levels, as confirmed by an innovative and highly reliable thermal analysis approach based on quasi-isothermal crystallization. As such, the data obtained from the different methods also allow a detailed investigation of the crucial factors affecting nanofiller dispersion, evidencing the importance of specific matrix/filler interactions and the need for proper melt processing conditions when targeting significant property enhancements. Finally, the wide potential of the developed methodologies for the characterization of polymeric nanocomposites in general is illustrated by an extension to carbon nanotube-based PCL composites, unambiguously demonstrating their complementarity and broad applicability. 相似文献
107.
Georgiana Surpateanu Jean-François Soulé Jean-Marie Beau Stéphanie Norsikian Bogdan I. Iorga 《Journal of carbohydrate chemistry》2013,32(2):114-129
The conformational flexibility of two glycal-type neuraminidase inhibitors has been studied, using several molecular modeling techniques. In agreement with the experimental data available, an intramolecular hydrogen bond, representing a key structural feature that controls the conformer distribution in solution, has been identified. The contribution of each substituent to the overall equilibrium was evaluated using simplified derivatives. Additionally, four methods for estimating NMR coupling constants from dihedral angles were evaluated and the Haasnoot method was found to be appropriate for this class of sugars. These results should allow a better understanding of the structural parameters governing physico-chemical properties of glycal-like compounds. Supplemental materials are available for this article. Go to the publisher's online edition of Journal of Carbohydrate Chemistry to view the free supplemental file. 相似文献
108.
Iztok Fister Marjan Mernik Bogdan Filipič 《Computational Optimization and Applications》2013,54(3):741-770
This paper proposes a hybrid self-adaptive evolutionary algorithm for graph coloring that is hybridized with the following novel elements: heuristic genotype-phenotype mapping, a swap local search heuristic, and a neutral survivor selection operator. This algorithm was compared with the evolutionary algorithm with the SAW method of Eiben et al., the Tabucol algorithm of Hertz and de Werra, and the hybrid evolutionary algorithm of Galinier and Hao. The performance of these algorithms were tested on a test suite consisting of randomly generated 3-colorable graphs of various structural features, such as graph size, type, edge density, and variability in sizes of color classes. Furthermore, the test graphs were generated including the phase transition where the graphs are hard to color. The purpose of the extensive experimental work was threefold: to investigate the behavior of the tested algorithms in the phase transition, to identify what impact hybridization with the DSatur traditional heuristic has on the evolutionary algorithm, and to show how graph structural features influence the performance of the graph-coloring algorithms. The results indicate that the performance of the hybrid self-adaptive evolutionary algorithm is comparable with, or better than, the performance of the hybrid evolutionary algorithm which is one of the best graph-coloring algorithms today. Moreover, the fact that all the considered algorithms performed poorly on flat graphs confirms that graphs of this type are really the hardest to color. 相似文献
109.
The computer operation is used to find all the possible layer sequences of poly-types. Identical arrangements are separated using the corresponding values of calculated structure factor. 相似文献
110.
An efficient and reliable synthesis of new thiazole-(amino)methylphosphonic, phosphinic acids, and phosphine oxides is reported. The synthetic protocol is based on nucleophilic addition of phosphorous species to thiazole derived imines. Unexpectedly, it was discovered that heating of thiazole-2-yl-(amino)methylphosphonates and phosphinates with aqueous HCl leads to their decomposition resulting in a rupture of the C-P bond, rejecting of the phosphorus containing fragment and formation of the corresponding secondary N-(thiazole-2-yl-methyl)-alkylamines. Two alternative mechanisms for this cleavage are postulated. 相似文献