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91.
The synthesis of 6‐methylsulfanyl‐2,4‐dithioxo‐1,2,3,4‐tetrahydropyrimidine‐5‐carbonitrile 4 is described. Compound 4 was reacted with various alkylants. The reaction with chloroacetic acid derivatives results in the formation of thieno[2,3‐d]pyrimidines 8 . When methyl iodide was used 2,4,6‐tris(methylsul‐fanyl)pyrimidine‐5‐carbonitrile 5 was obtained. The substitution of the methylsulfanyl groups in compound 5 by several N‐nuclophiles leads to amino substituted pyrimidines. 相似文献
92.
Colette Deschamps-Vallet Michle Meyer-Dayan Jean Andrieux Jacques Riboulleau Bernard Bodo Darius Molho 《Journal of heterocyclic chemistry》1977,14(3):489-492
5-Oxo-5H,7H-[2]benzopyrano[4,3-b][1]benzopyran ( 2 ) has been synthesized from 3-(o-hydroxybenzylidene)isochroman-1,4-dione ( 3 ) by reductive cyclization, and from 5H,7H[2]benzo-pyrano[4,3-b][1]benzopyran-5,7-dione ( 4 ) by selective hydro-genation. This second method affords the dihydro compound 6 or 6a,12a-dihydro-5H,7H-[2]benzopyrano[4,3-b] [1 ]benzopyran-5-one as reaction time increases. 相似文献
93.
Bodo Müller 《Nachrichten aus der Chemie》1998,46(5):549-549
94.
Bodo Saake Rudolf Patt Jürgen Puis K.-J. Linow Burkhard Philipp 《Macromolecular Symposia》1992,61(1):219-236
The investigation of polymers by gel permeation chromatography has become a standard method for the determination of the molecular weight distribution. In case of cellulose and pulps the samples are mostly carbanilated or nitrated in order to get them soluble in organic solvents. In this context it is important that the derivatives obtained represent the composition of the starting material. High molecular wood pulps were carbanilated and further prepared for chromatographic separation using different methods. For bleached and unbleached pulps, the influence of the refining conditions on the molecular weight distribution and on the percentage of the soluble portion of the derivatives was investigated. It could be shown that low-molecular portions of the cellulose samples were lost applying those refining methods which included precipitation steps. For unbleached pulps, the risk existed that part of the derivatives remained insoluble and formed gel-like particles. For some pulp samples better results could be obtained by elongation of the derivatization time. Some selected pulps were carbanilated and nitrated, and the corresponding results were compared. 相似文献
95.
Bodo Baumeister Abhigyan Som Gopal Das Naomi Sakai Francis Vilbois David Gerard ShatrughanP. Shahi Stefan Matile 《Helvetica chimica acta》2002,85(9):2740-2753
Intermediate internal charge repulsion (ICR) is required to create synthetic pores with large, stable, transmembrane, and variably functionalized space. This conclusion is drawn from maximal transport and, in one case, catalytic activity of p‐octiphenyl β‐barrel pores with internal lysine, aspartate, and histidine residues around pH 7, 6, and 4.5, respectively. pKa Simulations corroborate the experimental correlation of intermediate ICR with activity and suggest that insufficient ICR causes pore ‘implosion' and excess ICR pore ‘explosion'. Esterolysis experiments support the view that the formation of stable space within multifunctional p‐octiphenyl β‐barrels requires more ICR in bilayer membranes than in H2O. Multivalency effects are thought to account for p‐octiphenyl β‐barrel expansion with increasing number of β‐sheets, and proximity effects for unchanged pH profiles with increasing β‐sheet length. Q‐TOF‐nano‐ESI‐MS barrel‐denaturation experiments indicate that contributions from internal counterion effects are not negligible. The overall characteristics of p‐octiphenyl β‐barrel pores with internal lysine, aspartate, and histidine residues, unlike de novo ‘α‐barrels' and similarly to certain biological channels, underscore the usefulness of rigid‐rod molecules to preorganize complex multifunctional supramolecular architecture. 相似文献
96.
A survey is given on recent findings in the enzymology of cellulose acetate degradation. Acetyl esterases have been identified as the principal enzymes, initiating cellulose acetate degradation as a prerequisite for endoglucanase-catalyzed cellulose acetate depolymerisation. Acetyl esterases are provided by nature to deacetylate naturally occurring partly acetylated polysaccharides, i.e. xylan and chitin. Accordingly they are not designed to attack high DS cellulose acetate. Under these circumstances acetyl esterases require a pretreatment of cellulose acetate, leading to some reduction in DS, in case highly substituted material should be degraded. One of these treatments is composting under the conditions of which a partial deacetylation may occur under the action of heat and high pH, facilitating the accessibility for acetyl esterases. However from the present knowledge it cannot be excluded that certain microbial specialists exist, being capable to degrade high DS cellulose acetate. 相似文献
97.
Bodo Saake Stefan Horner Jürgen Puls Thomas Heinze Wolfgang Koch 《Cellulose (London, England)》2001,8(1):59-67
An approach is presented for the quantitative analysis of the substituent distribution in carboxymethyl cellulose (CMC). Standard substances have been isolated by preparative HPLC and characterised by 13C-NMR spectroscopy. The availability of these reference substances enabled a quantitative HPLC determination of glucose and its seven carboxymethyl derivatives by anion exchange chromatography and pulsed amperometric detection. A comparison of sulphuric acid and perchloric acid hydrolysis for conventional CMC samples gave higher yields for perchloric acid. The yield of the eight CMC building units decreased with increasing DS for both hydrolysis methods. Results were different, when samples from new synthesis concepts were investigated. While CMCs from induced phase separation showed increasing hydrolysis yields up to a DS of 1.9 regioselectively substituted 2,3-O-CMC gave lower yields with increasing DS. For 2,3-O-CMC samples sulphuric acid proved to be the superior hydrolysis medium. 相似文献
98.
A systematic derivation is presented of the twist-2 anomalous dimensions of the general quark and gluon light-ray operators in the generalized Bjorken region in leading order both for unpolarized and polarized scattering. Various representations of the anomalous dimensions are derived in the non-local and local light cone expansion and their properties are discussed in detail. Evolution equations for these operators are derived using different representations. General two- and single-variable evolution equations are presented for the expectation values of these operators for non-forward scattering. The Compton amplitude is calculated in terms of these distribution amplitudes. In the limit of forward scattering a new derivation of the integral relations between the twist-2 contributions to the structure functions is given. Special limiting cases which are derived from the general relations are discussed, as the forward case, near-forward scattering, and vacuum-meson transition. Solutions of the two-variable evolution equations for non-forward scattering are presented. 相似文献
99.
100.