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991.
Bo Zheng Yiquan Liu Huihui Li Yunhua Ye Xingming Gao Gu Yuan 《Journal of mass spectrometry : JMS》2009,44(10):1478-1481
In this research, the characteristic ions' abundance ratio between two isomers A and B in MS/MS mass spectra was defined as a parameter for discriminating diastereomers. Through this ratio, the discrimination of four pairs of cyclic peptide (CP) diastereomers was successfully achieved. Furthermore, in the analysis of diastereomers' mixtures, both calibration curve and calculational methods were substantiated to have high precision and accuracy. The average absolute errors of the two methods were 2.0 and 2.5% in the 48 measurements of 16 samples, respectively. This research provided a promising approach for the analysis of the CP diastereomers in the fields of asymmetrical synthesis, chiral natural products and structural biology by ESI‐MS/MS. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
992.
多源单汇网络资源调度路径优化探讨 总被引:1,自引:0,他引:1
在考虑队列长度的前提下 ,论文在分析多源单汇资源传输问题的基础上 ,以两源单汇网络为例 ,在资源到达终点所需时间最短约束下 ,研究、计算了最短传输时间的上下界 ,并提出了相应的算法 .论文的研究内容为进一步研究多源多汇问题建立了基础 ,提供了思路 . 相似文献
993.
Yong‐Qin Wei Ke‐Chen Wu Bo‐Tao Zhuang Zhang‐Feng Zhou Ming‐Xin Zhang Cai‐Ping Liu 《无机化学与普通化学杂志》2005,631(8):1532-1535
The silver complex Ag(PPh3)2(H2TMT) ( 1 )(H3TMT = 2,4,6‐trimercapto‐1,3,5‐triazine) has been synthesized and characterized. The ligand trimercaptotriazine exhibits a novel coordination mode and the complex shows a special hydrogen bonding linkage in the crystal packing. The colorless crystals of 1 exhibit broad emission in the visible region at room temperature. TDDFT calculation indicated that the π–π attraction is crucial for fluorescence of the title complex. 相似文献
994.
995.
Chaotic annealing with hypothesis test for function optimization in noisy environments 总被引:1,自引:0,他引:1
As a special mechanism to avoid being trapped in local minimum, the ergodicity property of chaos has been used as a novel searching technique for optimization problems, but there is no research work on chaos for optimization in noisy environments. In this paper, the performance of chaotic annealing (CA) for uncertain function optimization is investigated, and a new hybrid approach (namely CAHT) that combines CA and hypothesis test (HT) is proposed. In CAHT, the merits of CA are applied for well exploration and exploitation in searching space, and solution quality can be identified reliably by hypothesis test to reduce the repeated search to some extent and to reasonably estimate performance for solution. Simulation results and comparisons show that, chaos is helpful to improve the performance of SA for uncertain function optimization, and CAHT can further improve the searching efficiency, quality and robustness. 相似文献
996.
By using the theory of coincidence degree,we study a kind of periodic solutions to second order differential equation with a deviating argument such as x"(t) f(x'(t)) h(x(t))x'(t) g(x(t-τ(t)))=p(t),some sufficient conditions on the existence of periodic solutions are obtained. 相似文献
997.
Yaqin Fu Minghao Sun Yonggang Wu Zhishan Bo Dongge Ma 《Journal of polymer science. Part A, Polymer chemistry》2008,46(4):1349-1356
Conjugated polymers containing electron‐transporting, hole‐transporting, and blue light‐emitting units were synthesized by Suzuki polycondensation. These copolymers exhibited excellent thermal and optical stability. Optical investigation indicated that the incorporation of the spirobifluorene units in the polymer main chain could markedly increase the effective conjugation length of polymers. Electrochemical studies showed that the incorporation of spirobifluorene unit could raise the electrochemical stability and improve the electron‐ and hole‐injecting abilities. The electroluminescent results also showed that the introducing of spirobifluorene units could significantly improve the device performance. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1349–1356, 2008 相似文献
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