Über die Synthese und Struktur der Magnesium- und Calcium-Hydrazidocarbonate

Ohne Zusammenfassung     

Electron capture in high-energy ion-atom collisions

We discuss the non-relativistic theory of electron capture from atoms (or ions) by ions when the relative velocity of the collision is greater than the orbital velocity of the captured electron. We emphasize the specific difficulties due to the two-body Coulomb potentials occurring in this process We show how the simplifications introduced by the small value of the electron to proton mass ratio can be used to provide a valuable tool to evaluate the adequacy of the existing theories. Extensive comparisons between theory and experiment are carried out and a number of new theoretical results are presented.     

Optical information processing by the Fabry-Perot resonator

Properties of the Fabry-Perot resonator as a part of an optical imaging system are discussed from the point of view of optical information theory. Information capacity of the system is derived and expressed in terms of the number of degrees of freedom of the optical wave field at the output. It is pointed out that the Fabry-Perot resonator is well suited for processing of image signals having a periodic structure.     

Polarometrische Bestimmung von Methylenblau mit Phosphorwolframsäure

Zusammenfassung Ein Mol Phosphorwolframsäure reagiert in 2,5M Salzsäure mit 5 Mol Methylenblau unter Bildung eines Niederschlages, der in Wasser und verdünnten Mineralsäuren unlöslich ist. Diese Reaktion wurde zur polarometrischen Bestimmung von Methylenblau benützt. Bei Einhaltung aller Versuchsbedingungen, besonders der Acidität der Lösung, sind die Resultate gut. Der Äquivalenzpunkt der Titration wurde unter Verwendung einer modifizierten Rechenmethode bestimmt.

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Polarometric determination of methylene blue with phosphotungstic acid

Summary One mol phosphotungstic acid reacts in 2.5M hydrochloric acid with 5 mol Methylene Blue creating a precipitate insoluble in water and in diluted mineral acids. The given reaction was applied for the polarometric determination of Methylene Blue. Under keeping of all experimental conditions, especially of the solution acidity, the results are good. The equivalence point of the titration was determined using a modified method of calculation.

     

Microscopic quadrupole and hexadecapole moments of rare earth nuclei

The theoretical calculations of multipole moments of even-even rare earth nuclei are presented. The potential energy surface is evaluated by the shell correction method. The condition ensuring the equality of the density distribution of the macroscopic liquid droplet part of the potential energy and the density generated by the single particle potential is added. A single particle Nilsson potential is used. New, less stiff potential surfaces versusε ₄ are obtained while the multipole moments calculated at the equilibrium deformations agree well with experimental data.     

Kinetics of the fluorescence of poly(N-vinylcarbazole) and poly(N-vinylcarbazole) with 2,4,7-trinitrofluorenone in the solid state

The fluorescence decay time measurements by the stroboscopic method have been made on films of amorphous poly(N-vinylcarbazole) (PVCA) and PVCA doped with 2,4,7-trinitrofluorenone (TNF). The obtained lifetimes of two excimer species have at 77 K and at 300 K values of about 43 ns and 9 ns, which are similar to other measurements. The kinetics of excimer fluorescence and energy transfer in PVCA films are described by a simple model of the Stern-Volmer type. It assumes the fast migration of localized singlet excitons and their trapping in two species of excimer traps.We propose a modified kinetic model for films of PVCA with TNF. In this model we assume besides the exciton migration and trapping on excimer and impurity traps also the direct energy transfer from two excimer species to charge transfer complexes of PVCA with TNF by the Förster dipole-dipole mechanism. The estimated critical distance of this transfer are about 10 Å.