首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   35651篇
  免费   2938篇
  国内免费   3004篇
化学   25641篇
晶体学   504篇
力学   1238篇
综合类   161篇
数学   5157篇
物理学   8892篇
  2023年   361篇
  2022年   786篇
  2021年   862篇
  2020年   885篇
  2019年   956篇
  2018年   855篇
  2017年   864篇
  2016年   1506篇
  2015年   1449篇
  2014年   1610篇
  2013年   2856篇
  2012年   2824篇
  2011年   2936篇
  2010年   1962篇
  2009年   2085篇
  2008年   2334篇
  2007年   2140篇
  2006年   1816篇
  2005年   1709篇
  2004年   1797篇
  2003年   1315篇
  2002年   1206篇
  2001年   700篇
  2000年   630篇
  1999年   454篇
  1998年   372篇
  1997年   326篇
  1996年   331篇
  1995年   305篇
  1994年   217篇
  1993年   229篇
  1992年   195篇
  1991年   176篇
  1990年   157篇
  1989年   147篇
  1988年   163篇
  1987年   117篇
  1986年   134篇
  1985年   206篇
  1984年   202篇
  1983年   146篇
  1982年   136篇
  1981年   129篇
  1980年   127篇
  1979年   102篇
  1978年   86篇
  1977年   76篇
  1976年   78篇
  1975年   63篇
  1974年   64篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
具Hardy-Sobolev临界指数的奇异椭圆方程多解的存在性   总被引:1,自引:0,他引:1  
运用变分方法研究了下面问题-Δpu=μupx(s)s-2u f(x,u),x∈Ω,u=0,x∈Ω,多重解的存在性,其中Ω是一个具有光滑边界的有界区域.  相似文献   
3.
(S)-2-[2-(p-Tolylsulfinyl)phenyl]acetaldehyde reacts with different O-silylated ketenethioacetals in the presence of Yb(OTf)3 yielding β-hydroxythioesters in high yields and diastereoselectivities. The obtained compounds were readily transformed into β-hydroxyacids and their corresponding diols. These Mukaiyama aldol reactions are a direct evidence of the ability of the sulfinyl group to control 1,5- and 1,6-asymmetric induction processes.  相似文献   
4.
The EPR spectra evolution of Cs2Zn1?x Cux(ZrF6)2 · 6H2O (x=0.01, 0.6, 0.8, and 1.0) in the temperature range 4.2–330 K and the x-ray structure analysis of the compound with x=1.0 in the range 150–327 K show that the Jahn-Teller (JT) complex Cu(H2O)6 coordination sphere undergoes a plastic deformation. The observed effect is due to the combined influence of small lattice strains existing in the paraphase and a new one appearing as a result of a ferroelastic phase transition and increasing with decreasing temperature below T c . It is proved that both cooperative interactions between JT complexes and ferroelastic strain stabilize a certain JT configuration. The problem of instability of a JT configuration compressed at T ~ 265 K is discussed.  相似文献   
5.
We analyze the dynamics of an AdS5 braneworld with matter fields when gravity is allowed to deviate from the Einstein form on the brane. We consider exact five-dimensional warped solutions which are associated with conformal bulk fields of weight –4 and describe on the brane the following three dynamics: those of inhomogeneous dust, of generalized dark radiation, and of homogeneous polytropic dark energy. We show that, with modified gravity on the brane, the existence of such dynamical geometries requires the presence of non-conformal matter fields confined to the brane.  相似文献   
6.
The mechanisms involved in the formation of n‐butanol during the synthesis of butyl acrylate containing latices were investigated. The experimental results showed that neither the hydrolysis of butyl acrylate nor of the ester bond in the butyl acrylate segments of the polymer played a major role in the formation of n‐butanol, which was mainly generated from the polymer backbone, by transfer reactions to polymer chain followed by cyclization. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5838–5846, 2007  相似文献   
7.
We introduce here some Itô calculus for non-continuous Dirichlet processes. Such calculus extends what was known for continuous Dirichlet processes or for semimartingales. In particular we prove that non-continuous Dirichlet processes are stable under C 1 transformation.  相似文献   
8.
用于强磁场的快响应真空规的研制进展   总被引:2,自引:2,他引:0  
研制了能在强磁场、强干扰环境下工作的快响应真空电离规(快规),用于对HL 2A装置偏滤器室和等离子体附近的中性粒子密度和通量进行原位测量。介绍了快规的结构、工作原理、设计要点以及实验结果。在无磁场的情况下,快规对气体压强的测量范围为6.4×10-6~0.15Pa,在1×10-5~0.15Pa范围内,快规收集极离子流与发射电子流之比与气压保持良好线性关系;在0 15T的磁场下,快规的规管常数未发生显著变化,在规管对称轴与磁力线的夹角小于15o时,规管常数的变化小于10%。  相似文献   
9.
A phenomenological model for describing the production of Centauro events in relativistic heavy-ion collisions is discussed. The model provides quantitative predictions for kinematical variables, for the baryon number, and for the masses of a Centauro fireball and of its decay products. A Centauro fireball decays predominantly into nucleons, strange hyperons, and possibly strangelets. Centauro events in Pb + Pb collisions at the LHC energy are simulated for the CASTOR detector. The signatures of these events are discussed in detail.  相似文献   
10.
Three‐component photoinitiators comprised of an N‐arylphthalimide, a diarylketone, and a tertiary amine were investigated for their initiation efficiency of acrylate polymerization. The use of an electron‐deficient N‐arylphthalimide resulted in a greater acrylate polymerization rate than an electron‐rich N‐arylphthalimide. Triplet energies of each N‐arylphthalimide, determined from their phosphorescence spectra, and the respective rate constants for triplet quenching by the N‐arylphthalimide derivatives (acquired via laser flash photolysis) indicated that an electron–proton transfer from an intermediate radical species to the N‐arylphthalimide (not energy transfer from triplet sensitization) is responsible for generating the initiating radicals under the conditions and species concentrations used for polymerization. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4009–4015, 2004  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号