Magic nucleus 132Sn and its one-neutron-hole neighbor 131Sn

Prompt and delayed gamma-ray cascades in doubly magic 132Sn and its neighbor 131Sn have been studied at Gammasphere using a 248Cm fission source. Isotopic assignments of unknown gamma rays were based on coincidences with known transitions in A = 112-116 Pd fission partners. The yrast level spectra of both tin nuclei are interpreted using empirical nucleon-nucleon interactions from the 132Sn and 208Pb regions. Results include identification of the (nuf(7/2)h(-1)(11/2))9(+) aligned state in 132Sn and of extensive (nuf(7/2)h(-2)(11/2)), (nuf(7/2)d(-1)(3/2)h(-1)(11/2)) and (nuh(-1)(11/2)x3(-)) multiplets in 131Sn. The previously reported beta(-) decay of an unusual 131In high-spin isomer to levels in 131Sn is also elucidated.     

Present status and future aspects of nuclear structure close to 100Sn

The present status of experimental approach to ¹⁰⁰Sn in the spectroscopy of excited states is landmarked by the T_z=3/2 nuclei between ⁹⁵Pd and ¹⁰¹In and the T_z=1 nuclei ⁹⁴Pd and ⁹⁸Cd. The detection limits with Pre-EUROBALL γ-arrays and ancillary detectors are below the 10^?5 level of the total fusion- evaporation residue cross section. A large scale shell model analysis of the existing data reveals the shell structure at ¹⁰⁰Sn, which shows a remarkable similarity to ⁵⁶Ni. Evidence for an increasing proton-neutron interaction in approaching the N=Z line is deduced from high spin isomers and spherical yrast lines. The effective E2 operator for protons and neutrons and implications for a low lying particle-hole (ph) E2 excitation in ¹⁰⁰Sn are discussed.     

Zur Ermittlung des Äthanolgehaltes galenischer Zubereitungen durch Bestimmung von Siedetemperaturen

Analytical and Bioanalytical Chemistry -     

Zur Bestimmung des Proteingehaltes in Weizen und Mehlproben

Ohne Zusammenfassung     

In-beam study of102Sn

Excited states in¹⁰²Sn have been identified for the first time, in an in-beamγ-ray spectroscopic experiment. Twoγ-ray transitions with energies 1472 and 497 keV following the decay of the seniority 6⁺ isomer with t_1/2=1.0(5)μs were unambiguously assigned to¹⁰²Sn. Due to the very low cross section of about 2µb for producing¹⁰²Sn in the reaction⁵⁰Cr(⁵⁸Ni,1α2n), a highly selective detector setup utilizing NORDBALL ancillary detectors and a recoil catcher device was used. Highγ-ray detection efficiency was achieved with two EUROBALL Ge cluster detectors.     

Optical spectroscopy of a polyfluorene copolymer at high pressure: intra- and intermolecular interactions

We present optical spectroscopy studies of the conjugated polymer poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) (F8BT) at high pressure. The photoluminescence spectrum of F8BT in a dilute solid-state solution in polystyrene redshifts by 320 meV over 7.4 GPa, while that of a F8BT thin film redshifts 460 meV over a comparable pressure range. We attribute the redshift in solution to intrachain pressure effects, principally conformational planarization. The additional contribution from interchain pi-electron interactions accounts for the larger redshift of thin films.     

Spacetime emergence of the robertson-walker universe from a matrix model

Using a novel, string theory-inspired formalism based on a Hamiltonian constraint, we obtain a conformal mechanical system for the spatially flat four-dimensional Robertson-Walker Universe. Depending on parameter choices, this system describes either a relativistic particle in the Robertson-Walker background or metric fluctuations of the Robertson-Walker geometry. Moreover, we derive a tree-level M theory matrix model in this time-dependent background. Imposing the Hamiltonian constraint forces the spacetime geometry to be fuzzy near the big bang, while the classical Robertson-Walker geometry emerges as the Universe expands. From our approach, we also derive the temperature of the Universe interpolating between the radiation and matter dominated eras.     

Diels-Alder approach for the construction of halogenated, o-nitro biaryl templates and application to the total synthesis of the anti-HIV agent siamenol

A rapid Diels-Alder approach to halogenated biaryl templates is described. These biaryl templates are available in two steps from the corresponding aromatic aldehydes. The scope of subsequent Suzuki couplings on the biaryl chlorides is explored. Good tolerance for both electron-donating and electron-withdrawing groups in the coupling process can be achieved. Further functionalization of the biaryl templates is described. Hydrogenation of the nitro moiety with concomitant removal of the benzyl ether yields the o-anilino, o-phenolic polyaryls. Selective reduction of the nitro group can be accomplished. Alternatively, the benzyl ether can be selectively removed under Lewis acidic conditions. The utilization of the Diels-Alder adducts for the synthesis of a series of chlorinated carbazoles via the Cadogan cyclization is also demonstrated. Finally, application of this technology to the total synthesis of siamenol, an anti-HIV agent, is reported.