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121.
Dominique Petit Jean-Pierre Korb Pierre Levitz Jean LeBideau David Brevet 《Comptes Rendus Chimie》2010,13(4):409-411
We present the first results of the nuclear magnetic relaxation dispersion (NMRD) of the confined proton-bearing cation (BMI) and fluorine-bearing anion (TFSI) pair of ionic liquids (Li+-ionogels) confined within a silica-like mesoporous matrices designed for lithium batteries. These results are in favour of a very-correlated dynamical motion of the anion–cation pair within the solid and disordered silica matrix. 相似文献
122.
123.
We study the relationship between two classical approaches for quantitative ergodic properties: the first one based on Lyapunov type controls and popularized by Meyn and Tweedie, the second one based on functional inequalities (of Poincaré type). We show that they can be linked through new inequalities (Lyapunov-Poincaré inequalities). Explicit examples for diffusion processes are studied, improving some results in the literature. The example of the kinetic Fokker-Planck equation recently studied by Hérau and Nier, Helffer and Nier, and Villani is in particular discussed in the final section. 相似文献
124.
Dominique Foata 《Journal of Combinatorial Theory, Series A》2008,115(5):726-736
Using classical transformations on the symmetric group and two transformations constructed in Fix-Mahonian Calculus I, we show that several multivariable statistics are equidistributed either with the triplet (fix, des, maj), or the pair (fix, maj), where “fix,” “des” and “maj” denote the number of fixed points, the number of descents and the major index, respectively. 相似文献
125.
126.
Dominique Langevin Dr. 《Chemphyschem》2008,9(4):510-522
This paper reviews the properties of aqueous foams. The current state of knowledge is summarized briefly and the interdisciplinary aspects of this field of investigation are emphasized. Many phenomena are controlled by physical laws, but they are highly dependent upon the chemicals used as foam stabilizers: surfactants, polymers, particles. Most of the existing work is related to surfactants and polymer foams, and little is known yet for particle foams although research in this field is becoming popular. This article presents the general concepts used to describe the monolayers and the films and also some of the recent advances being made in this area. 相似文献
127.
Dominique Duchêne Gilles Ponchel 《Journal of inclusion phenomena and macrocyclic chemistry》2002,44(1-4):15-16
The use of nanoparticles is of great interest for oral or parenteral administration. In fact, nanoparticles not only can protect the active ingredient, but they confer on it a large contact surface with biological membranes and a possible improvement in bioavailability. Biodegradability of nanoparticles, which can be considered as a pre-requisite in the case of parenteral administration 相似文献
128.
Bayes minimax estimators of the mean of a scale mixture of multivariate normal distributions 总被引:1,自引:0,他引:1
Bayes estimation of the mean of a variance mixture of multivariate normal distributions is considered under sum of squared errors loss. We find broad class of priors (also in the variance mixture of normal class) which result in proper and generalized Bayes minimax estimators. This paper extends the results of Strawderman [Minimax estimation of location parameters for certain spherically symmetric distribution, J. Multivariate Anal. 4 (1974) 255-264] in a manner similar to that of Maruyama [Admissible minimax estimators of a mean vector of scale mixtures of multivariate normal distribution, J. Multivariate Anal. 21 (2003) 69-78] but somewhat more in the spirit of Fourdrinier et al. [On the construction of bayes minimax estimators, Ann. Statist. 26 (1998) 660-671] for the normal case, in the sense that we construct classes of priors giving rise to minimaxity. A feature of this paper is that in certain cases we are able to construct proper Bayes minimax estimators satisfying the properties and bounds in Strawderman [Minimax estimation of location parameters for certain spherically symmetric distribution, J. Multivariate Anal. 4 (1974) 255-264]. We also give some insight into why Strawderman's results do or do not seem to apply in certain cases. In cases where it does not apply, we give minimax estimators based on Berger's [Minimax estimation of location vectors for a wide class of densities, Ann. Statist. 3 (1975) 1318-1328] results. A main condition for minimaxity is that the mixing distributions of the sampling distribution and the prior distribution satisfy a monotone likelihood ratio property with respect to a scale parameter. 相似文献
129.
Regis D. Gougeon Dr. Marianna Lucio Arnaud De Boel Moritz Frommberger Dr. Norbert Hertkorn Dr. Dominique Peyron Dr. David Chassagne Dr. François Feuillat Dr. Philippe Cayot Prof. Andrée Voilley Prof. Istvan Gebefügi Dr. Philippe Schmitt‐Kopplin Priv.‐Doz. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(3):600-611
A non‐targeted, ultra‐high‐resolution mass spectrometric, direct analysis of oak‐wood extracts from two species (Quercus robur L. and Quercus petraea Liebl.) from three French forests, and of a wine aged in barrels derived therefrom has been performed to identify families of metabolites that could discriminate both the species and the geographical origin of woods. From 12 T ultra‐high‐resolution Fourier transform ion cyclotron resonance mass spectra of wood extracts, hundreds of mass signals were identified as possible significant biomarkers of the two species, with phenolic and carbohydrate moieties leading the differentiation between Q. robur and Q. petraea, respectively, as corroborated by both FTMS and NMR data. For the first time, it is shown that oak woods can also be discriminated on the basis of hundreds of forest‐related compounds, and particular emphasis is put on sessile oaks from the Tronçais forest, for which sugars are significantly discriminant. Despite the higher complexity and diversity of wine metabolites, forest‐related compounds can also be detected in wines aged in related barrels. It is only by using these non‐targeted analyses that such innovative results, which reveal specific chemodiversities of natural materials, can be obtained. 相似文献
130.
Cláudia M. Morais Valérie Montouillout Michael Deschamps Dinu Iuga Franck Fayon Filipe A. A. Paz João Rocha Christian Fernandez Dominique Massiot 《Magnetic resonance in chemistry : MRC》2009,47(11):942-947
From one‐ to two‐ and three‐dimensional MAS NMR solid‐state experiments involving 31P and 27Al, we show that the structure of microporous alumino‐phosphate AlPO4‐40 contains at least four times more sites than expected, and we attribute two types of AlIV sites. The newly described 27Al‐31P MQ‐HMQC opens new possibilities of describing details of three‐dimensional bounded networks. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献