Charge kinetics in spinel and yttria-stabilized zirconia

Spinel and zirconia were studied by measuring the total secondary electron emission (SEE) yield σ in a dedicated scanning electron microscope (SEM) especially equipped to study the fundamental aspects of the charge trapping in insulating materials during a 1.1 keV electron irradiation at room temperature. The variation of the total SEE yield with the injected dose for both spinel and zirconia is different. In spinel the coefficient σ starts from its intrinsic value σ₀ = 4 and reaches a plateau at σ = 1 at the end of irradiation, which corresponds to the self-regulated regime. The continuity of the curves, shot after shot, proves that the trapped charges are stable and does not spread out in the material as injection proceeds. In this case spinel is called “trapper insulator”. In contrast with the spinel, σ in zirconia, never reaches unity while the injected charge increases: it evolves from its intrinsic yield σ₀ = 2.3 to a steady value a few percent above 1. The curve shows the relaxation of the positive generated charge. In this case zirconia is called “conductive insulator”. The difference in the charging kinetics of the two materials is attributed to the difference in conductivities.     

Alkaloids from the stem bark of Turraeanthus africanus (Meliaceae)

Fractionation of the methanol extract of the stem bark of Turraeanthus africanus led to the isolation of two new alkaloids designated turraeanthin A and B, together with two known alkaloids. The structures of the new alkaloids were elucidated by means of spectroscopic analysis and characterized as 10-O-demethyl-17-O-methyl isoarnottianamide and 11-demethoxyl-12-methoxyl oxynitidine respectively.     

Theoretical interpretation of the line shape of crystalline adipic acid

A general quantum theoretical approach of the upsilon(X-H) IR line shape of cyclic dimers of weakly H-bonded species in the crystal state is proposed. In this model, the adiabatic approximation (allowing to separate the high-frequency motion from the slow one of the H-bond bridge) is performed for each separate H-bond bridge of the dimer and a strong nonadiabatic correction is introduced into the model via the resonant exchange between the fast-mode excited states of the two moieties. Quantum indirect damping and Fermi resonances are taken into account. The present model reduces satisfactorily to many models in the literature dealing with more special situations. It has been applied to the cyclic dimers of adipic acid in the crystal phase. It correctly fits the experimental line shape of the hydrogenated compound and predicts satisfactorily the evolution in the line shapes with temperature and the change in the line shape with isotopic substitution.     

Experimental investigation of radiation transmission through a water spray

Radiation attenuation by a water spray is experimentally investigated. Spectral transmissivity measurements are performed between 1000 and with an experimental device involving a Fourier transform spectrometer. The spray is produced by a so-called Tee-Jet 400 067 nozzle for water pressure between 1.5 and 6 bar. Key features like mean attenuation levels due to absorption and scattering by droplets and complex absorption pattern by water vapor are identified. Known effect of attenuation modification when increasing the water pressure is observed. A simulation is also performed to evaluate a numerical code developed in a companion study. The achieved agreement demonstrates the ability of the simulation to describe the radiation attenuation by the spray.     

A stabilization for three‐dimensional discontinuous Galerkin discretizations applied to nonhydrostatic atmospheric simulations

A discontinuous Galerkin nonhydrostatic atmospheric model is used for two‐dimensional and three‐dimensional simulations. There is a wide range of timescales to be dealt with. To do so, two different implicit/explicit time discretizations are implemented. A stabilization, based upon a reduced‐order discretization of the gravity term, is introduced to ensure the balance between pressure and gravity effects. While not affecting significantly the convergence properties of the scheme, this approach allows the simulation of anisotropic flows without generating spurious oscillations, as it happens for a classical discontinuous Galerkin discretization. This approach is shown to be less diffusive than usual spatial filters. A stability analysis demonstrates that the use of this modified scheme discards the instability associated with the usual discretization. Validation against analytical solutions is performed, confirming the good convergence and stability properties of the scheme. Numerical results demonstrate the attractivity of the discontinuous Galerkin method with implicit/explicit time integration for large‐scale atmospheric flows. Copyright © 2015 John Wiley & Sons, Ltd.     

Study of polycarbonate–bismuth nitrate composite for shielding against gamma radiation

Journal of Radioanalytical and Nuclear Chemistry - Polycarbonate (PC) loaded with different filler levels equal to 0.1, 0.2, 0.3, 0.5, 0.75, 1.0, 2.5, 3.5 and 5.0 wt% (weight percent) of...     

Optimization of structural topology in the high-porosity regime

We propose a new approach to topology optimization, based on the use of “single-scale laminates” as structural components. The method is well-founded, because in the high porosity limit these structures achieve maximal stiffness and minimal weight. The method is useful, because the Hooke's law of a single-scale laminate has a simple, explicit formula which scales linearly with weight. And it is interesting, because the selection of relatively simple, manufacturable designs can be addressed using linear or quadratic programming. Our contributions are two-fold: (a) we establish the foundation of this approach, by defining single-scale laminates and giving self-contained proofs of their optimality in the high-porosity limit; and (b) we explore two numerical applications—minimizing weight with a constraint on the Hooke's law, and imposing continuity on a spatially varying microstructure.     

Hydrogenolysis of cyclohexane over Ir/SiO(2) catalyst: a mechanistic study of carbon--carbon bond cleavage on metallic surfaces.

The hydrogenolysis of cyclohexane catalyzed by supported Ir/SiO(2) has been studied to get mechanistic information on the elementary steps of C--C bond cleavage for cyclic saturated hydrocarbons. The reaction was studied under conditions in which no dehydrogenation to benzene occurs. When a mixture of cyclohexane and H(2) flows over a Ir/SiO(2) catalyst at 200 degrees C and for a H(2)/cyclohexane ratio superior to 40, methane, ethane, propane, n-butane, n-pentane, and n-hexane are identified to be primary products. The hydrogenolysis of ethane and n-hexane has also been studied to clarify several mechanistic questions. To account for the primary products in the above reactions, a mechanism is proposed in which the key step of the carbon--carbon bond cleavage occurs via concerted electronic transfer in dimetallacyclopentane intermediate. The comparison of product distributions in the hydrogenolysis of cyclohexane and that observed for n-hexane led to conclusions about the relative ease of carbon--carbon bond cleavage with respect to surface alkyl isomerization.