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61.
62.
A heuristic algorithm is described for vehicle routing and scheduling problems to minimise the total travel time, where the time required for a vehicle to travel along any road in the network varies according to the time of travel. The variation is caused by congestion that is typically greatest during morning and evening rush hours. The algorithm is used to schedule a fleet of delivery vehicles operating in the South West of the United Kingdom for a sample of days. The results demonstrate how conventional methods that do not take time-varying speeds into account when planning, except for an overall contingency allowance, may still lead to some routes taking too long. The results are analysed to show that in the case study using the proposed approach can lead to savings in CO2 emissions of about 7%. 相似文献
63.
Magnesium isotopic equilibrium in chlorophylls 总被引:2,自引:0,他引:2
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65.
Rybolt TR Wells CE Sisson CR Black CB Ziegler KA 《Journal of colloid and interface science》2007,314(2):434-445
The calculated molecule-surface binding energy, E(cal)( *), for physical adsorption was determined using molecular mechanics MM2 parameters for a model graphite surface and various organic molecules. The results for E(cal)( *) were compared to published experimental binding energy values, E( *), from gas chromatography (GC) or thermal desorption (TD). The binding energies from GC were for isolated molecules in the Henry's law region of adsorption, and the binding energies from TD were for molecules in monolayer coverage on a highly oriented pyrolytic graphite (HOPG). A simple desorption model was used to allow the calculation of monolayer coverage to include both molecule-surface and molecule-molecule interactions and then the results were compared to experimental values. For the 14 TD organic adsorbates (polyaromatic hydrocarbons, alcohols, benzene, substituted benzenes, methane, chloroalkanes, N,N-dimethylformamide, and C(60) Buckyball), the experimental versus calculated binding energies were E( *)=1.1193E(cal)( *) and r(2)=0.967. The GC E( *) values were also well correlated by calculated E(cal)( *) values for a set of 11 benzene and methyl substituted benzenes and for another set of 10 alkanes and haloalkanes. The TD E(cal)( *) mechanics computation provides a useful comparison to the one for GC data since adsorbate-adsorbate interactions as well as adsorbate-surface must be considered. 相似文献
66.
This paper details an investigation into the laser processing of medium-density fibreboard (MDF). Part 1 reports on the determination of process parameter settings for the effective cutting of MDF by CO2 laser, using an established experimental methodology developed to study the interrelationship between and effects of varying laser set-up parameters. Results are presented for both continuous wave (CW) and pulse mode (PM) cutting, and the associated cut quality effects have been commented on. 相似文献
67.
Kelly Black 《Numerical Methods for Partial Differential Equations》1997,13(6):587-599
A spectral element technique is examined, which builds upon a local discretization within the spectral space. To approximate a given system of equations the domain is subdivided into nonoverlapping quadrilateral elements, and within each element a discretization is found in the spectral space. The difference is that the test functions are divided into the higher-order polynomials, which have zero boundaries and lower-order polynomials, which are nonzero on one boundary. The method is examined for Navier–Stokes incompressible flow for fluid flow within a driven cavity and for flow over a backstep. © 1997 John Wiley & Sons, Inc. Numer Methods Partial Differential Eq 13: 587–599, 1997 相似文献
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69.
Klukovich HM Kean ZS Black Ramirez AL Lenhardt JM Lin J Hu X Craig SL 《Journal of the American Chemical Society》2012,134(23):9577-9580
Epoxidized polybutadiene and epoxidized polynorbornene were subjected to pulsed ultrasound in the presence of small molecules capable of being trapped by carbonyl ylides. When epoxidized polybutadiene was sonicated, there was no observable small molecule addition to the polymer. Concurrently, no appreciable isomerization (cis to trans epoxide) was observed, indicating that the epoxide rings along the backbone are not mechanically active under the experimental conditions employed. In contrast, when epoxidized polynorbornene was subjected to the same conditions, both addition of ylide trapping reagents and net isomerization of cis to trans epoxide were observed. The results demonstrate the mechanical activity of epoxides, show that mechanophore activity is determined not only by the functional group but also the polymer backbone in which it is embedded, and facilitate a characterization of the reactivity of the ring-opened dialkyl epoxide. 相似文献
70.
Kim A Black R Hyun YJ Nazar LF Prouzet E 《Chemical communications (Cambridge, England)》2012,48(36):4335-4337
Monolithic porous silica and carbon structures have been obtained by the synthesis of silica inside the aqueous phase of a sponge-like Swollen Liquid Crystal, and the parallel preparation of carbon replica. 相似文献