矿化剂对铝酸钙粉的结构与光谱性能的影响

研究了矿化剂对制备铝酸钙粉的结构与性能的影响.研究中以铝矾土和石灰石为原料,加入一定量的矿化剂,混合均匀,经高温煅烧制得铝酸钙粉.借助于红外光谱、X射线粉末衍射、差热-热重分析等手段对不同原料的铝酸钙粉的结构、组成及性能进行了表征和研究,并对矿化剂在合成铝酸钙中的矿化机理进行探讨.研究表明:加入矿化剂后,可在更低温度条件下煅烧制备出铝酸钙粉,有利于节能减排.红外光谱分析、XRD分析、DTA-TG分析显示:未加矿化剂煅烧时,生成的产物主要是Ca3Al10O18,CaAl2Si2O8.加入矿化剂后煅烧生成的产物主要是易浸出Al2O3的CaAl3BO7和Ca3Al10O18,而不易浸出Al2O3的CaAl2Si2O8的含量大大降低.同时显示,加入矿化剂后,原料中的方解石(CaCO3)分解更容易;CaCO3与铝矾土反应更充分;更有利于促使铝矾土中的Al-Si键断裂,将铝矾土中的Al释放出来;并可降低铝酸钙的煅烧温度.研究还显示:加入矿化剂后,可以改变原产物的晶体结构与成分,有利于降低煅烧反应温度.     

空腔靶能量吸收,转换特性实验研究

本文介绍空腔靶设计的物理思想、及能量吸收特性、X光转换特性和堵腔特性的实验研究方法,给出了实验观察到的一系列物理现象,通过对现象的分析而得出空腔靶的能量吸收和X光转换明显优于平面靶;利用相对孔径较大的聚焦透镜打空腔靶有利于改善靶的能量吸收和转换特性的结论。     

Cascade-exciton model analysis of level density parameter dependence in proton induced fission cross sections of some sub-actinide nuclei

Fission cross sections strongly depend on the ratio of the level density parameter in fission to neutron emission, a_f/a_n. In this work, a cascade-exciton model implemented in the code CEM95 has been used to observe this effect for proton induced fission cross sections of tungsten, lead and bismuth. The method was employed using different level density parameter ratios for each fission cross section calculation. The calculated fission cross sections are compared with the available experimental data in the literature. It has been observed that a change of the ratio of the level density parameter, a_f/a_n, is necessary with the incident energy of the proton, to best estimate the fission cross sections in CEM95.     

彩色负片印片颗粒指数的准确测定

分析了彩色负片印片颗粒指数σper实际测试中不同性能负片的测试特点和影响因素。印片颗粒指数的测试点应根据彩色负片的感光特性确定,为正常扩印时对应正片0．74中灰密度的负片密度点。影响印片颗粒指数值的两个主要因素是彩色相纸的反差修正系数α和彩色负片的覆盖力系数ECP;建立了α和ECP的实验求取方法,并通过对几种负片参量的实际测定,分析和说明了参量变化对印片颗粒指数数值的影响程度和应进行的修正。     

SrRuO3样品的制备及性能研究

利用化学共沉淀法制备了SrRuO3样品.X射线衍射确定样品为单相正交畸变钙钛矿结构.扫描电子显微镜观察了颗粒形貌基本成球形,颗粒尺寸分布在150~300 nm范围之间,SrRuO3样品在161 K温度以下具有铁磁性,SrRuO3样品没有表现出金属导电性.     

X光底片在位相对标定

本文描述了X光底片在位相对标定技术。其原理是使X射线谱经阶梯形吸收滤片透射后,对X光底片曝光,测量底片的曝光量。文中给出了标定方法和数据处理方法,而且也给出了在X光激光实验中得到的Kodak AA5底片的特性曲线。     

离散Lyapunov矩阵方程X—AXB=C的一种数值解法

本文提供了求解离散Lyapunov矩阵方程的一种数值解法。首先讨论了系数矩阵为三对角形矩阵的公式解法,然后通过相似变换,将该方法推广到一般情形。     

RESEARCH ON SOME CHARACTERISTICS AND IMPROVEMENTS OF A 70cm STREAMER CHAMBER

In this paper the influence of various proportion of Ne-He gases and the time delay on the quality of streamer tracks has been studied. The diameterand density of streamers under these mixed-gas conditions have been measured.
The time resolution of this streamer chamber was determined to be 2.1μs in 69% Ne+31% He+8×10^－8 SF₆, and as 177μs in pure neon by using the exponentially decreasing relation of streamer desity with delay time. The spatial resolution was determined to be 0.32mm in Ne+3×10^－8 SF₆ by measuring the streamer diameters, and the method of track standard deviation was also used.
Some results show that the diameter and brightness increase with increasing high voltage, but become rather even when high voltage continues increasing.
Photographs were taken with domestically produced special film (32 DIN, 60 lines/mm), being similar to Kodak SO-143.
A special designed central electrode of the streamer chamber with its wires inlaid in lucite plate is successful for preventing gas from breakdown near wires. Besides, delay time has been reduced to 1.3μs, mainly by the Marx generator and its trigger system the parameters of which have been chosen by a series of experiments.     

非傍轴平顶高斯光束M2因子两种定义的比较研究

基于功率密度的二阶矩方法，推导出了非傍轴平顶高斯(FG)光束束宽和远场发散角的解析表达式.研究表明，当w0/λ→0时，远场发散角趋于渐近值θmax=63.435°，与阶数无关.使用非傍轴高斯光束代替傍轴高斯光束作为理想光束，研究了非傍轴FG光束的M2因子，并与传统定义的M2因子作了比较.在非傍轴范畴，非傍轴FG光束的M2因子不仅与阶数N有关，而且与w0/λ有关.按照定义，当w0/λ→0时，非傍轴FG光束的M2因子不等于0，对阶数N=1, 2, 3时，M2因子分别趋于0.913,0.882和0.886.当N→∞时，M2因子取最小值M2min=0.816.     

钐(Ⅱ)类卡宾CH_3SmCH_2X(X=Cl、Br和Ⅰ)促进乙烯环丙烷化反应途径的理论研究(英文)

用密度泛函B3LYP方法研究了过渡金属钐类卡宾与乙烯的环丙烷化反应的机理。对三种不同的钐的SS试剂CH_3SmCH_2X(其中X=Cl、Br和Ⅰ)分别和CH_2CH_2反应的各反应物、中间体、过渡态和产物构型的全部结构几何参数进行了优化,用内禀反应坐标(IRC)计算和频率分析方法,对过渡态进行了验证。结果表明：CH_3SmCH_2X(其中X=Cl、Br和Ⅰ)与CH_2CH_2环丙烷化反应按亚甲基转移通道(通道A)和卡宾金属化通道(通道B)都可以进行,与锂类卡宾的反应机理相同,只是按亚甲基转移通道(通道A)进行反应较容易一些,而且此反应在较低的温度下就可以发生。